Capture of liquid hydrogen boiloff with metal hydride absorbers

A procedure which uses metal hydrides to capture some of this low pressure (,1 psig) hydrogen for subsequent reliquefaction is described. Of the five normally occurring sources of boil-off vapor the stream associated with the off-loading of liquid tankers during dewar refill was identified as the most cost effective and readily recoverable. The design, fabrication and testing of a proof-of-concept capture device, operating at a rate that is commensurate with the evolution of vapor by the target stream, is described. Liberation of the captured hydrogen gas at pressure .15 psig at normal temperatures (typical liquefier compressor suction pressure) are also demonstrated. A payback time of less than three years is projected

Universal Statistics of the Critical Depinning Force of Elastic Systems in Random Media

We study the rescaled probability distribution of the critical depinning force of an elastic system in a random medium. We put in evidence the underlying connection between the critical properties of the depinning transition and the extreme value statistics of correlated variables. The distribution is Gaussian for all periodic systems, while in the case of random manifolds there exists a family of universal functions ranging from the Gaussian to the Gumbel distribution. Both of these scenarios are a priori experimentally accessible in finite, macroscopic, disordered elastic systems.Comment: 4 pages, 4 figure

How collective asperity detachments nucleate slip at frictional interfaces

Sliding at a quasi-statically loaded frictional interface can occur via macroscopic slip events, which nucleate locally before propagating as rupture fronts very similar to fracture. We introduce a novel microscopic model of a frictional interface that includes asperity-level disorder, elastic interaction between local slip events, and inertia. For a perfectly flat and homogeneously loaded interface, we find that slip is nucleated by avalanches of asperity detachments of extension larger than a critical radius $A_c$ governed by a Griffith criterion. We find that after slip, the density of asperities at a local distance to yielding $x_\sigma$ presents a pseudo-gap $P(x_\sigma) \sim (x_\sigma)^\theta$, where $\theta$ is a non-universal exponent that depends on the statistics of the disorder. This result makes a link between friction and the plasticity of amorphous materials where a pseudo-gap is also present. For friction, we find that a consequence is that stick-slip is an extremely slowly decaying finite size effect, while the slip nucleation radius $A_c$ diverges as a $\theta$-dependent power law of the system size. We discuss how these predictions can be tested experimentally

Structure of an intraplate fold-and-thrust belt: The Iberian Chain. A synthesis

The Iberian Chain is a complex intraplate fold-and-thrust belt resulting from the convergence between the Eurasian, Iberian and African plates during the late Eocene to the Miocene. The main trend of its contractional structures is NW-SE, but E-W, NE-SW and N-S-trending structures are also present. The boundaries of the chain with its surrounding foreland basins are always thrusts. The North-Iberian Thrust separates the chain from the Ebro Basin to the North, while the Serranía de Cuenca Thrust makes the SE boundary of the chain, separating it from the Tajo Basin and La Mancha foreland areas. Between these thrusts, the contractional structure is basement-involved, while South of the Serranía de Cuenca Thrust only Mesozoic and Cenozoic rocks are involved in the thrust-system, detached in the evaporitic Triassic materials. Two parts can be differentiated considering the major structure of the chain. The western and central areas hold two major anticlinoriums separated by the Almazán Synclinorium. East of the Teruel Depression, E-Wstriking N-verging thrusts in the North, and NW-SE-striking S-verging thrusts in the center and South are the dominant structures. The crust thickened during the Cenozoic contraction generating a mean crustal thickening of about 5km. The horizontal shortening obtained from cross-sections is 32km, and from a density-gravity section of 57.5km. These two values may be considered end values. The relief of the Iberian Chain has a strong areal coincidence with the contractional structures and the thickened crust, indicating that they are genetically related

Analysis of ischaemic crisis using the informational causal entropy-complexity plane

In the present work, an ischaemic process, mainly focused on the reperfusion stage, is studied using the informational causal entropy-complexity plane. Ischaemic wall behavior under this condition was analyzed through wall thickness and ventricular pressure variations, acquired during an obstructive flow maneuver performed on left coronary arteries of surgically instrumented animals. Basically, the induction of ischaemia depends on the temporary occlusion of left circumflex coronary artery (which supplies blood to the posterior left ventricular wall) that lasts for a few seconds. Normal perfusion of the wall was then reestablished while the anterior ventricular wall remained adequately perfused during the entire maneuver. The obtained results showed that system dynamics could be effectively described by entropy-complexity loops, in both abnormally and well perfused walls. These results could contribute to making an objective indicator of the recovery heart tissues after an ischaemic process, in a way to quantify the restoration of myocardial behavior after the supply of oxygen to the ventricular wall was suppressed for a brief period.Fil: Legnani, Walter. Universidad Tecnológica Nacional. Facultad Regional Buenos Aires; Argentina. Universidad Nacional de Lanús; ArgentinaFil: Traversaro Varela, Francisco. Instituto Tecnológico de Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Redelico, Francisco Oscar. Hospital Italiano; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Quilmes; ArgentinaFil: Cymberknop, Leandro Javier. Instituto Tecnologico de Buenos Aires. Departamento de Bioingenieria; Argentina. Universidad Tecnológica Nacional. Facultad Regional Buenos Aires; ArgentinaFil: Armentano, Ricardo Luis. Universidad Tecnológica Nacional. Facultad Regional Buenos Aires; Argentina. Instituto Tecnologico de Buenos Aires. Departamento de Bioingenieria; ArgentinaFil: Rosso, Osvaldo Aníbal. Universidad de los Andes; Chile. Universidade Federal de Alagoas; Brasil. Hospital Italiano; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentin

Flavin Binding to the Deca-heme Cytochrome MtrC: Insights from Computational Molecular Simulation

Certain dissimilatory bacteria have the remarkable ability to use extracellular metal oxide minerals instead of oxygen as terminal electron sinks, using a process known as "extracellular respiration". Specialized multiheme cytochromes located on the outer membrane of the microbe were shown to be crucial for electron transfer from the cell surface to the mineral. This process is facilitated by soluble, biogenic flavins secreted by the organism for the purpose of acting as an electron shuttle. However, their interactions with the outer-membrane cytochromes are not established on a molecular scale. Here, we study the interaction between the outer-membrane deca-heme cytochrome MtrC from Shewanella oneidensis and flavin mononucleotide (FMN in fully oxidized quinone form) using computational docking. We find that interaction of FMN with MtrC is significantly weaker than with known FMN-binding proteins, but identify a mildly preferred interaction site close to heme 2 with a dissociation constant (Kd) = 490 μM, in good agreement with recent experimental estimates, Kd = 255 μM. The weak interaction with MtrC can be qualitatively explained by the smaller number of hydrogen bonds that the planar headgroup of FMN can form with this protein compared to FMN-binding proteins. Molecular dynamics simulation gives indications for a possible conformational switch upon cleavage of the disulphide bond of MtrC, but without concomitant increase in binding affinities according to this docking study. Overall, our results suggest that binding of FMN to MtrC is reversible and not highly specific, which may be consistent with a role as redox shuttle that facilitates extracellular respiration

Polaronic structure of excess electrons and holes for a series of bulk iron oxides

Iron oxides such as hematite (α-Fe2O3) play an important role in diverse fields ranging from biogeochemistry to photocatalysis. Here we perform calculations of both the electron and electron hole polaron structures and associated reorganisation energies for a series of bulk iron oxides: hematite (α-Fe2O3), lepidocrocite (γ-FeOOH), goethite (α-FeOOH) and white rust (Fe(OH)2). Through the use of gap-optimized hybrid functionals and large supercells under periodic boundary conditions, we remove some of the complications and uncertainties present in earlier cluster model calculations. It is found that while the electron hole polaron in these materials generally localises onto a single iron site, the electron polaron localises across two iron sites of the same spin layer as a consequence of the lower reorganisation energy for electrons compared to holes. An exception to these trends is the hole of goethite, which according to our calculations does not form a localised polaron

Brand Names as Keywords in Sponsored Search Advertising

The business models of major Web search engines depend on online advertising, primarily in the form of keyword advertising. In recent years, a controversy has gained notoriety worldwide, in both the international court systems and the media. It concerns a form of potential “bait and switch” advertising where a consumer, searching using the brand name of one company, is presented with an advertisement by a competitor of the searched-for brand. We refer to this practice as “piggybacking.” In the U.S. in particular, the legality of this practice, and the potential liability of the search engines for contributing to trademark infringement, is unclear. However, the eventual resolutions of the issue could significantly and negatively impact the business model of Internet search engines. In this paper, we investigate the actual prevalence of piggybacking of major brands in U.S. search engines. We submitted 100 search queries consisting of top global brand names to three major search engines. Analysis of 2,350 advertisements from search engine results pages showed that just 4 percent were triggered by competitors’ trademarked terms. There was even lower use of those trademark terms in the ad text. Thus, overall competitive piggybacking does not appear to be a deceptive or widespread phenomenon. Implications for this are discussed, and suggestions for future research are presented

Dynamics below the depinning threshold

We study the steady-state low-temperature dynamics of an elastic line in a disordered medium below the depinning threshold. Analogously to the equilibrium dynamics, in the limit T->0, the steady state is dominated by a single configuration which is occupied with probability one. We develop an exact algorithm to target this dominant configuration and to analyze its geometrical properties as a function of the driving force. The roughness exponent of the line at large scales is identical to the one at depinning. No length scale diverges in the steady state regime as the depinning threshold is approached from below. We do find, a divergent length, but it is associated only with the transient relaxation between metastable states.Comment: 4 pages, 3 figure