Chemical mass transfer in shear zones and metacarbonate xenoliths: a comparison of four mass balance approaches

International audienceMass balance calculations have been performed through a comparison of published graphical and statistical approaches applied to two contrasted geological settings: (i) the development of a greenschist-facies ductile shear-zone that recorded a weak volume change but significant mass transfers, and (ii) the formation of exoskarns in metacarbonate xenoliths that recorded a large volume decrease related to huge mass transfers. The comparison of the four mass-balance approaches shows that, if uncertainties are ignored, (1) they yield similar results concerning the mobile vs immobile behaviour of many components; (2) they yield similar mass-change values on bulk rock and on individual chemical elements (bulk-rock mass-change values differ by a maximum of ca. 15 % between graphical and statistical treatments of the metacarbonate xenolith evolution). The main difference concerns the uncertainties on mass changes (for bulk rocks and individual elements), which are much larger with the graphical than with the statistical approaches when uncertainties on chemical elements are taken into account, as they should be.The main advantage of the graphical methods is their rapid implementation and the clarity of the diagrams. Their main disadvantages are that uncertainties on each chemical element and bulk compositions are not taken into account and the difficulty in choosing an accurate immobility field to precisely define errors. Graphical methods need to be completed by a statistical treatment that gives absolute mass transfer results. The statistical approaches have the advantage of taking into account the chemical heterogeneities of the compared populations, in conjunction to a precise data treatment. The statistical treatment is an important and necessary step to decipher and to be pertinent in interpreting mobility/immobility of chemical elements, and, thus, in the absolute quantification of mass and volume changes

Quantification of mass transfers and mineralogical transformations in a thrust fault (Monte Perdido thrust unit, southern Pyrenees, Spain)

In fold-and-thrust belts, shortening is mainly accommodated by thrust faults which are preferential zones for recrystallisation and mass transfer. This study focuses on a detachment fault related to the emplacement of the Monte Perdido thrust unit in the southern Pyrenees. The studied fault zone consists of a 10 m thick intensively foliated phyllonite developed within the Millaris marls, of Eocene age. The lithological homogeneity of the hanging wall and footwall allows us to compare the Millaris marls outside the fault zone with the highly deformed marls located in the fault zone and to quantify the chemical, mineralogical and volumetric changes related to deformation processes along the fault. The Millaris marls are composed of detrital quartz, illite, chlorite, minor albite and pyrite, in a micritic calcite matrix. In the fault zone, the cleavage planes are marked by clay minerals and calcite ± chlorite veins attest to fluid–mineral interactions during deformation. The mineral proportions in all samples from both the fault zone and Millaris marls have been quantified by two methods: (1) X-ray diffraction and Rietveld refinement, and (2) bulk chemical analyses as well as microprobe analyses to calculate modal composition. The excellent agreement between the results of these two methods allows us to estimate mineralogical variations using a modification of the Gresens' equation. During fault activation, up to 45 wt% of calcite was lost while the amounts of quartz and chlorite remained unchanged. Illite content remained constant to slightly enriched. The mineralogical variations were coupled with a significant volume loss (up to 45%) mostly due to the dissolution of micritic calcite grains. Deformation was accompanied by pressure solution and phyllosilicates recrystallisation. These processes accommodated slip along the fault. They required fluids as catalyst, but they did not necessitate major chemical transfers

Petrological, petrophysical and petrothermal study of a folded sedimentary succession: the Oliana anticline (Southern Pyrenees), outcrop analogue of a geothermal reservoir

The Oliana anticline (Southern Pyrenees) has been characterized as an outcrop analogue of a geothermal reservoir using field data (stratigraphy and fracturing) and petrological, petrophysical and petrothermal analyses. Five lithofacies were established including conglomerates, hybrid arenites, lithic arenites, carbonates and evaporites. Petrophysical measurements indicate widely dispersed values of bulk density, connected porosity, permeability and velocity of compressional acoustic waves. Connected porosity is the factor that mostly influences bulk density, compressional wave velocity and permeability. In turn, diagenetic processes (such as dissolution and cementation) and fracturing, coupled with petrological features such as mineral composition, matrix content and grain size, are the most critical factors controlling rock porosity along the Oliana anticline. Thermal conductivity measures reveal a compositional control on the thermal properties of rocks. Thermal characterization of the structure reveals a low conductive area that matches the carbonate and evaporite succession of the anticline core and a highly conductive zone associated with the detrital succession of the fold limbs. The Oliana anticline has been classified as a petrothermal system due to the low permeability values of the studied sedimentary succession. Despite such classification, this contribution provides a useful exploration tool for future studies of non-conventional geothermal and CO2 storage sites located in folded sedimentary successions in the proximal domain of foreland basins

Petrophysical and petrothermal dataset of the sedimentary succession in the Oliana anticline (Southern Pyrenees)

The petrophysical and petrothermal characterization of the sedimentary succession of the Oliana anticline in the Southern Pyrenees has been performed on the basis of mineral density, connected porosity, permeability, P-wave velocity and thermal conductivity measurements of rock samples distributed along this anticline. This dataset was used to explain: (I) the variability of petrophysical rock properties along the Oliana anticline, (II) the distribution of thermal conductivity along the sedimentary units of the anticline, (III) the relationships between the fold and petrology concerning the mineral density, connected porosity, permeability, P-wave velocity and thermal conductivity of rocks and (IV) the tectonic and diagenetic controls underlying the observed relationships, as described in the research article: 'Petrological, petrophysical and petrothermal study of a folded sedimentary succession: the Oliana anticline (Southern Pyrenees), outcrop analogue of a geothermal reservoir - Global and Planetary Change Journal (2023)". This contribution presents here the raw and statistical datasets used to discuss the potential of the Oliana anticline as a geothermal reservoir analogue and also includes an extended methodological section that proposes a new procedure to measure the thermal conductivity of highly heterogeneous coarse-grained sedimentary rocks using the Modified Transient Source Plane (MTPS) method on a TCi C-Therm thermal analyzer. These complete datasets can be used to better discuss and understand the principal limitations of outcrop analogue studies applied to unconventional geothermal reservoirs in foreland basins on the basis of the analysis of rock petrophysical and petrothermal properties. Furthermore, the data obtained in the Oliana anticline can be used to understand the structural, diagenetic and petrological factors that can modify the petrophysical and petrothermal properties of rocks and to discuss the potential of foreland basin margins to be used as geothermal reservoirs, comparing the data obtained in Oliana with studies developed in similar geological settings worldwide.</p

Evolution of diagenetic conditions and burial history in Buntsandstein Gp. fractured sandstones (Upper Rhine Graben) from in-situ δ¹⁸O of quartz and ⁴⁰Ar/³⁹Ar geochronology of K-feldspar overgrowths

In-situ δ¹⁸O measured in the quartz overgrowths help identify temperature and fluid origin variations responsible for cementation of the pore network (matrix and fracture) in the Buntsandstein Gp. sandstone reservoirs within the Upper Rhine Graben. The overgrowths record two types of the evolution of δ¹⁸O: 1) a monotonous decrease of the δ¹⁸Oovergrowth interpreted as linked to an increasing burial temperature and 2) random fluctuations, interpreted as pointing out the injection of allochthonous fluids in faulted areas, on the cementation processes of the pore network (both intergranular and fracture planes). Fluids causing the quartz cementation are either autochthonous buffered in ¹⁸O from clay illitisation; or allochthonous fluids of meteoric origin with δ¹⁸O below − 5%. These allochthonous fluids are in thermal disequilibrium with the host sandstone. The measured signal of δ¹⁸Oovergrowth measured from samples and calculated curves testing hypothetic δ¹⁸Ofluid are compared to T–t evolution during burial. This modelling proposes the initiation of quartz cementation during the Jurassic and is validated by the in-situ ⁴⁰Ar/³⁹Ar dating results obtained on the feldspar overgrowths predating quartz overgrowths. A similar diagenetic history is recorded on the graben shoulders and in the buried parts of the basin. Here, the beginning of the pore network cementation predates the structuration in blocks of the basin before the Cenozoic graben opening

Fault-controlled and stratabound Dolostones in the Late Aptian-earliest Albian Benassal Formation (Maestrat Basin, E Spain): petrology and geochemistry constrains

Fault-controlled hydrothermal dolomitization of the Late Aptian to earliest Albian Benassal Fm shallow water carbonates resulted in the seismic-scale stratabound dolostone geobodies that characterize the Benicàssim case study (Maestrat Basin, E Spain). Petrological and geochemical data indicate that dolomite cement (DC1) filling intergranular porosity in grain-dominated facies constituted the initial stage of dolomitization. The bulk of the dolostone is formed by a replacive nonplanar-a to planar-s dolomite (RD1) crystal mosaic with very low porosity and characteristic retentive fabric. Neomorphic recrystallization of RD1 to form replacive dolomite RD2 occurred by successive dolomitizing fluid flow. The replacement sequence DC1-RD1-RD2 is characterized by a depletion in the oxygen isotopic composition (mean δ18O(V-PDB) values from −6.92, to −8.55, to −9.86¿), which is interpreted to result from progressively higher temperature fluids. Clear dolomite overgrowths (overdolomitization) precipitated during the last stage of replacement. Strontium isotopic composition suggests that the most likely origin of magnesium was Cretaceous seawater-derived brines that were heated and enriched in radiogenic strontium and iron while circulating through the Paleozoic basement and/or Permo-Triassic red beds. Burial curves and analytical data indicate that the replacement took place at burial depths between 500 and 750 m, and by hydrothermal fluids exceeding temperatures of 80 °C. Following the partial dolomitization of the host rock, porosity considerably increased in dolostones by burial corrosion related to the circulation of acidic fluids derived from the emplacement of the Mississippi Valley-Type deposits. Overpressured acidic fluids circulated along faults, fractures and open stylolites. Saddle dolomite and ore-stage calcite cement filled most of the newly created vuggy porosity. Subsequent to MVT mineralization, precipitation of calcite cements resulted from the migration of meteoric-derived fluids during uplift and subaerial exposure. This late calcite cement destroyed most of the dolostone porosity and constitutes the main cause for its present day poor reservoir qualit

Continental weathering as a driver of Late Cretaceous cooling : new insights from clay mineralogy of Campanian sediments from the southern Tethyan margin to the Boreal realm

21 pagesInternational audienceNew clay mineralogical analyses have been performed on Campanian sediments from the Tethyan and Boreal realms along a palaeolatitudinal transect from 45° to 20°N (Danish Basin, North Sea, Paris Basin, Mons Basin, Aquitaine Basin, Umbria-Marche Basin and Tunisian Atlas). Significant terrigenous inputs are evidenced by increasing proportions of detrital clay minerals such as illite, kaolinite and chlorite at various levels in the mid- to upper Campanian, while smectitic minerals predominate and represented the background of the Late Cretaceous clay sedimentation. Our new results highlight a distinct latitudinal distribution of clay minerals, with the occurrence of kaolinite in southern sections and an almost total absence of this mineral in northern areas. This latitudinal trend points to an at least partial climatic control on clay mineral sedimentation, with a humid zone developed between 20° and 35°N. The association and co-evolution of illite, chlorite and kaolinite in most sections suggest a reworking of these minerals from basement rocks weathered by hydrolysis, which we link to the formation of relief around the Tethys due to compression associated with incipient Tethyan closure. Diachronism in the occurrence of detrital minerals between sections, with detrital input starting earlier during the Santonian in the south than in the north, highlights the northward progression of the deformation related to the anticlockwise rotation of Africa. Increasing continental weathering and erosion, evidenced by our clay mineralogical data through the Campanian, may have resulted in enhanced CO2 consumption by silicate weathering, thereby contributing to Late Cretaceous climatic cooling

NectarCAM : a camera for the medium size telescopes of the Cherenkov Telescope Array

NectarCAM is a camera proposed for the medium-sized telescopes of the Cherenkov Telescope Array (CTA) covering the central energy range of ~100 GeV to ~30 TeV. It has a modular design and is based on the NECTAr chip, at the heart of which is a GHz sampling Switched Capacitor Array and a 12-bit Analog to Digital converter. The camera will be equipped with 265 7-photomultiplier modules, covering a field of view of 8 degrees. Each module includes the photomultiplier bases, high voltage supply, pre-amplifier, trigger, readout and Ethernet transceiver. The recorded events last between a few nanoseconds and tens of nanoseconds. The camera trigger will be flexible so as to minimize the read-out dead-time of the NECTAr chips. NectarCAM is designed to sustain a data rate of more than 4 kHz with less than 5\% dead time. The camera concept, the design and tests of the various subcomponents and results of thermal and electrical prototypes are presented. The design includes the mechanical structure, cooling of the electronics, read-out, clock distribution, slow control, data-acquisition, triggering, monitoring and services.Comment: In Proceedings of the 34th International Cosmic Ray Conference (ICRC2015), The Hague, The Netherlands. All CTA contributions at arXiv:1508.0589

Pressure solution-fracturing interactions in weakly cohesive carbonate sediments and rocks: example of the synsedimentary deformation of the Campanian chalk from the Mons Basin (Belgium)

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