302 research outputs found
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NMR imaging and hydrodynamic analysis of neutrally buoyant non-Newtonian slurry flows
The flow of solids loaded suspension in cylindrical pipes has been the object of intense experimental and theoretical investigations in recent years. These types of flows are of great interest in chemical engineering because of their important use in many industrial manufacturing processes. Such flows are for example encountered in the manufacture of solid-rocket propellants, advanced ceramics, reinforced polymer composites, in heterogenous catalytic reactors, and in the pipeline transport of liquid-solids suspensions. In most cases, the suspension microstructure and the degree of solids dispersion greatly affect the final performance of the manufactured product. For example, solid propellant pellets need to be extremely-well dispersed in gel matrices for use as rocket engine solid fuels. The homogeneity of pellet dispersion is critical to allow good uniformity of the burn rate, which in turn affects the final mechanical performance of the engine. Today`s manufacturing of such fuels uses continuous flow processes rather than batch processes. Unfortunately, the hydrodynamics of such flow processes is poorly understood and is difficult to assess because it requires the simultaneous measurements of liquid/solids phase velocities and volume fractions. Due to the recent development in pulsed Fourier Transform NMR imaging, NMR imaging is now becoming a powerful technique for the non intrusive investigation of multi-phase flows. This paper reports and exposes a state-of-the-art experimental and theoretical methodology that can be used to study such flows. The hydrodynamic model developed for this study is a two-phase flow shear thinning model with standard constitutive fluid/solids interphase drag and solids compaction stresses. this model shows good agreement with experimental data and the limitations of this model are discussed
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Correlated geophysical, geochemical, and volcanological manifestations of plume-ridge interaction along the GalĂĄpagos Spreading Center
As the GalĂĄpagos hot spot is approached from the west along the GalĂĄpagos Spreading Center there are systematic increases in crustal thickness and in the K/Ti, Nb/Zr, ÂłHe/âŽHe, HâO, and NaâO content of lavas recovered from the spreading axis. These increases correlate with progressive transitions from rift valley to axial high morphology along with decreases in average swell depth, residual mantle Bouguer gravity anomaly, magma chamber depth, average lava Mg #, Ca/Al ratio, and the frequency of point-fed versus fissure-fed volcanism. Magma chamber depth and axial morphology display a âthresholdâ effect in which small changes in magma supply result in large changes in these variables. These correlated variations in geophysical, geochemical, and volcanological manifestations of plume-ridge interaction along the western GalĂĄpagos Spreading Center reflect the combined effects of changes in mantle temperature and source composition on melt generation processes, and the consequences of these variations on magma supply, axial thermal structure, basalt chemistry, and styles of volcanism.Keywords: hotspots, mid-ocean ridges, Mantle plume
Quantitative imaging of concentrated suspensions under flow
We review recent advances in imaging the flow of concentrated suspensions,
focussing on the use of confocal microscopy to obtain time-resolved information
on the single-particle level in these systems. After motivating the need for
quantitative (confocal) imaging in suspension rheology, we briefly describe the
particles, sample environments, microscopy tools and analysis algorithms needed
to perform this kind of experiments. The second part of the review focusses on
microscopic aspects of the flow of concentrated model hard-sphere-like
suspensions, and the relation to non-linear rheological phenomena such as
yielding, shear localization, wall slip and shear-induced ordering. Both
Brownian and non-Brownian systems will be described. We show how quantitative
imaging can improve our understanding of the connection between microscopic
dynamics and bulk flow.Comment: Review on imaging hard-sphere suspensions, incl summary of
methodology. Submitted for special volume 'High Solid Dispersions' ed. M.
Cloitre, Vol. xx of 'Advances and Polymer Science' (Springer, Berlin, 2009);
22 pages, 16 fig
Fossil energy in economic growth: A study of the energy direction of technical change, 1950-2012
Climate change mitigation challenges national economies to increase productivity while reducing fossil energy consumption. Fossil energy-saving technical change has been assumed to accomplish this, yet empirical evidence is scarce. This paper investigates the long-run relationship between the rate and direction of technical change with respect to fossil energy and labor in the world economy. Growth rates of labor productivity and the fossil energy-labor ratio are examined for more than 95 of world output between 1950 and 2012. The average elasticity of the energy-labor ratio with respect to labor productivity is close to one, implying highly energy-using technical change, but no trade-o between factor productivity growth rates. This stylized fact suggests the importance of a cheap, abundant energy supply for robust global growth, and a more important role for renewable energy. Integrated assessment models do not incorporate this restriction which may result in poorly speci ed baseline scenarios
Lower crustal crystallization and melt evolution at mid-ocean ridges
Author Posting. © The Author(s), 2012. This is the author's version of the work. It is posted here by permission of Nature Publishing Group for personal use, not for redistribution. The definitive version was published in Nature Geoscience 5 (2012): 651â655, doi:10.1038/ngeo1552.Mid-ocean ridge magma is produced when Earthâs mantle rises beneath the ridge axis and melts as a result of the decrease in pressure. This magma subsequently undergoes cooling and crystallization to form the oceanic crust. However, there is no consensus on where within the crust or upper mantle crystallization occurs1-5. Here we provide direct geochemical evidence for the depths of crystallization beneath ridge axes of two spreading centres located in the Pacific Ocean: the fast-spreading-rate East Pacific Rise and intermediate-spreading-rate Juan de Fuca Ridge. Specifically, we measure volatile concentrations in olivine-hosted melt inclusions to derive vapour-saturation pressures and to calculate crystallisation depth. We also analyse the melt inclusions for major and trace element concentrations, allowing us to compare the distributions of crystallisation and to track the evolution of the melt during ascent through the oceanic crust. We find that most crystallisation occurs within a seismically-imaged melt lens located in the shallow crust at both ridges, but over 25% of the melt inclusions have crystallisation pressures consistent with formation in the lower oceanic crust. Furthermore, our results suggest that melts formed beneath the ridge axis can be efficiently mixed and undergo olivine crystallisation in the mantle, prior to ascent into the ocean crust.This research was supported by the National Science
Foundation (EAR-0646694) and the WHOI Deep Ocean Exploration Institute/Ocean
Ridge Initiative.2013-02-1
Effusive and explosive volcanism on the ultraslow-spreading Gakkel Ridge, 85°E
Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 13 (2012): Q10005, doi:10.1029/2012GC004187.We use high-definition seafloor digital imagery and multibeam bathymetric data acquired during the 2007 Arctic Gakkel Vents Expedition (AGAVE) to evaluate the volcanic characteristics of the 85°E segment of the ultraslow spreading Gakkel Ridge (9 mm yrâ1 full rate). Our seafloor imagery reveals that the axial valley is covered by numerous, small-volume (order ~1000 m3) lava flows displaying a range of ages and morphologies as well as unconsolidated volcaniclastic deposits with thicknesses up to 10 cm. The valley floor contains two prominent volcanic lineaments made up of axis-parallel ridges and small, cratered volcanic cones. The lava flows appear to have erupted from a number of distinct source vents within the ~12â15 km-wide axial valley. Only a few of these flows are fresh enough to have potentially erupted during the 1999 seismic swarm at this site, and these are associated with the Oden and Loke volcanic cones. We model the widespread volcaniclastic deposits we observed on the seafloor as having been generated by the explosive discharge of CO2 that accumulated in (possibly deep) crustal melt reservoirs. The energy released during explosive discharge, combined with the buoyant rise of hot fluid, lofted fragmented clasts of rapidly cooling magma into the water column, and they subsequently settled onto the seafloor as fall deposits surrounding the source vent.We gratefully acknowledge
the financial support of the National Aeronautics and Space
Administration, the National Science Foundation (N.S.F.), the
International Polar Year 2007â2008, and Woods Hole Oceanographic
Institution; and the graduate support provided by N.S.F.,
the NDSEG Fellowship, and WHOI Deep Ocean Exploration
Institute.2013-04-0
Geochemistry of lavas from the 2005â2006 eruption at the East Pacific Rise, 9°46âČNâ9°56âČN : implications for ridge crest plumbing and decadal changes in magma chamber compositions
Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 11 (2010): Q05T09, doi:10.1029/2009GC002977.Detailed mapping, sampling, and geochemical analyses of lava flows erupted from an âŒ18 km long section of the northern East Pacific Rise (EPR) from 9°46âČN to 9°56âČN during 2005â2006 provide unique data pertaining to the short-term thermochemical changes in a mid-ocean ridge magmatic system. The 2005â2006 lavas are typical normal mid-oceanic ridge basalt with strongly depleted incompatible trace element patterns with marked negative Sr and Eu/Eu* anomalies and are slightly more evolved than lavas erupted in 1991â1992 at the same location on the EPR. Spatial geochemical differences show that lavas from the northern and southern limits of the 2005â2006 eruption are more evolved than those erupted in the central portion of the fissure system. Similar spatial patterns observed in 1991â1992 lavas suggest geochemical gradients are preserved over decadal time scales. Products of northern axial and off-axis fissure eruptions are consistent with the eruption of cooler, more fractionated lavas that also record a parental melt component not observed in the main suite of 2005â2006 lavas. Radiogenic isotopic ratios for 2005â2006 lavas fall within larger isotopic fields defined for young axial lavas from 9°N to 10°N EPR, including those from the 1991â1992 eruption. Geochemical data from the 2005â2006 eruption are consistent with an invariable mantle source over the spatial extent of the eruption and petrogenetic processes (e.g., fractional crystallization and magma mixing) operating within the crystal mush zone and axial magma chamber (AMC) before and during the 13 year repose period. Geochemical modeling suggests that the 2005â2006 lavas represent differentiated residual liquids from the 1991â1992 eruption that were modified by melts added from deeper within the crust and that the eruption was not initiated by the injection of hotter, more primitive basalt directly into the AMC. Rather, the eruption was driven by AMC pressurization from persistent or episodic addition of more evolved magma from the crystal mush zone into the overlying subridge AMC during the period between the two eruptions. Heat balance calculations of a hydrothermally cooled AMC support this model and show that continual addition of melt from the mush zone was required to maintain a sizable AMC over this time interval.This work has been supported by
NSF grants OCEâ0525863 and OCEâ0732366 (D. J. Fornari
and S. A. Soule), OCEâ0636469 (K. H. Rubin), and OCEâ
0138088 (M. R. Perfit), as well as postdoctoral fellowship funds
from the University of Florida
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