Geochemical, Isotopic and Single Crystal 40Ar/39Ar Age Constraints on the Evolution of the Cerro Galan Ignimbrites

The giant ignimbrites that erupted from the Cerro Galan caldera complex in the southern Puna of the high Andean plateau are considered to be linked to crustal and mantle melting as a consequence of delamination of gravitationally unstable thickened crust and mantle lithosphere over a steepening subduction zone. Major and trace element analyses of Cerro Galan ignimbrites (68-71% SiO2) that include 65 new analyses can be interpreted by evolution at three crustal levels. AFC modeling and new fractionation corrected d18O values from quartz (+7.63-8.85%o) are consistent with the ignimbrite magmas being near 50:50 mixtures of enriched mantle (87Sr/86Sr ~ 0.7055) and crustal melts (87Sr/86Sr near 0.715-0.735). Processes at lower crustal levels are predicated on steep heavy REE patterns (Sm/Yb = 4-7), high Sr contents (>250 ppm) and very low Nb/Ta (9-5) ratios, which are attributed to amphibolite partial melts mixing with fractionating mantle basalts to produces hybrid melt that rise leaving a gravitationally unstable garnet-bearing residue. Processes at mid crustal levels create large negative Eu anomalies (Eu/Eu* = 0.45-0.70) and variable trace element enrichment in a crystallizing mush zone with a temperature near 800-850ºC The mush zone was repeatedly recharged from depth and partially evacuated into upper crustal magma chambers at times of regional contraction. Crystallinity differences in the ignimbrites are attributed to biotite, zoned plagioclase and other antecrysts entering higher level chambers where variable amounts of near-eutectic crystallization occurs at temperature as low as 680ºC just preceding eruption. 40Ar/39Ar single crystal sanidine weighted mean plateau and isochron ages combined with trace element patterns show that the Galan ignimbrite erupted in more than one batch including a ~ 2.13 Ma intracaldera flow and outflows to the west and north at near 2.09 and 2.06 Ma. Episodic delamination of gravitationally unstable lower crust and mantle lithosphere and injection of basaltic magmas whose changing chemistry reflects their evolution over a steepening subduction zone could trigger the eruptions of the Cerro Galan ignimbrites.Fil: Kay, Suzanne Mahlburg. Cornell University; Estados UnidosFil: Coira, Beatriz Lidia Luisa. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Wörner, Gerhard. Universität Göttingen; AlemaniaFil: Kay, Robert W.. Cornell University; Estados UnidosFil: Singer, Bradley S.. University of Wisconsin; Estados Unido

Converting Fontan-Björk to 1.5- or 2-ventricle circulation

Patients with tricuspid atresia and ventricular septal defect have in the past occasionally undergone a Fontan with “Björk” modification to create a connection between the right atrium and the right ventricular outflow tract. While rarely performed now, patients with this physiology often face severe complications requiring re-intervention. We hypothesize that surgical conversion to a 2-ventricle or 1.5-ventricle circulation can improve hemodynamics, clinical status, and thus increase time to transplant. We present two successful cases to illustrate this idea

Historical-institutionalist perspectives on the development of the EU budget system

The EU budget has only recently started to feature in theories of European integration. Studies typically adopt a historical-institutionalist framework, exploring notions such as path dependency. They have, however, generally been rather aggregated, or coarse-grained, in their approach. The EU budget has thus been treated as a single entity rather than a series of inter-linked institutions. This paper seeks to address these lacunae by adopting a fine-grained approach. This enables us to emphasize the connections that exist between EU budgetary institutions, in both time and space. We show that the initial set of budgetary institutions was unable, over time, to achieve consistently their treaty-based objectives. In response, rather than reform these institutions at potentially high political cost, additional institutions were layered on top of the extant structures. We thus demonstrate how some EU budgetary institutions have remained unchanged, whilst others have been added or changed over time

Effect of hydrofracking fluid on colloid transport in the unsaturated zone

Hydraulic fracturing is expanding rapidly in the US to meet increasing energy demand and requires high volumes of hydrofracking fluid to displace natural gas from shale. Accidental spills and deliberate land application of hydrofracking fluids, which return to the surface during hydrofracking, are common causes of environmental contamination. Since the chemistry of hydrofracking fluids favors transport of colloids and mineral particles through rock cracks, it may also facilitate transport of in situ colloids and associated pollutants in unsaturated soils. We investigated this by subsequently injecting deionized water and flowback fluid at increasing flow rates into unsaturated sand columns containing colloids. Colloid retention and mobilization was measured in the column effluent and visualized in situ with bright field microscopy. While <5% of initial colloids were released by flushing with deionized water, 32–36% were released by flushing with flowback fluid in two distinct breakthrough peaks. These peaks resulted from 1) surface tension reduction and steric repulsion and 2) slow kinetic disaggregation of colloid flocs. Increasing the flow rate of the flowback fluid mobilized an additional 36% of colloids, due to the expansion of water filled pore space. This study suggests that hydrofracking fluid may also indirectly contaminate groundwater by remobilizing existing colloidal pollutants

UV Imaging Polarimetry of the Seyfert 2 Galaxy Mrk 3

We present UV imaging polarimetry data of the Seyfert 2 galaxy Mrk 3 taken by the Hubble Space Telescope. The polarized flux is found to be extended to ~1 kpc from the nucleus, and the position angles of polarization are centrosymmetric, confirming that the polarization is caused by scattering. We determine the location of the hidden nucleus as the center of this centrosymmetric pattern. From the polarization images taken in two broad bands, we have obtained the color distribution of the polarized flux. Some regions have blue polarized flux, consistent with optically-thin dust scattering, but some bright knots have a color similar to that of Seyfert 1 nucleus. Also, the recent Chandra X-ray observation suggests that the ratio of scattered UV flux to scattered X-ray flux is rather similar to the intrinsic UV/X-ray ratio in a Seyfert 1 nucleus, if the observed extended X-ray continuum is scattered light. While the scattered X-ray would be essentially from electron scattering, the UV slope and UV/X-ray ratio both being similar to Seyfert 1's would lead to two possibilities as to the nature of the UV scatterers. One is that the UV may also be scattered by electrons, in which case the scattering gas is somehow dust-free. The other is that the UV is scattered by dust grains, but the wavelength-independent UV scattering with low efficiency indicated by the UV slope and UV/X-ray ratio would suggest that the grains reside in UV-opaque clouds, or the dust might be mainly composed of large grains and lacks small-grain population.Comment: 15 pages, 8 figures (plus 2 color versions of grayscale figures), To appear in ApJ; minor corrections for the proofs of the manuscrip

Framing Photovoice Using a Social---Ecological Logic Model as a Guide.

Photovoice is a community-based participatory action research method designed to uncover the root causes of community problems and to collectively address them. Individual change and empowerment are desired outcomes of the photovoice process, but more importantly, the process seeks to engage groups and whole communities to foster positive systems change. This article presents a logic model informed by the social-ecological model of health to guide photovoice planners and participants in planning activities that produce individual-and community-level change. The model presented here should help planners and participants plan, implement, and evaluate other photovoice efforts and provide them a visual guide to ensure that all parties are on the same conceptual page and increase the intentionality of their efforts

Resilience of Vietnamese Refugees: Resources to Cope with Natural Disasters in Their Resettled Country

Objective: Study findings suggest that refugees are more vulnerable than the general population to mental disorders from disasters. This pilot study explored the nature of Vietnamese refugees’ resilience to a potential natural disaster as a first step toward improving their disaster mental health.Methods: Interviews were conducted with 20 ethnic Vietnamese and Montagnard adult refugees using a semistructured interview guide. Factors in resilience at both individual and family levels were examined.Results: Our results indicated that these refugees had positive personalities and strong family cohesion. However, although a majority of the participants had experienced natural disasters, they lacked knowledge and specific strategies to cope with these events. The individual participants and their families lacked sufficient information, financial resources, emergency supplies, or social support for a natural disaster.Conclusions: Enhancing refugees’ current strengths in responding to disasters, delivering them tailored emergency training, strengthening relationships between refugee service providers and refugee communities, and advocating for refugees’ socioeconomic capacity building should be considered