154 research outputs found

    Physics of InAIAs/InGaAs Heterostructure Field-Effect Transistors

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    Contains an introduction, reports on two research projects and a list of publications.Joint Services Electronics Program Contract DAAL03-92-C-0001Joint Services Electronics Program Grant DAAH04-95-1-0038Raytheon Corporation Contract 90-58203Texas Instruments Agreement dated 08/14/9

    Three femoral stem designs without corrosion: A review of 2095 stems

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    © 2020 Naudie et al. Introduction: Corrosion at the head–neck interface of modular components in total hip arthroplasty (THA) has been reported as a cause of failure of modern total hip replacement implants. While this method of failure has been well described, it remains poorly understood. The purpose of this study is to review the three most commonly used uncemented femoral stems at our institution over the last fifteen years and to correlate any established risk factors with rates of revision, particularly corrosion. Methods: We reviewed 2095 patients from March 2000 to September 2015 who underwent total hip arthroplasty with one of three uncemented femoral stem designs. All stems were made of a Ti6Al4V alloy with a 12/14 taper design. We included only those stems coupled with a CoCr head and a highly crosslinked polyethylene liner. We evaluated age, gender, body mass index (BMI), femoral head size, head length, neck angle and offset and correlated these to the incidence of all cause revision, as well as revision excluding infection. Results: There were no recognized corrosion-related revisions identified. There was no association between age, BMI, gender, head length, neck angle and offset to all cause revision or revision with infection excluded (p\u3e0.05). Femoral head size less than 32mm was associated with higher all cause revision rates (OR 4.60 (95% CI 1.8, 11.8)) and when excluding infection as a reason for revision (OR 4.94 (95% CI 1.7, 14.41)). Conclusion: Over the last fifteen years, we have not identified any cases of corrosion with the three most commonly used femoral stems used at out institution. While we acknowledge that no femoral stem is immune to corrosion, certain femoral stem designs may be uniquely resistant to this mode of failure. Level of Evidence: III

    Hubble Space Telescope Observations of the Oldest Star Clusters in the LMC

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    We present V, V-I color-magnitude diagrams (CMDs) for three old star clusters in the Large Magellanic Cloud (LMC): NGC 1466, NGC 2257 and Hodge 11. Our data extend about 3 magnitudes below the main-sequence turnoff, allowing us to determine accurate relative ages and the blue straggler frequencies. Based on a differential comparison of the CMDs, any age difference between the three LMC clusters is less than 1.5 Gyr. Comparing their CMDs to those of M 92 and M 3, the LMC clusters, unless their published metallicities are significantly in error, are the same age as the old Galactic globulars. The similar ages to Galactic globulars are shown to be consistent with hierarchial clustering models of galaxy formation. The blue straggler frequencies are also similar to those of Galactic globular clusters. We derive a true distance modulus to the LMC of (m-M)=18.46 +/- 0.09 (assuming (m-M)=14.61 for M 92) using these three LMC clusters.Comment: 22 pages; to be published in Ap

    Prospects for local co-governance

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    British local authorities and their partners are increasingly developing new ways of working together with local communities. The nature of this co-working, however, is complex, multi-faceted and little understood. This article argues for greater clarity of thinking on the topic, by analysing this co-working as a form of political co-governance, and drawing attention in particular to issues of scale and democracy. Using evidence from a study of 43 local authority areas, 16 authorities are identified where co-governance is practised, following three main types of approach: service-influencing, service-delivering and parish council developing. It is concluded that strengthening political co-governance is essential for a healthy democracy

    High Voltage Mg-Doped Na 0.67 Ni 0.3– x Mg x Mn 0.7 O 2 ( x = 0.05, 0.1) Na-Ion Cathodes with Enhanced Stability and Rate Capability

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    Magnesium substituted P2-structure Na0.67Ni0.3Mn0.7O2 materials have been prepared by a facile solid-state method and investigated as cathodes in sodium-ion batteries. The Mg-doped materials described here were characterized by X-ray diffraction (XRD), 23Na solid-state nuclear magnetic resonance (SS-NMR), and scanning electron microscopy (SEM). The electrochemical performance of the samples was tested in half cells vs Na metal at room temperature. The Mg-doped materials operate at a high average voltage of ca. 3.3 V vs Na/Na+ delivering specific capacities of ∼120 mAh g–1, which remain stable up to 50 cycles. Mg doping suppresses the well-known P2–O2 phase transition observed in the undoped composition by stabilizing the reversible OP4 phase during charging (during Na removal). GITT measurements showed that the Na-ion mobility is improved by 2 orders of magnitude with respect to the parent P2–Na0.67Ni0.3Mn0.7O2 material. The fast Na-ion mobility may be the cause of the enhanced rate performance

    A Deep HST Search for Escaping Lyman Continuum Flux at z~1.3: Evidence for an Evolving Ionizing Emissivity

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    We have obtained deep Hubble Space Telescope far-UV images of 15 starburst galaxies at z~1.3 in the GOODS fields to search for escaping Lyman continuum photons. These are the deepest far-UV images m_{AB}=28.7, 3\sigma, 1" diameter) over this large an area (4.83 arcmin^2) and provide the best escape fraction constraints for any galaxy at any redshift. We do not detect any individual galaxies, with 3\sigma limits to the Lyman Continuum (~700 \AA) flux 50--149 times fainter (in f_nu) than the rest-frame UV (1500 \AA) continuum fluxes. Correcting for the mean IGM attenuation (factor ~2), as well as an intrinsic stellar Lyman Break (~3), these limits translate to relative escape fraction limits of f_{esc,rel}<[0.03,0.21]. The stacked limit is f_{esc,rel}(3\sigma)<0.02. We use a Monte Carlo simulation to properly account for the expected distribution of IGM opacities. When including constraints from previous surveys at z~1.3 we find that, at the 95% confidence level, no more than 8% of star--forming galaxies at z~1.3 can have relative escape fractions greater than 0.50. Alternatively, if the majority of galaxies have low, but non-zero, escaping Lyman Continuum, the escape fraction can not be more than 0.04. Both the stacked limits, and the limits from the Monte Carlo simulation suggest that the average ionizing emissivity (relative to non-ionizing UV emissivity) at z~1.3 is significantly lower than has been observed in Lyman Break Galaxies (LBGs) at z~3. If the ionizing emissivity of star-forming galaxies is in fact increasing with redshift, it would help to explain the high photoionization rates seen in the IGM at z>4 and reionization of the intergalactic medium at z>6. [Abridged]Comment: Submitted to ApJ (Nov. 6) Comments Welcome. 11 pages, 8 figure

    Oxygen redox chemistry without excess alkali-metal ions in Na2/3[Mg0.28Mn0.72]O2

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    The search for improved energy-storage materials has revealed Li- and Na-rich intercalation compounds as promising high-capacity cathodes. They exhibit capacities in excess of what would be expected from alkali-ion removal/reinsertion and charge compensation by transition-metal (TM) ions. The additional capacity is provided through charge compensation by oxygen redox chemistry and some oxygen loss. It has been reported previously that oxygen redox occurs in O 2p orbitals that interact with alkali ions in the TM and alkali-ion layers (that is, oxygen redox occurs in compounds containing Li+–O(2p)–Li+ interactions). Na2/3[Mg0.28Mn0.72]O2 exhibits an excess capacity and here we show that this is caused by oxygen redox, even though Mg2+ resides in the TM layers rather than alkali-metal (AM) ions, which demonstrates that excess AM ions are not required to activate oxygen redox. We also show that, unlike the alkali-rich compounds, Na2/3[Mg0.28Mn0.72]O2 does not lose oxygen. The extraction of alkali ions from the alkali and TM layers in the alkali-rich compounds results in severely underbonded oxygen, which promotes oxygen loss, whereas Mg2+ remains in Na2/3[Mg0.28Mn0.72]O2, which stabilizes oxygen

    High voltage structural evolution and enhanced Na-ion diffusion in P2-Na2/3Ni1/3-xMgxMn2/3O2 (0 < x < 0.2) cathodes from diffraction, electrochemical and ab initio studies

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    We have presented a detailed investigation of the effects of Mg substitution on the structure, electrochemical performance and Na-ion diffusion in high voltage P2-type Na2/3Ni1/3-xMgxMn2/3O2 (0 <x< 0.20) cathode materials for Na-ion batteries. Structural analysis using neutron diffraction showed that Mg2+ substitutes random Ni2+ on the 2b sites from ordered [(Ni2+/Mn4+)O6] honeycomb units along the ab-plane, leading to an AB-type structure that can be indexed using the P63 space group. Within the sodium layers, high Mg-substituting levels (i.e. x = 0.2) caused a disruption in the typical Na zig-zag ordering observed in the undoped material, leading to a more disordered Na distribution in the layers. Load curves of the x = 0.1, 0.2 materials show smooth electrochemistry, indicative of a solid-solution process. Furthermore, DFT calculations showed an increase on Na-ion diffusivity on the Mg-substituted samples. Enhanced cycling stability was also observed in these materials; structural analysis using high-resolution in-operando synchrotron X-ray diffraction show that such an improved electrochemical performance is caused by the suppression of the O2 phase and switch to the formation of an OP4 phase. Ab-initio studies support our experimental evidence showing that the OP4 phase (cf. O2) is the most thermodynamically stable phase at high voltages for Mg-substituted compounds. Finally, we have provided evidence using diffraction for the x = 1/2 and x = 1/3 intermediate Na+-vacancy ordered phases in P2-Na 2/3Ni1/3Mn2/3O2

    Ética na pesquisa com crianças: ausências e desafios

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    Valendo-se da sociologia da infância, o texto discute as questões da infância, da pesquisa e da ética que devem enformar todos os procedimentos desencadeados no processo de pesquisa com crianças. Será inicialmente apresentado o estado da arte acerca das discussões que têm caraterizado esse debate, que, sendo recente, conta com uma significativa reflexão. Apresentamos, ainda, alguns desafios que são fundamentais serem enfrentados para que se consiga uma ética viável na investigação com crianças, que passam pela indispensabilidade de se pensar as questões de poder que se estabelecem entre adultos e crianças; que passam também pelo enfrentamento do desafio que decorre das hierarquias protocolares e a maneira como estas podem contribuir para a invisibilidade epistemológica das crianças na pesquisa; que passam, finalmente, por um questionamento crítico relativamente à forma como é salvaguardada a autoria, quer de crianças, quer de adultos, na análise, interpretação e produção dos dados.This paper discusses, from the sociology of childhood, the issues of childhood, research and ethics which must shape the methodological procedures undertaken in the research processes with children. We, firstly, will present the state-of-the-art theoretical discussions that have been characterizing this debate, which, although recent, are already very significant. We also present some challenges, which are essential to face, in order to achieve a feasible ethic in research with children, which are related to the need to think about the power issues between adults and children. We also have to consider that the challenge stems from the protocol hierarchies and how sometimes these can contribute to the epistemological invisibility of children in research. Finally, a third challenge that mobilizes a critical analysis related to the way issues of authorship of children and adult, in the analysis, interpretation and production of scientific texts, are respected.Valiéndose de la sociología en la infancia, el texto discute las cuestiones de la infancia, de la investigación y la ética que deben conformar todos los procedimientos desencadenados en el proceso de investigación con niños y niñas. En primer lugar se presenta el estado de la arte acerca de las discusiones que vienen caracterizando a tal debate, que aun siendo reciente, ya cuenta con una significativa reflexión. Presentamos también algunos de los desafíos que resulta fundamental afrontar para alcanzar una ética viable en la investigación con niños y niñas, que pasan por la obligada necesidad de pensar las cuestiones de poder que se establecen entre adultos y niños; que pasan también por el afrontamiento al desafío que resulta de las jerarquías protocolarias y la forma cómo estas pueden contribuir para la invisibilidad epistemológica de los niños y niñas en la investigación. Que pasan, por fin, por un cuestionamiento crítico en cuanto a la forma como se salvaguarda la autoría, ya sea de niños o de adultos, en el análisis, interpretación y producción de datos.CIEC - Centro de Investigação em Estudos da Criança, IE, UMinho (UI 317 da FCT), PortugalFundos Nacionais através da FCT (Fundação para a Ciência e a Tecnologia) e cofinanciado pelo Fundo Europeu de Desenvolvimento Regional (FEDER) através do COMPETE 2020 – Programa Operacional Competitividade e Internacionalização (POCI) no âmbito do CIEC (Centro de Investigação em Estudos da Criança, da Universidade do Minho) com a referência POCI-01-0145-FEDER-00756

    Adolescents, Adults and Rewards: Comparing Motivational Neurocircuitry Recruitment Using fMRI

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    Background: Adolescent risk-taking, including behaviors resulting in injury or death, has been attributed in part to maturational differences in mesolimbic incentive-motivational neurocircuitry, including ostensible oversensitivity of the nucleus accumbens (NAcc) to rewards. Methodology/Principal Findings: To test whether adolescents showed increased NAcc activation by cues for rewards, or by delivery of rewards, we scanned 24 adolescents (age 12–17) and 24 adults age (22–42) with functional magnetic resonance imaging while they performed a monetary incentive delay (MID) task. The MID task was configured to temporally disentangle potential reward or potential loss anticipation-related brain signal from reward or loss notification-related signal. Subjects saw cues signaling opportunities to win or avoid losing 0,0, .50, or $5 for responding quickly to a subsequent target. Subjects then viewed feedback of their trial success after a variable interval from cue presentation of between 6 to17 s. Adolescents showed reduced NAcc recruitment by reward-predictive cues compared to adult controls in a linear contrast with non-incentive cues, and in a volume-of-interest analysis of signal change in the NAcc. In contrast, adolescents showed little difference in striatal and frontocortical responsiveness to reward deliveries compared to adults. Conclusions/Significance: In light of divergent developmental difference findings between neuroimaging incentive paradigms (as well as at different stages within the same task), these data suggest that maturational differences i
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