Biogeochemical processes in sediments of the Manfredonia Gulf (Southern Adriatic Sea): early diagenesis of carbon and nutrient and benthic exchange

In order to understand the mechanisms responsible of the recycle of carbon and nutrients at the sediment-water interface and to understand the role of sediments in nutrients mass balance in coastal water, cores were collected (pore waters and solid phases) and benthic fluxes (oxygen, dissolved nutrients, dissolved iron and manganese, alkalinity and TCO2) were measured in two stations in the Gulf of Manfredonia (Southern Adriatic Sea). Stations were chosen to include a site, in the offshore part of the gulf, under the influence of western Adriatic current and another site, in the inner part of the gulf, under influence of gyres occurring inside the gulf. Both stations were placed in areas characterized by high sedimentation rate. Fluxes at sediment water interface show higher values in S2 site during the summer. Bio-irrigation seems to be the main transport mechanism characterizing both sites, with more evident effects during summer in S1 site

Mussel watch program for microplastics in the Mediterranean sea: Identification of biomarkers of exposure using Mytilus galloprovincialis

Microplastics (MPs) are ubiquitous pollutants that have also been detected in the aquatic ecosystems at high concentrations. The use of shellfish as bioindicators is widespread for assessing and monitoring the environmental quality in both freshwater and marine environments. On this path, biomarkers represent an effective tool in monitoring programs. This minireview would broaden the existing knowledge on biomarkers of MPs in the Mediterranean mussel Mytilus galloprovincialis. This species was selected as it is widely distributed across the Mediterranean Sea and used as a bioindicator to monitor the presence of MPs in the marine environment. The literature search returned only 11 studies, mainly related to oxidative stress biomarkers. Although certain biomarkers were explored to estimate the effects of MPs on M. galloprovincialis, a battery of standardized and validated biomarkers as well as the inclusion of new ones are needed in future studies to obtain more comparable and robust findings across the Mediterranean Sea

Applications of MCMC methods on function spaces

In the course of this thesis, several different applications of data assimilation will be looked at. In each case, a rigorous mathematical framework will be constructed, in a Bayesian context, to enable the use of various types of data to infer on various infinite dimensional parameters of the system that has been observed. After careful consideration of the forward problem, well-defined posterior distributions on function space are constructed. Using MCMC methods which are defined on these function spaces themselves, we can construct Markov chains whose invariant measures are the posterior of interest. From this point, we can implement these methods on a computer, having finally discretised the problem. The philosophy that we adhere to throughout, is the idea that numerical methods formulated on function space are robust under discretisation, and do not suffer from the curse of dimensionality typically suffered by sampling methods formulated after disretisation. The first few chapters (after the introductory chapter) will focus on various aspects of data assimilation of observations of Stokes ow dynamics. Chapter 2 will focus on Eulerian data where direct observations of the velocity of the fluid at various points in time and space will be made. Chapter 3 will concentrate on data assimilation of indirect observations of the field, in the form of the positions of passive tracers in the flow. In these two chapters we will assume that the forcing of the system is known and that we are merely trying to recover the initial condition of the flow field. In chapter 4 we will consider both Eulerian and Lagrangian data assimilation, with the added complexity of trying to use the data to not only infer on the initial condition but also on the space-time dependant forcing of the system. In chapter 5 we will try to show how these smoothing methods could be adapted into a filtering algorithm, and a simple example will be presented. In the final chapter, 6, this Bayesian framework on function space will be applied to a shape matching problem with applications in the biomedical sciences.EThOS - Electronic Theses Online ServiceEngineering and Physical Sciences Research Council (EPSRC)GBUnited Kingdo

Osteochondral defects in the ankle: why painful?

Osteochondral defects of the ankle can either heal and remain asymptomatic or progress to deep ankle pain on weight bearing and formation of subchondral bone cysts. The development of a symptomatic OD depends on various factors, including the damage and insufficient repair of the subchondral bone plate. The ankle joint has a high congruency. During loading, compressed cartilage forces its water into the microfractured subchondral bone, leading to a localized high increased flow and pressure of fluid in the subchondral bone. This will result in local osteolysis and can explain the slow development of a subchondral cyst. The pain does not arise from the cartilage lesion, but is most probably caused by repetitive high fluid pressure during walking, which results in stimulation of the highly innervated subchondral bone underneath the cartilage defect. Understanding the natural history of osteochondral defects could lead to the development of strategies for preventing progressive joint damage

Biogeochemistry, grain size and mineralogy of the Central and Southern Adriatic Sea sediments: a review.

Volume 26 Supplement 1, January 2010

Mediterranean coastal lagoons: The importance of monitoring in sediments the biochemical composition of organic matter

Transitional water ecosystems are targeted by the European Union (EU) Water Framework Directive (WFD, CE 2000/60) monitoring programs in coastal zones. Concerning sediments, activities performed for the WFD focus on a few variables concerning the biochemical composition of organic matter. Our research reports the effects of oxygen availability on the biochemical composition of organic matter in sediments to highlight levels of targeted variables in time and, according to the depth of sediment layer, both under oxygenated and anoxic conditions in a mesocosm study on sediment cores. Results provide evidence that tested factors of interest (i.e., disturbance type, oxygenic versus anoxic conditions; persistence time of disturbance, 0\u201314 days; penetration through sedimentary layers, 0\u201310 cm depth) are able to significantly affect the biochemical composition of organic matter in sediments. Large part of the variables considered in this study (total organic carbon (TOC), total phosphorous (TP), total sulphur (TS), Fe, carbohydrates (CHO), total proteins (PRT), biopolymeric carbon (BPC), chlorophyll-a (Chl-a) are significantly affected and correlated to the oxygenation levels and could be good early indicators of important changes of environmental conditions. Monitoring activities performed under WFD guidelines and management strategies of Mediterranean coastal lagoon ecosystems shall include the biochemical composition of organic matter in sediment to provide an exhaustive picture of such dynamic ecosystems