Letter from G. C. Shearer to the pastor of the Christian Church

Letter from G. C. Shearer to the pastor of the Christian Church in Gainesville, Florida. The one-page handwritten note is on G. C. Shearer letterhead and is dated 13 February 1910. There is a transcript of the correspondence in the item PDF

Stabilized lanthanum sulphur compounds

Lanthanum sulfide is maintained in the stable cubic phase form over a temperature range of from 500 C to 1500 C by adding to it small amounts of calcium, barium, or strontium. This compound is an excellent thermoelectric material

A comparison of the in vitro and in planta responses of Phytophthora cinnamomi isolates to phosphite

Research in plant pathology often relies on testing interactions between a fungicide and a pathogen in vitro and extrapolating from these results what may happen in planta. Likewise, results from glasshouse experiments are used to estimate what will happen if the fungicide is applied in the field. However, it is difficult to obtain conditions in vitro and in the glasshouse which reflect the conditions where the fungicide may eventually be used, in the field. The aim of this paper is to compare results of the effect of phosphite on P. cinnamomi isolates in vitro and in planta

Oxygen Fugacity of the Upper Mantle of Mars. Evidence from the Partitioning Behavior of Vanadium in Y980459 (Y98) and other Olivine-Phyric Shergottites

Using partitioning behavior of V between olivine and basaltic liquid precisely calibrated for martian basalts, we determined the redox state of primitive (olivine-rich, high Mg#) martian basalts near their liquidus. The combination of oxidation state and incompatible element characteristics determined from early olivine indicates that correlations between fO2 and other geochemical characteristics observed in many martian basalts is also a fundamental characteristic of these primitive magmas. However, our data does not exhibit the range of fO2 observed in these previous studies.. We conclude that the fO2 for the martian upper mantle is approximately IW+1 and is incompatible-element depleted. It seems most likely (although clearly open to interpretation) that these mantle-derived magmas assimilated a more oxidizing (>IW+3), incompatible-element enriched, lower crustal component as they ponded at the base of the martian crust

Automatic Reconstruction of Fault Networks from Seismicity Catalogs: 3D Optimal Anisotropic Dynamic Clustering

We propose a new pattern recognition method that is able to reconstruct the 3D structure of the active part of a fault network using the spatial location of earthquakes. The method is a generalization of the so-called dynamic clustering method, that originally partitions a set of datapoints into clusters, using a global minimization criterion over the spatial inertia of those clusters. The new method improves on it by taking into account the full spatial inertia tensor of each cluster, in order to partition the dataset into fault-like, anisotropic clusters. Given a catalog of seismic events, the output is the optimal set of plane segments that fits the spatial structure of the data. Each plane segment is fully characterized by its location, size and orientation. The main tunable parameter is the accuracy of the earthquake localizations, which fixes the resolution, i.e. the residual variance of the fit. The resolution determines the number of fault segments needed to describe the earthquake catalog, the better the resolution, the finer the structure of the reconstructed fault segments. The algorithm reconstructs successfully the fault segments of synthetic earthquake catalogs. Applied to the real catalog constituted of a subset of the aftershocks sequence of the 28th June 1992 Landers earthquake in Southern California, the reconstructed plane segments fully agree with faults already known on geological maps, or with blind faults that appear quite obvious on longer-term catalogs. Future improvements of the method are discussed, as well as its potential use in the multi-scale study of the inner structure of fault zones

Optical Pulse-Phased Photopolarimetry of PSR B0656+14

We have observed the optical pulse profile of PSR B0656+14 in 10 phase bins at a high signal-to-noise ratio, and have measured the linear polarization profile over 30% of the pulsar period with some significance. The pulse profile is double-peaked, with a bridge of emission between the two peaks, similar to gamma-ray profiles observed in other pulsars. There is no detectable unpulsed flux, to a 1-sigma limit of 16% of the pulse-averaged flux. The emission in the bridge is highly (~ 100%) polarized, with a position angle sweep in excellent agreement with the prediction of the Rotating Vector Model as determined from radio polarization observations. We are able to account for the gross features of the optical light curve (i.e., the phase separation of the peaks) using both polar cap and outer gap models. Using the polar cap model, we are also able to estimate the height of the optical emission regions.Comment: 27 pages, 11 figures, accepted by ApJ (scheduled v597 n2, November 10, 2003

Facile O-atom insertion into C-C and C-H bonds by a trinuclear copper complex designed to harness a singlet oxene

Two trinuclear copper [CuICuICuI(L)]1+ complexes have been prepared with the multidentate ligands (L) 3,3'-(1,4-diazepane-1,4-diyl)bis(1-((2-(dimethylamino)ethyl)(methyl)amino)propan-2-ol) (7-Me) and (3,3'-(1,4-diazepane-1,4-diyl)bis(1-((2-(diethylamino) ethyl)(ethyl) amino)propan-2-ol) (7-Et) as models for the active site of the particulate methane monooxygenase (pMMO). The ligands were designed to form the proper spatial and electronic geometry to harness a "singlet oxene," according to the mechanism previously suggested by our laboratory. Consistent with the design strategy, both [CuICuICuI(L)]1+ reacted with dioxygen to form a putative bis(µ3-oxo)CuIICuIICuIII species, capable of facile O-atom insertion across the central C-C bond of benzil and 2,3-butanedione at ambient temperature and pressure. These complexes also catalyze facile O-atom transfer to the C-H bond of CH3CN to form glycolonitrile. These results, together with our recent biochemical studies on pMMO, provide support for our hypothesis that the hydroxylation site of pMMO contains a trinuclear copper cluster that mediates C-H bond activation by a singlet oxene mechanism

Changes in vitamin biomarkers during a 2-year intervention trial involving increased fruit and vegetable consumption by free-living volunteers

Peer reviewedPublisher PD

Conditioning bounds for traveltime tomography in layered media

This paper revisits the problem of recovering a smooth, isotropic, layered wave speed profile from surface traveltime information. While it is classic knowledge that the diving (refracted) rays classically determine the wave speed in a weakly well-posed fashion via the Abel transform, we show in this paper that traveltimes of reflected rays do not contain enough information to recover the medium in a well-posed manner, regardless of the discretization. The counterpart of the Abel transform in the case of reflected rays is a Fredholm kernel of the first kind which is shown to have singular values that decay at least root-exponentially. Kinematically equivalent media are characterized in terms of a sequence of matching moments. This severe conditioning issue comes on top of the well-known rearrangement ambiguity due to low velocity zones. Numerical experiments in an ideal scenario show that a waveform-based model inversion code fits data accurately while converging to the wrong wave speed profile