Sequential Separation of Uranium, Hafnium and Neodymium from Natural Waters Concentrated by Iron Coprecipitation

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/111909/1/ggr12049-sup-0002-TableS1.pdfhttp://deepblue.lib.umich.edu/bitstream/2027.42/111909/2/ggr12049-sup-0003-TableS2.pdfhttp://deepblue.lib.umich.edu/bitstream/2027.42/111909/3/ggr12049-sup-0008-TableS7.pdfhttp://deepblue.lib.umich.edu/bitstream/2027.42/111909/4/ggr12049-sup-0001-FigS1.pdfhttp://deepblue.lib.umich.edu/bitstream/2027.42/111909/5/ggr12049.pdfhttp://deepblue.lib.umich.edu/bitstream/2027.42/111909/6/ggr12049-sup-0004-TableS3.pdfhttp://deepblue.lib.umich.edu/bitstream/2027.42/111909/7/ggr12049-sup-0005-TableS4.pdfhttp://deepblue.lib.umich.edu/bitstream/2027.42/111909/8/ggr12049-sup-0006-TableS5.pdfhttp://deepblue.lib.umich.edu/bitstream/2027.42/111909/9/ggr12049-sup-0007-TableS6.pd

Sr and O isotopes in western Aleutian seafloor lavas: Implications for the source of fluids and trace element character of arc volcanic rocks

Highlights • An eclogite-melt component (slab melt) is present in volcanic rocks throughout the Aleutian arc. • Fluids that drive slab melting are produced by dehydration of serpentinite in the subducting plate. • Slab melting encompasses a large section of mafic oceanic crust unaffected by seawater alteration. • The subducting plate beneath the Aleutian arc is hotter than indicated by most thermal models. Abstract High Mg# andesites and dacites (Mg# = molar Mg/Mg + Fe) from western Aleutian seafloor volcanoes carry high concentrations of Sr (>1000 ppm) that is unradiogenic (87Sr/86Sr 0.7030). Data patterns in plots of 87Sr/86Sr vs Y/Sr and Nd/Sr imply the existence of an eclogite-melt source component – formed by partial melting of MORB eclogite in the subducting Pacific Plate – which is most clearly expressed in the compositions of western Aleutian andesites and dacites (Nd/Sr and Y/Sr 2 km below the paleo-seafloor. Oxygen isotopes in western Aleutian seafloor lavas, which fall within a narrow range of MORB-like values (δ18O=5.1–5.7δ18O=5.1–5.7), are also consistent with this model. These results indicate that the subducting Pacific lithosphere beneath the Aleutian arc is significantly hotter than indicated my most thermal models

Geochemistry and mineralogy of the phonolite lava lake, Erebus volcano, Antarctica: 1972–2004 and comparison with older lavas

Author Posting. © Elsevier B.V., 2008. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Journal of Volcanology and Geothermal Research 177 (2008): 589-605, doi:10.1016/j.jvolgeores.2007.11.025.Mount Erebus, Antarctica, is a large (3794 m) alkaline open-conduit stratovolcano that hosts a vigorously convecting and persistently degassing lake of anorthoclase phonolite magma. The composition of the lake was investigated by analyzing glass and mineral compositions in lava bombs erupted between 1972 and 2004. Matrix glass, titanomagnetite, olivine, clinopyroxene, and fluor-apatite compositions are invariant and show that the magmatic temperature (~1000°C) and oxygen fugacity (ΔlogFMQ = -0.9) have been stable. Large temperature variations at the lake surface (ca. 400 - 500°C) are not reflected in mineral compositions. Anorthoclase phenocrysts up to 10 cm in length feature a restricted compositional range (An10.3-22.9Ab62.8-68.1Or11.4-27.2) with complex textural and compositional zoning. Anorthoclase textures and compositions indicate crystallization occurs at low degrees of effective undercooling. We propose shallow water exsolution causes crystallization to occur and shallow convection repeats this process multiple times, yielding extremely large anorthoclase crystals. Minor variations in eruptive activity from 1972 to 2004 are decoupled from magma compositions. The variations probably relate to changes in conduit geometry within the volcano and/or variable input of CO2-rich volatiles into the upper-level magma chamber from deeper in the system. Eleven bulk samples of phonolite lava from the summit plateau that range in age from 0 ± 4 ka to 17 ± 8 ka were analyzed for major and trace elements. Small compositional variations are controlled by anorthoclase content. The lavas are indistinguishable from modern bulk lava bomb compositions and demonstrate that Erebus volcano has been erupting lava and tephra from the summit region with the same bulk composition for ~17 ka.The work at Erebus volcano and the continued operation of the Mount Erebus Volcano Observatory is supported by grants (OPP-0229305, ANT-0538414) from the Office of Polar Programs, National Science Foundation

A 210Pb–226Ra–230Th–238U study of Klyuchevskoy and Bezymianny volcanoes, Kamchatka

Lavas from Klyuchevskoy and Bezymianny volcanoes, Kamchatka, appear to show a link between the extent of partial melting in their mantle source region and the subsequent degree of fractionation suffered by the magmas during passage through the crust. This fractionation may have occurred on timescales significantly less than 1000 years if observed 226Ra excesses largely reflect variable residual porosity in the source melting region. Unlike most arc lavas, those with the highest MgO contents and Ba/Th ratios have the lowest 226Ra excess. Forward models suggest that those portions of the source which had undergone the greatest addition of U by fluids from the subducting plate also underwent the greatest extents of partial melting at the highest residual porosity. At Kluchevskoy, a change from eruption of high-MgO to high-Al2O3 basaltic andesites around 1945 is reflected in an increase in size of 226Ra excess which seems to require a simultaneous decrease in residual porosity and suggests a rapid changes in the melting regime. The eruption of andesites at Bezyminanny, simultaneous with the eruption of basaltic andesites at Klyuchevskoy, further suggests that different degree melts produced at differing residual porosity can be formed and extracted from the melt region at the same time. Thus, the melting processes beneath Klyuchevskoy and Bezyminanny are demonstrably complex. They have clearly been influenced by both fluid addition from the subducting plate and extension and decompression beneath the Central Kamchatka Depression. Finally, the 210Pb data are, with one or two exceptions, in equilibrium with 226Ra, suggesting that there was restricted relative magma-gas movement in this highly productive magmatic system

Short length scale mantle heterogeneity beneath Iceland probed by glacial modulation of melting

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Short length scale mantle heterogeneity beneath Iceland probed by glacial modulation of melting

Glacial modulation of melting beneath Iceland provides a unique opportunity to better understand both the nature and length scale of mantle heterogeneity. At the end of the last glacial period, View the MathML source BP, eruption rates were ∼20–100 times greater than in glacial or late postglacial times and geophysical modeling posits that rapid melting of the large ice sheet covering Iceland caused a transient increase in mantle decompression melting rates. Here we present the first time-series of Sr–Nd–Hf–Pb isotopic data for a full glacial cycle from a spatially confined region of basaltic volcanism in northern Iceland. Basalts and picrites erupted during the early postglacial burst of volcanic activity are systematically offset to more depleted isotopic compositions than those of lavas erupted during glacial or recent (<7 kyr) times. These new isotopic data, coupled with major and trace element data, show that the mantle underneath northern Iceland is heterogeneous on small (<100 km) length scales. The temporal response of the isotopic compositions of the basalts to glacial unloading indicates that the isotopic composition of mantle heterogeneities can be linked to their melting behavior. The present geochemical data can be accounted for by a melting model in which a lithologically heterogeneous mantle source contains an enriched component more fusible than its companion depleted component