The influence of riparian-hyporheic zone on the hydrological responses in an intermittent stream

Stream and riparian groundwater hydrology has been studied in a small intermittent stream draining a forested catchment for a system representative of a Mediterranean climate. The relationship between precipitation and stream runoff and the interactions between stream water and the surrounding riparian groundwater have been analysed under a wide spectrum of meteorological conditions. The hypothesis that the hydrological condition of the near-stream groundwater compartment can regulate the runoff generation during precipitation events was tested. Stream runoff is characterised by a summer dry period, and precipitation input explained only 25% of runoff variability over the study period (r² =0.25, d.f.=51, p<0.001). The variability of precipitation v. stream runoff is explained partly by the hydrogeological properties of the riparian near-stream zone. This zone is characterised by high hydrological conductivity values and abrupt changes in groundwater level in summer. The summer dry period begins with a rapid decrease in near-stream groundwater level, and ends just after the first autumnal rain when the original groundwater level recovers suddenly. Within this period, storms do not cause major stream runoff since water infiltrates rapidly into the riparian compartment until it is refilled during the subsequent winter and spring; then the precipitation explains the 80% of the stream runoff variability (r²=0.80, d.f.=34, p<0.001). These results suggest that the hydrological interaction between the riparian groundwater compartment and the stream channel is important in elucidating the hydrological responses during drought periods in small Mediterranean streams.</p> <p style='line-height: 20px;'><b>Keywords:</b> riparian zone, groundwater hydrology, runoff, intermittent stream, Mediterranean climate</p

Modelling the inorganic nitrogen behaviour in a small Mediterranean forested catchment, Fuirosos (Catalonia)

The aim of this work was to couple a nitrogen (N) sub-model to already existent hydrological lumped (LU4-N) and semi-distributed (LU4-R-N and SD4-R-N) conceptual models, to improve our understanding of the factors and processes controlling nitrogen cycling and losses in Mediterranean catchments. The N model adopted provides a simplified conceptualization of the soil nitrogen cycle considering mineralization, nitrification, immobilization, denitrification, plant uptake, and ammonium adsorption/desorption. It also includes nitrification and denitrification in the shallow perched aquifer. We included a soil moisture threshold for all the considered soil biological processes. The results suggested that all the nitrogen processes were highly influenced by the rain episodes and that soil microbial processes occurred in pulses stimulated by soil moisture increasing after rain. Our simulation highlighted the riparian zone as a possible source of nitrate, especially after the summer drought period, but it can also act as an important sink of nitrate due to denitrification, in particular during the wettest period of the year. The riparian zone was a key element to simulate the catchment nitrate behaviour. The lumped LU4-N model (which does not include the riparian zone) could not be validated, while both the semi-distributed LU4-R-N and SD4-R-N model (which include the riparian zone) gave satisfactory results for the calibration process and acceptable results for the temporal validation process

Nitrogen concentrations in a small Mediterranean stream: 1. Nitrate 2. Ammonium

The importance of storm frequency as well as the groundwater and hyporheic inputs on nitrate (NO₃-N) and ammonium (NH₄-N) levels in stream water were studied in a small perennial Mediterranean catchment, Riera Major, in northeast Spain. NO₃-N concentrations ranged from 0.15 to 1.9 mg l^-1. Discharge explained 47% of the annual NO₃-N concentration variance, but this percentage increased to 97% when single floods were analysed. The rate of change in nitrate concentration with respect to flow, &#916;NO₃-N/&#916;Q, ranged widely from 0 to 20 &#956;g NO₃-N s l^-2. The &#916;NO₃-N/&#916;Q values fitted to a non linear model with respect to the storm flow magnitude (&#916;Q) (r²&#61;0.48, d.f.&#61;22, P<0.01). High values of &#916;NO₃-N/&#916;Q occurred at intermediate &#916;Q values, whereas low &#916;NO₃-N/&#916;Q values occurred during severe storms (&#916;Q > 400 l s^-1). N₃-N concentrations exhibit anticlockwise hysteresis patterns with changing flow and the patterns observed for autumnal and winter storms indicated that groundwater was the main N₃-N source for stream and hyporheic water. At baseflow, NO₃-N concentration in groundwater was higher (t&#61;4.75, d.f.&#61;29, P>0.001) and co-varied with concentrations in the stream (r&#61;0.91, d.f.&#61;28, P<0.001). In contrast, NO₃-N concentration in hyporheic water was identical to that in stream water. The role of the hyporheic zone as source or sink for ammonium was studied hyporheic was studied comparing its concentrations in stream and hyporheic zone before and after a major storm occurred in October 1994 that removed particulate organic matter stored in sediments. Results showed high ammonium concentrations (75&#177;28 s.d. &#956;g NH₄-N l^-1) before the storm flow in the hyporheic zone. After the storm, the ammonium concentration in the hyporheic dropped by 80% (13.6&#177;8 &#956;g N₄-N l^-1) and approached to the level found in stream water (11&#177;8 &#956;g NH₄-N l^-1) indicating that indisturbed hyporheic sediments act as a source for ammonium. After the storm, the ammonium concentrations in the stream, hyporheic and groundwater zones were very similar suggesting that stream ammonium concentrations are sustained mainly by input from groundwater. The present study provides evidence that storm flow magnitude is an important source of variability of nitrate concentration and fluxes in Mediterranean streams subjected to an irregular precipitation regime with prolonged dry periods

Calibration of the INCA model in a Mediterranean forested catchment: the effect of hydrological inter-annual variability in an intermittent stream

International audienceMediterranean regions are characterised by a stream hydrology with a marked seasonal pattern and high inter-annual variability. Accordingly, soil N processes and leaching of solutes in Mediterranean regions also show a marked seasonality, occurring in pulses as soils re-wet following rain. The Integrated Nitrogen Catchment model (INCA) was applied to Fuirosos, a Mediterranean catchment located in NE Spain using hydrological data and streamwater nitrate and ammonium concentrations collected from 1999 to 2002. This study tested the model under Mediterranean climate conditions and assessed the effect of the high inter-annual variability on the ability of INCA to simulate discharge and N fluxes. The model was calibrated for the whole three-year period and the n coefficients of determinion (r2) between simulated and observed data were 0.54 and 0.1 for discharge and nitrate temporal dynamics, respectively. Ammonium dynamics were simulated poorly and the linear regression between observed and simulated data was not significant statistically. To assess the effect of inter-annual variability on INCA simulations, the calibration process was run separately for two contrasting hydrological years: a dry year with a total rainfall of 525 mm and a wet year with a total of 871 mm. The coefficients of determination for the correlation between observed and simulated discharge for these two periods were 0.67 (p2 = 0.13 p2 = 0.56 p Keywords: environmental modelling, intermittent stream, Mediterranean climate, Fuirosos, hydrology, nitrat

Improving keratoconus management with central corneal regularization and corneal collagen cross-linking protocol treatment

Purpose. To evaluate safety and efficacy of customized central corneal regularization (CCR), together with simultaneous accelerated corneal collagen cross-linking (A-CXL) - CCR-CXL protocol, to treat keratoconus-related corneal ectasia. Design. Retrospective, comparative observational case series. Methods. Patients that had undergone combined CCR-CXL protocol. Main inclusion criteria were keratoconus visual acuity deterioration and contact lens intolerance. All patients underwent complete ophthalmological evaluation, corrected distance visual acuity (CDVA) and Scheimpflug-corneal tomography. Central corneal regularization was performed by ablation using flying spot laser. Subsequently, the stroma was saturated with 0.17% riboflavin-5-phosphate added every 2 minutes, followed by A-CXL 9 mW/cm2 for 10 minutes. CDVA, medium keratometry value (Kmed), and total corneal morphological irregularity index (CMI) of patients were analyzed before surgery and after 1, 3 and 12 months. A P value of.05 or less was considered statistically significant. Results. 46 eyes of 39 keratoconus patients were treated. At 1 month, the mean CDVA (LogMar) increased from 0.19 ± 0.02 to 0.12 ± 0.02 (P &lt; .05), and the difference remained stable at month 12. Kmax decrease was statistically significant from 57.02 ± 5.65 to 50.21 ± 4.48 (P &lt; .05). CMI decreased significantly from 47.8 ± 2.84 to 30.1 ± 2.4 (P &lt; .01). Conclusions. CCR-CXL protocol is safe and effective in arresting keratectasia progression and increasing corneal optic regularity in keratoconus. These findings showed a significant improvement in CDVA, keratometry values and corneal optical aberrations after being treated with the CCR-CXL protocol. Copyright © Società Editrice Universo (SEU

Molecular dynamics in polymer networks containing caprolactone and ethylene glycol moieties studied by dielectric relaxation spectroscopy

Copolymer networks with methacrylate main chain and caprolactone and ethylene glycol side groups were obtained by free radical copolymerisation of caprolactone methacrylate (CLMA) and poly(ethylene glycol) methacrylate (PEGMA). Dielectric relaxation spectroscopy was used to analyse molecular mobility of the different groups in the system. Only one main dielectric relaxation process was found in CLMA/PEGMA copolymer networks, located between those of the corresponding homonetworks, indicating that the system does not present phase separation. The copolymers show a secondary relaxation process at temperatures below &#8722;50 °C, which can be assigned to the overlapping of the corresponding secondary processes for the homopolymer networks; one of them was related to the local mobility of caprolactone units in CLMA and the second one was assigned to the twisting motions within ethylene glycol moiety in PEGMA. Besides the relaxation processes, the mobility of space charges has been analysed by means of conductivity and electric modulus formalisms.The support from the Spanish Ministry of Economy and Competitiveness (MINECO) and FEDER funds under the project MAT2012-38359-C03-01 is gratefully acknowledged.Sabater I Serra, R.; Escobar Ivirico, JL.; Romero Colomer, FJ.; Andrio Balado, A.; Gómez Ribelles, JL. (2014). Molecular dynamics in polymer networks containing caprolactone and ethylene glycol moieties studied by dielectric relaxation spectroscopy. Journal of Non-Crystalline Solids. 404:109-115. https://doi.org/10.1016/j.jnoncrysol.2014.08.013S10911540

soft robotic manipulation of onions and artichokes in the food industry

This paper presents the development of a robotic solution for a problem of fast manipulation and handling of onions or artichokes in the food industry. The complete solution consists of a parallel robotic manipulatior, a specially designed end-effector based on a customized vacuum suction cup, and a computer vision software developed for pick and place operations. First, the selection and design process of the proposed robotic solution to fit with the initial requeriments is presented, including the customized vacuum suction cup. Then, the kinematic analysis of the parallel manipulator needed to develop the robot control system is reviewed. Moreover, computer vision application is presented inthe paper. Hardware details of the implementation of the building prototype are also shown. Finally, conclusions and future work show the current status of the project