Temperature measurements and thermal gradient estimates on the slope and shelf edge region of the Beaufort Sea, Canada

In situ temperature measurements were conducted at 63 gravity-core stations during the 2013 expedition with the CCGS Sir Wilfrid Laurier in the Canadian Beaufort Sea. Outriggers attached to the outside of the gravity core-barrel were used to mount portable miniature temperature loggers (MTL) for down-core in situ temperature measurements. Several sub-regions were investigated during the expedition including two shelf-slope crossings, three mud volcano-type expulsion features, as well as two canyon sites. The last site visited was at the Gary Knolls, just east of the Mackenzie Trough at water depths of less than 100 m. Overall, temperature data obtained from the MTLs were of high quality at most stations and the data acquisition technique was proven to be robust and easy to adapt in the Arctic. However, depth determination for each logger position remains the largest challenge as no additional pressure sensor was used with the MTLs. Instead, depths were estimated based on the apparent core penetration and the geometry of the outriggers. The most significant result from this work is the discovery of the very large apparent geothermal gradients associated with the two expulsion features (EF) Coke Cap and the mud volcano at 420 m water depth. Temperatures measured within the top 2.5 meter below seafloor suggest geothermal gradients of up to 2.94ºC/m (Station 96, 420m EF) and 1.37 ºC/m (Station 58, Coke Cap EF). Away from the centre of the EFs, thermal gradients decrease to values of 0.5ºC/m for Station 99 at the 420 m EF, and 0.92ºC/m at Station 21 at the Coke Cap EF. Temperature data across the slope-shelf transect and the two transects across the canyon heads did not reveal considerable geothermal gradients, but show a water-depth dependent trend in temperature. From deep to shallow water, temperature appear to decrease until the most negative temperature values are found on the shelf itself at water depths of ~100 m (-1.2 to -1.4ºC). Overall, data from the top 1.0 to 1.5 meter below seafloor are likely affected by seasonal variations in the water column temperature and may not be used to define geothermal gradients. With an optimal full penetration of the core barrel, the deepest temperature data are from ~2.3 mbsf, which limits the accuracy of the estimated geothermal gradients as only few data points (2 - 4) can be used in the calculations

Detectionof gas hydrates infaults using azimuthal seismic velocity analysis,Vestnesa Ridge, W-Svalbard Margin

Accepted for publication in Journal of Geophysical Research. Solid Earth. Copyright 2020 American Geophysical Union. Further reproduction or electronic distribution is not permitted.Joint analysis of electrical resistivity and seismic velocity data is primarily used to detect the presence of gas hydrate‐filled faults and fractures. In this study, we present a novel approach to infer the occurrence of structurally‐controlled gas hydrate accumulations using azimuthal seismic velocity analysis. We perform this analysis using ocean‐bottom seismic (OBS) data at two sites on Vestnesa Ridge, W‐Svalbard Margin. Previous geophysical studies inferred the presence of gas hydrates at shallow depths (up to ~190‐195 m below the seafloor) in marine sediments of Vestnesa Ridge. We analyze azimuthal P‐wave seismic velocities in relation with steeply‐dipping near surface faults to study structural controls on gas hydrate distribution. This unique analysis documents directional changes in seismic velocities along and across faults. P‐wave velocities are elevated and reduced by ~0.06‐0.08 km/s in azimuths where the raypath plane lies along the fault plane in the gas hydrate stability zone (GHSZ) and below the base of the GHSZ, respectively. The resulting velocities can be explained with the presence of gas hydrate‐ and free gas‐filled faults above and below the base of the GHSZ, respectively. Moreover, the occurrence of elevated and reduced (>0.05 km/s) seismic velocities in groups of azimuths bounded by faults, suggests compartmentalization of gas hydrates and free gas by fault planes. Results from gas hydrate saturation modelling suggest that these observed changes in seismic velocities with azimuth can be due to gas hydrate saturated faults of thickness greater than 20 cm and considerably smaller than 300 cm

Ocean Bottom Seismometer Experiment on the Beaufort shelf and slope region conducted during Expedition ARA04C on the IBRV Araon

Expedition ARA04C (conducted from September 10 - September 26, 2013 in Canadian waters) on the Korean icebreaker IBRV Araon was laid out to investigate the Beaufort Sea shelf and slope region and collect geo-scientific data for various aspects relevant to the GSC's mandated regional geo-hazard assessment of the offshore Beaufort region. A critical element of the geohazards is the distribution of permafrost across the submerged shelf. To address this question a set of six Ocean Bottom Seismometers (OBS) were deployed in a grid pattern across the near shelf-edge zone, and a set of three OBS was used in a second deployment along a central shelfcrossing north-east to south-west oriented line. Initial data processing was carried out, which is required for any follow-up detailed velocity analysis. The processing included definition of exact shot times, geometry calculation, OBS position re-location, and OBS orientation analysis. A preliminary analysis of the hydrophone and vertical-component data from the OBS stations reveals a P-wave-velocity structure with values ranging from 1800 m/s to over 4000 m/s indicative of wide-spread ice-bearing sediments. This open-file report also contains the digital OBS data for all stations in standard SEGY format, together with the required raw and processed geometry information

Active mud volcanoes on the continental slope of the Canadian Beaufort Sea

The major geochemical characteristics of Red Sea brine are summarized for 11 brine-filled deeps located along the central graben axis between 19°N and 27°N. The major element composition of the different brine pools is mainly controlled by variable mixing situations of halite-saturated solution (evaporite dissolution) with Red Sea deep water. The brine chemistry is also influenced by hydrothermal water/rock interaction, whereas magmatic and sedimentary rock reactions can be distinguished by boron, lithium, and magnesium/calcium chemistry. Moreover, hydrocarbon chemistry (concentrations and δ 13 C data) of brine indicates variable injection of light hydrocarbons from organic source rocks and strong secondary (bacterial or thermogenic) degradation processes. A simple statistical cluster analysis approach was selected to look for similarities in brine chemistry and to classify the various brine pools, as the measured chemical brine compositions show remarkably strong concentration variations for some elements. The cluster analysis indicates two main classes of brine. Type I brine chemistry (Oceanographer and Kebrit Deeps) is controlled by evaporite dissolution and contributions from sediment alteration. The Type II brine (Suakin, Port Sudan, Erba, Albatross, Discovery, Atlantis II, Nereus, Shaban, and Conrad Deeps) is influenced by variable contributions from volcanic/ magmatic rock alteration. The chemical brine classification can be correlated with the sedimentary and tectonic setting of the related depressions. Type I brine-filled deeps are located slightly off-axis from the central Red Sea graben. A typical " collapse structure formation " which has been defined for the Kebrit Deep by evaluating seismic and geomorphological data probably corresponds to our Type I brine. Type II brine located in depressions in the northern Red Sea (i.e., Conrad and Shaban Deeps) could be correlated to " volcanic intrusion-/extrusion-related " deep formation. The chemical indications for hydrothermal influence on Conrad and Shaban Deep brine can be related to brines from the multi-deeps region in the central Red Sea, where volcanic/magmatic fluid/rock interaction is most obvious. The strongest hydrothermal influence is observed in Atlantis II brine (central multi-deeps region), which is also the hottest Red Sea brine body in 2011 (*68.2 °C)

Effectiveness of preoperative staging in rectal cancer: digital rectal examination, endoluminal ultrasound or magnetic resonance imaging?

In rectal cancer, preoperative staging should identify early tumours suitable for treatment by surgery alone and locally advanced tumours that require therapy to induce tumour regression from the potential resection margin. Currently, local staging can be performed by digital rectal examination (DRE), endoluminal ultrasound (EUS) or magnetic resonance imaging (MRI). Each staging method was compared for clinical benefit and cost-effectiveness. The accuracy of high-resolution MRI, DRE and EUS in identifying favourable, unfavourable and locally advanced rectal carcinomas in 98 patients undergoing total mesorectal excision was compared prospectively against the resection specimen pathological as the gold standard. Agreement between each staging modality with pathology assessment of tumour favourability was calculated with the chance-corrected agreement given as the kappa statistic, based on marginal homogenised data. Differences in effectiveness of the staging modalities were compared with differences in costs of the staging modalities to generate cost effectiveness ratios. Agreement between staging and histologic assessment of tumour favourability was 94% for MRI (kappa=0.81, s.e.=0.05; kappa(W)=0.83), compared with very poor agreements of 65% for DRE (kappa=0.08, s.e.=0.068, kappa(W)=0.16) and 69% for EUS (kappa=0.17, s.e.=0.065, kappa(W)=0.17). The resource benefits resulting from the use of MRI rather than DRE was 67164 UK pounds and 92244 UK pounds when MRI was used rather than EUS. Magnetic resonance imaging dominated both DRE and EUS on cost and clinical effectiveness by selecting appropriate patients for neoadjuvant therapy and justifies its use for local staging of rectal cancer patients

Freshwater Seepage Into Sediments of the Shelf, Shelf Edge, and Continental Slope of the Canadian Beaufort Sea

Long‐term warming of the continental shelf of the Canadian Beaufort Sea caused by the transgression associated with the last deglaciation may be causing decomposition of relict offshore subsea permafrost and gas hydrates. To evaluate this possibility, pore waters from 118 sediment cores up to 7.3‐m long were taken on the shelf and slope and analyzed for chloride concentrations and δ180 and δD composition. We observed downcore decreases in pore waters Cl− concentration in sediments from all sites from the inner shelf (<20‐m water depth), from the shelf edge, from the outer slope (down to 1,000‐m water depths), and from localized shelf features such as midshelf pingo‐like features and inner shelf pockmarks. In contrast, pore water freshening is absent from all investigated cores of the Mackenzie Trough. Downcore pore waters Cl− concentration decreases indicate regional widespread freshwater seepage. Extrapolations to zero Cl− of pore water Cl− versus δ180 regression lines indicate that freshwaters in these environments carry different isotope signatures and thus are sourced from different reservoirs. These isotopic signatures indicate that freshening of shelf sediments pore waters is a result of downward infiltration of Mackenzie River water, freshening of shelf edge sediments is due to relict submarine permafrost degradation or gas hydrate decomposition under the shelf, and freshening of slope sediments is consistent with regional groundwater flow and submarine groundwater discharge as far as 150 km from shore. These results confirm ongoing decomposition of offshore permafrost and suggest extensive current groundwater discharge far from the coast

Evidence for a deep gas hydrate stability zone associated with submerged permafrost on the Canadian Arctic Beaufort Shelf, Northwest Territories

The presence of offshore permafrost in the Canadian Beaufort Sea region has previously been identified from seismic and borehole data. The consequence of such permafrost is the possibility of an underlying gas-hydrate stability zone. In this study the authors present the first evidence for the widespread occurrence of gas hydrate in the offshore portion of the Beaufort Shelf using 3-D seismic data. A reflector of opposite polarity relative to the seafloor was identified at a depth of about 1000 m below seafloor that mimics some of the behaviour of the traditionally seen bottom-simulating reflectors in marine gas-hydrate regimes; however, the reflection identified is not truly bottom simulating, as its depth is rather controlled by the rapidly thinning wedge of submerged permafrost. The depth of the reflector decreases with increasing water depth, as predicted from thermal modelling. The reflection crosscuts strata and marks a zone of enhanced reflectivity underneath, possibly originating from free gas that accumulated at this phase boundary over time as the permafrost and associated gas-hydrate stability zones were thinning in response to the transgression. The presence of a clear and widespread gas-hydrate stability field beneath the permafrost has widespread implications on the region, including deep-drilling hazards associated with the presence of free gas, possible overpressure, and lateral migration of fluids and associated expulsion at the seafloor