1,499 research outputs found
Test of long-range exchange-correlation kernels of time-dependent density functional theory at surfaces: Application to Si(111)2×1
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Reflectivity Anisotropy Spectra of Cu- and Ag- (110) surfaces from {\it ab initio} theory
We are able to disentagle the effects of the intraband and interband parts of
the bulk dielectric function on the bare dielectric anisotropy of the surface.
We show how the position, sign and amplitude of the structures observed in such
spectra depend on the above quantities. The lineshape of all the calculated
structures agree very well with the ones observed experimentally for samples
treated by suitable surface cleaning. In particular, we reproduce the observed
single peak structure of Ag at high energy, found to represent a state of the
clean surface different from the one giving the originally observed double peak
structure. This results is not reproduced by the 'local field' model.Comment: 4 pages, 3 figures. submitted to Phys. Rev. Let
Role of cellulose oxidation in the yellowing of ancient paper
The yellowing of paper on aging causes major aesthetic damages of cultural heritage. It is due to cellulose oxidation, a complex process with many possible products still to be clarified. By comparing ultraviolet-visible reflectance spectra of ancient and artificially aged modern papers with ab initio time-dependent density functional theory calculations, we identify and estimate the abundance of oxidized functional groups acting as chromophores and responsible of paper yellowing. This knowledge can be used to set up strategies and selective chemical treatments preventing paper yellowing
Stochastic interacting particle systems out of equilibrium
This paper provides an introduction to some stochastic models of lattice
gases out of equilibrium and a discussion of results of various kinds obtained
in recent years. Although these models are different in their microscopic
features, a unified picture is emerging at the macroscopic level, applicable,
in our view, to real phenomena where diffusion is the dominating physical
mechanism. We rely mainly on an approach developed by the authors based on the
study of dynamical large fluctuations in stationary states of open systems. The
outcome of this approach is a theory connecting the non equilibrium
thermodynamics to the transport coefficients via a variational principle. This
leads ultimately to a functional derivative equation of Hamilton-Jacobi type
for the non equilibrium free energy in which local thermodynamic variables are
the independent arguments. In the first part of the paper we give a detailed
introduction to the microscopic dynamics considered, while the second part,
devoted to the macroscopic properties, illustrates many consequences of the
Hamilton-Jacobi equation. In both parts several novelties are included.Comment: 36 page
Optimal network topologies for local search with congestion
The problem of searchability in decentralized complex networks is of great
importance in computer science, economy and sociology. We present a formalism
that is able to cope simultaneously with the problem of search and the
congestion effects that arise when parallel searches are performed, and obtain
expressions for the average search cost--written in terms of the search
algorithm and the topological properties of the network--both in presence and
abscence of congestion. This formalism is used to obtain optimal network
structures for a system using a local search algorithm. It is found that only
two classes of networks can be optimal: star-like configurations, when the
number of parallel searches is small, and homogeneous-isotropic configurations,
when the number of parallel searches is large.Comment: 4 pages. Final version accepted in PR
Ab initio optical properties of Si(100)
We compute the linear optical properties of different reconstructions of the
clean and hydrogenated Si(100) surface within DFT-LDA, using norm-conserving
pseudopotentials. The equilibrium atomic geometries of the surfaces, determined
from self-consistent total energy calculations within the Car-Parrinello
scheme, strongly influence Reflectance Anisotropy Spectra (RAS), showing
differences between the p(2x2) and c(4x2)reconstructions. The Differential
Reflectivity spectrum for the c(4x2) reconstruction shows a positive peak at
energies < 1 eV, in agreement with experimental results.Comment: fig. 2 correcte
Caracterização genética de ostras nativas do gênero Crassostrea no Brasil: base para o estabelecimento de um programa nacional de melhoramento.
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