Adsorption geometry, conformation, and electronic structure of 2H-octaethylporphyrin on Ag(111) and Fe metalation in ultra high vacuum

Due to the growing interest in the ferromagnetic properties of Fe-octaethylporphyrins (Fe-OEP) for applications in spintronics, methods to produce stable Fe-porphyrins with no Cl atoms are highly demanded. Here, we demonstrate the formation of Fe-OEP layers on Ag(111) single crystal by the ultra high vacuum in situ metalation of the free-base 2H-2,3,7,8,12,13,17,18- octaethylporphyrin (2H-OEP) molecules. The metalation proceeds exactly as in the case of 2H-5,10,15,20-tetraphenylporphyrin (2H-TPP) on the same substrate. An extensive surface characterization by means of X-ray photoemission spectroscopy, valence band photoemission, and NEXAFS with synchrotron radiation light provides information on molecular conformation and electronic structure in the monolayer and multilayer cases. We demonstrate that the presence of the ethyl groups affects the tilt of the adsorbed molecules, the conformation of the macrocycle, and the polarization screening in multilayers, but has only a minor effect in the metalation process with respect to 2H-TPP. \ua9 2013 American Institute of Physics

The DELPHI Small-angle Tile Calorimeter

The Small angle TIle Calorimeter (STIC) provides calorimetric coverage in the very forward region for the DELPHI experiment at the CERN LEP collider. A veto system composed of two scintillator layers allows to trigger on single photon events and provides e - gamma separation. We present here some results of extensive measurements performed on part of the calorimeter and the veto system in the CERN test beams prior to installation and report on the performance achieved during the 1994 LEP run

The silicon shower maximum detector for the STIC

The structure of a shashlik calorimeter allows the insertion of tracking detectors within the longitudinal sampling to improve the accuracy in the determination of the direction of the showering particle and the e/pi separation ability. The new forward calorimeter of the DELPHI detector has been equipped with two planes of silicon pad detectors respectively after 4 and 7.4 radiation lengths. The novelty of these silicon detectors is that to cope with the shashlik readout fibers, they had to incorporate 1.4 mm holes every cm(2). The detector consists of circular strips with a radial pitch of 1.7 mm and an angular granularity of 22.5 degrees, read out by means of the MX4 preamplifier. The preamplifier is located at 35 cm from the silicon detector and the signal is carried by Kapton cables bonded to the detector. The matching to the MX4 input pitch of 44 mu m was made by a specially developed fanin hybrid

The small angle tile calorimeter project in DELPHI

The new Small Angle Tile Calorimeter (STIC) covers the forward regions in DELPHI. The main motivation for its construction was to achieve a systematic error of 0.1% on the luminosity determination. This detector consists of a ''shashlik'' type calorimeter, equipped with two planes of silicon pad detectors placed respectively after 4 and 7.4 radiation lengths. A veto counter, composed of two scintillator planes, covers the front of the calorimeter to allow e-gamma separation and to provide a neutral energy trigger. The physics motivations for this project, results from extensive testbeam measurements and the performance during the 1994 LEP run are reported here

A silicon pad shower maximum detector for a Shashlik calorimeter

The new luminosity monitor of the DELPHI detector, STIC (Small angle Tile Calorimeter), was built using a Shashlik technique. This technique does not provide longitudinal sampling of the showers, which limits the measurement of the direction of the incident particles and the e - pi separation, For these reasons STIC was equipped with a Silicon Pad Shower Maximum Detector (SPSMD). In order to match the silicon detectors to the Shashlik read out by wavelength shifter (WLS) fibers, the silicon wafers had to be drilled with a precision better than 10 mu m without damaging the active area of the detectors. This paper describes the SPSMD with emphasis on the fabrication techniques and on the components used. Some preliminary results of the detector performance from data taken with a 45 GeV electron beam at CERN are presented

Performance of the DELPHI small angle tile calorimeter

The DELPHI STIC detector is a lead-scintillator sampling calorimeter with wave length shifting optical fibers used for light collection. The main goal of the calorimeter at LEP100 is to measure the luminosity with an accuracy better than 0.1%. The detector has been in operation since the 1994 LEP run. Presented here is the performance measured during the 1994-1995 LEP runs, with the emphasis on the achieved energy and space resolution, the long-term stability and the efficiency of the detector. The new bunch-trains mode of LEP requires a rather sophisticated trigger and timing scheme which is also presented. To control the trigger efficiency and stability of the calorimeter channels, a LED-based monitoring system has been developed

Performance of a shashlik calorimeter at LEPII

The Small Angle TIle Calorimeter (STIC) is a sampling lead-scintillator calorimeter, built with "shashlik" technique. Results are presented from extensive studies of the detector performance at LEP

Performance of the new high precision luminosity monitor of DELPHI

The STIC calorimeter was installed in the DELPHI detector in 1994. The main goal is to measure the luminosity with an accuracy better than 0.1 %. The calorimeter was built using the ''Shashlik'' technique. The light is collected by wavelength shifting fibers and readout by phototetrodes that can operate inside the magnetic field. The detector performance during the 1994-1995 data taking is presented. The different contributions to the systematic error on the luminosity measurement are discussed

Search for pentaquarks in the hadronic decays of the Z boson with the DELPHI detector at LEP

15 pages, 5 figures, Accepted by Phys. Lett. BThe quark model does not exclude states composed of more than three quarks, like pentaquark systems. Controversial evidence for such states has been published in the last years, in particular: for a strange pentaquark Theta(1540)+; for a double-strange state, the Xi(1862)--, subsequently called Phi(1860)--; and for a charmed state, the Theta_c(3100)^0. If confirmed, a full pentaquark family might exist; such pentaquark states could be produced in e+e- annihilations near the Z energy. In this paper a search for pentaquarks is described using the DELPHI detector at LEP, characterized by powerful particle identification sub-systems crucial in the separation of the signal from the background for these states. At 95% CL, upper limits are set on the production rates of such particles and their charge-conjugate state per Z decay: x Br(Theta+ -> pK0_S) Xi- pi-) D*+ pbar) < 8.8 x 10^{-4}