Some of Piaget's questions on moral judgment applied to some children in American schools

Thesis (M.A.)--Boston Universit

Bounds for the discrete correlation of infinite sequences on k symbols and generalized Rudin-Shapiro sequences

Motivated by the known autocorrelation properties of the Rudin-Shapiro sequence, we study the discrete correlation among infinite sequences over a finite alphabet, where we just take into account whether two symbols are identical. We show by combinatorial means that sequences cannot be "too" different, and by an explicit construction generalizing the Rudin-Shapiro sequence, we show that we can achieve the maximum possible difference.Comment: Improved Introduction and new Section 6 (Lovasz local lemma

Electric field gradients from first-principles and point-ion calculations

Point-ion models have been extensively used to determine "hole numbers" at copper and oxygen sites in high-temperature superconducting cuprate compounds from measured nuclear quadrupole frequencies. The present study assesses the reliability of point-ion models to predict electric field gradients accurately and also the implicit assumption that the values can be calculated from the "holes" and not the total electronic structure. First-principles cluster calculations using basis sets centred on the nuclei have enabled the determination of the charge and spin density distribution in the CuO2-plane. The contributions to the electric field gradients and the magnetic hyperfine couplings are analysed in detail. In particular they are partitioned into regions in an attempt to find a correlation with the most commonly used point-ion model, the Sternheimer equation which depends on the two parameters R and gamma. Our most optimistic objective was to find expressions for these parameters, which would improve our understanding of them, but although estimates of the R parameter were encouraging the method used to obtain the gamma parameter indicate that the two parameters may not be independent. The problem seems to stem from the covalently bonded nature of the CuO2-planes in these structures which severely questions using the Sternheimer equation for such crystals, since its derivation is heavily reliant on the application of perturbation theory to predominantly ionic structures. Furthermore it is shown that the complementary contributions of electrons and holes in an isolated ion cannot be applied to estimates of electric field gradients at copper and oxygen nuclei in cuprates.Comment: 19 pages, 4 figure

Towards a quantum-chemical description of crystalline insulators: A Wannier-function-based Hartree-Fock study of Li2O and Na2O

A recently proposed approach for performing electronic-structure calculations on crystalline insulators in terms of localized orthogonal orbitals is applied to the oxides of lithium and sodium, Li2O and Na2O. Cohesive energies, lattice constants and bulk moduli of the aforementioned systems are determined at the Hartree-Fock level, and the corresponding values are shown to be in excellent agreement with the values obtained by a traditional Bloch-orbital-based Hartree-Fock approach. The present Wannier-function-based approach is expected to be advantageous in the treatment of electron-correlation effects in an infinite solid by conventional quantum-chemical methods.Comment: 15 Pages, RevTex, 3 postscript figures (included), to appear in the Journal of Chemical Physics, May 15, 199

First-Principles Calculation of Electric Field Gradients and Hyperfine Couplings in YBa2Cu3O7

The local electronic structure of YBa2Cu3O7 has been calculated using first-principles cluster methods. Several clusters embedded in an appropriate background potential have been investigated. The electric field gradients at the copper and oxygen sites are determined and compared to previous theoretical calculations and experiments. Spin polarized calculations with different spin multiplicities have enabled a detailed study of the spin density distribution to be made and a simultaneous determination of magnetic hyperfine coupling parameters. The contributions from on-site and transferred hyperfine fields have been disentangled with the conclusion that the transferred spin densities essentially are due to nearest neighbour copper ions only with marginal influence of ions further away. This implies that the variant temperature dependencies of the planar copper and oxygen NMR spin-lattice relaxation rates are only compatible with commensurate antiferromagnetic correlations. The theoretical hyperfine parameters are compared with those derived from experimental data.Comment: 14 pages, 12 figures, accepted to appear in EPJ

Small- and medium-sized enterprise owners' perception of success in the textile and apparel industries : multiple case studies

Title from PDF of title page (University of Missouri--Columbia, viewed on July 11, 2011).The entire thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file; a non-technical public abstract appears in the public.pdf file.Thesis advisor: Dr. Jung E. Ha-Brookshire.Includes bibliographical references.M.S. University of Missouri--Columbia 2011.Small- to medium-sized enterprises (SMEs) are a critical part of many industries in today's U.S. economy, and are particularly important to the U.S. textile and apparel industry. While the importance of SMEs to the textile and apparel industry is great, little is known about SME owners perceptions of their success. To help minimize the gap in our understanding of SME success the research addressed how textile and apparel SME owners perceive their success. The theoretical frameworks of Maslow's hierarchy of needs and self-efficacy was used to explore the study questions: (1) how do U.S. textile and apparel SME owners perceive their success?, (2) how does the concept of self-efficacy play a role in SME owners' perceptions of success?; and (3) does Maslow's theory of human motivation provide a reasonable framework for understanding U.S. textile and apparel SMEs' success? The findings showed that SME owners describe their perceptions of success through the five themes; establishing a solid business foundation, fostering strong customer relationships, creating ties to the local community, flexibility through SME ownership, and happiness in their personal lives. The themes seemed to build upon one another, making Maslow's hierarchy a possible framework to be used in understanding SME owners' perceptions of success. The findings also showed that self-efficacy can play a role in how SME owners perceive their success

The Properties of the Heterogeneous Shakhbazyan Groups of Galaxies in the SDSS

We present a systematic study of the sub-sample of Shakhbazyan groups (SHKs) covered by the Sloan Digital Sky Survey Data Release--5 (SDSS-5). SHKs probe an environment with characteristics which are intermediate between those of loose and very compact groups. Surprisingly, we found that several groups identifying algorithms (e.g. Berlind et al. 2006, Tago et al. 2008) miss this type of structures. Using the SDSS-5 spectroscopic data and the photometric redshifts derived in D'Abrusco et al. 2007, we identified possible group members in photometric redshift space and derived, for each group, several individual properties. We also combined pointed and stacked Rosat All Sky Survey data to investigate the X-ray luminosities of these systems. Our study confirms that the majority of groups are physical entities with richness in the range 3--13 galaxies, and properties ranging between those of loose and compact groups. We confirm that SHK groups are richer in early-type galaxies than the surrounding environment and the field, as expected from the morphology-density relation and from the selection of groups of red galaxies. Furthermore, our work supports the existence of two sub-classes of structures, the first one being formed by compact and isolated groups and the second formed by extended structures. We suggest that while the first class of objects dwells in less dense regions like the outer parts of clusters or the field, possibly sharing the properties of Hickson Compact Groups, the more extended structures represent a mixture of [core+halo] configurations and cores of rich clusters. X-ray luminosities for SHKs are generally consistent with these results and with the expectations for the L_X-sigma_v relation, but also suggest the velocity dispersions reported in literature are underestimated for some of the richest systems.Comment: 20 pages, 14 figures, 4 tables. Accepted for publication by MNRA

Optical waveguiding in proton-implanted GaAs

We have produced optical waveguides in n-type GaAs by implantation with 300-keV protons. The guiding is shown to be due to the elimination of charge carriers from the implanted region. Annealing of the waveguide leads to very large reductions in the 1.15-µ guided-wave absorption

Ground state properties of heavy alkali halides

We extend previous work on alkali halides by calculations for the heavy-atom species RbF, RbCl, LiBr, NaBr, KBr, RbBr, LiI, NaI, KI, and RbI. Relativistic effects are included by means of energy-consistent pseudopotentials, correlations are treated at the coupled-cluster level. A striking deficiency of the Hartree-Fock approach are lattice constants deviating by up to 7.5 % from experimental values which is reduced to a maximum error of 2.4 % by taking into account electron correlation. Besides, we provide ab-initio data for in-crystal polarizabilities and van der Waals coefficients.Comment: accepted by Phys. Rev.