Diacetyl in Australian dry red wines and its significance in wine quality

The diacetyl content of 466 Australian dry red table wines ranged from less than 0.1 ppm to 7.5 ppm with a mean of 2.4 ppm. Malo-lactic fermentation had occurred in 71 per cent of the wines, which had a mean diacetyl level of 2.8 ppm. In wines which had not undergone malo-lactic fermentation the mean diacetyl level 1.3 ppm.Taste threshold tests showed that a difference of as little as 1 ppm could be detected in a light dry red wine containing 0.3 ppm diacetyl. In a full flavoured darker wine of higher quality containing 3 ppm the minimum detectable addition was 1.3 ppm.It is considered that diacetyl in amounts up to 2 to 4 ppm, depending on the wine, improved quality by adding complexity to the flavour. Above these levels the aroma of diacetyl became identifiable as such and resulted in a reduction in quality. The diacetyl content of a range of red table wines stored at 15° C showed a mean decrease of 19 per cent in diacetyl content in 4 months, 22 per cent in 8 months, 26 per cent in 12 months and 28 per c ent in 18 months

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Direct Experimental Observation of in situ Dehydrogenation of an Amine-Borane System Using Gas Electron Diffraction

In situ dehydrogenation of azetidine-BH3, which is a candidate for hydrogen storage, was observed with the parent and dehydrogenated analogue subjected to rigorous structural and thermochemical investigations. The structural analyses utilized gas electron diffraction supported by high-level quantum calculations, while the pathway for the unimolecular hydrogen release reaction in the absence and presence of BH3 as a bifunctional catalyst was predicted at the CBS-QB3 level. The catalyzed dehydrogenation pathway has a barrier lower than the predicted B-N bond dissociation energy, hence favoring the dehydrogenation process over the dissociation of the complex. The predicted enthalpy of dehydrogenation at the CCSD(T)/CBS level indicates that mild reaction conditions would be required for hydrogen release and that the compound is closer to thermoneutral than linear amine boranes. The entropy and free energy change for the dehydrogenation process show that the reaction is exergonic, energetically feasible, and will proceed spontaneously toward hydrogen release, all of which are important factors for hydrogen storage

Control of framework interpenetration for in situ modified hydroxyl functionalised IRMOFs

Accepted for publication 31st August 2012By intimate control of reaction conditions, phase-pure crystalline porous metal-organic framework materials [Zn(4)O(L)(3)] with interpenetrated and non-interpenetrated structures can be synthesised. Under certain conditions, these reactions occur with concomitant deprotection of masked alcohols located on the organic links which yield accessible 'metal-binding' functional groups within the frameworks.Damien Rankine, Antonio Avellaneda, Matthew R. Hill, Christian J. Doonan, and Christopher J. Sumb

Ecology, ontology and pedagogy at Camp Coorong

No abstract available

Diffusion Tensor Imaging for Diagnosing Root Avulsions in Traumatic Adult Brachial Plexus Injuries: A Proof-of-Concept Study

Cross-sectional MRI has modest diagnostic accuracy for diagnosing traumatic brachial plexus root avulsions. Consequently, patients either undergo major exploratory surgery or months of surveillance to determine if and what nerve reconstruction is needed. This study aimed to develop a diffusion tensor imaging (DTI) protocol at 3 Tesla to visualize normal roots and identify traumatic root avulsions of the brachial plexus. Seven healthy adults and 12 adults with known (operatively explored) unilateral traumatic brachial plexus root avulsions were scanned. DTI was acquired using a single-shot echo-planar imaging sequence at 3 Tesla. The brachial plexus was visualized by deterministic tractography. Fractional anisotropy (FA) and mean diffusivity (MD) were calculated for injured and avulsed roots in the lateral recesses of the vertebral foramen. Compared to healthy nerves roots, the FA of avulsed nerve roots was lower (mean difference 0.1 [95% CI 0.07, 0.13]; p < 0.001) and the MD was greater (mean difference 0.32 × 10−3 mm2/s [95% CI 0.11, 0.53]; p < 0.001). Deterministic tractography reconstructed both normal roots and root avulsions of the brachial plexus; the negative-predictive value for at least one root avulsion was 100% (95% CI 78, 100). Therefore, DTI might help visualize both normal and injured roots of the brachial plexus aided by tractography. The precision of this technique and how it relates to neural microstructure will be further investigated in a prospective diagnostic accuracy study of patients with acute brachial plexus injuries

On the particle paths and the stagnation points in small-amplitude deep-water waves

In order to obtain quite precise information about the shape of the particle paths below small-amplitude gravity waves travelling on irrotational deep water, analytic solutions of the nonlinear differential equation system describing the particle motion are provided. All these solutions are not closed curves. Some particle trajectories are peakon-like, others can be expressed with the aid of the Jacobi elliptic functions or with the aid of the hyperelliptic functions. Remarks on the stagnation points of the small-amplitude irrotational deep-water waves are also made.Comment: to appear in J. Math. Fluid Mech. arXiv admin note: text overlap with arXiv:1106.382

Chelation-driven fluorescence deactivation in three alkali earth metal MOFs containing 2,2’-dihydroxybiphenyl-4,4’-dicarboxylate

First published online 04 Sep 2013Three new metal-organic frameworks (MOFs) have been synthesised from alkali earth metal ions of increasing ionic radii (Mg, Ca and Sr) and 2,2’-dihydroxybiphenyl-4,4’-dicarboxylic acid (H4diol). The distinct coordination environments, framework topologies and the non-coordinated diol moieties accessed are a result of using differently sized metal ions for MOF synthesis which affects the ability of the diol moieties to chelate the metal. Detailed structural analysis of [Sr3(H2diol)3(DMF)5], [Ca3.5(Hdiol)(H2diol)2(DMF)5] and [Mg(H2diol)(DMF)2] show distinctive variations in variable temperature expansion/contraction properties and porosity. In addition, [Sr3(H2diol)3(DMF)5] and [Ca3.5(Hdiol)(H2diol)2(DMF)5] display a broad fluorescence emission (λmax = ~435 nm) under ultraviolet light due to the presence of non-coordinated biphenyl-diol moieties within the structures, while chelation of Mg by the diol pocket in [Mg(H2diol)(DMF)2] leads to quenching of the ligand fluorescence.Damien Rankine, Tony D. Keene, Christopher J. Sumby and Christian J. Doona

Volatile and thermally stable polymeric tin trifluoroacetates

Tin trifluoroacetates are effective vapor phase single-source precursors for F-doped SnO2, but their structures have been poorly understood for decades. Here we undertook a comprehensive structural analysis of these compounds in both the solid and gas phases through a combined single-crystal X-ray crystallography, gas phase electron diffraction, and density functional theory investigation. Tin(II) bis(trifluoroacetate) (1) thermally decomposes into a 1:1 mixture of 1 and ditin(II) μ-oxybis(μ-trifluoroacetate) (2) during sublimation, which then polymerize into hexatin(II)-di-μ3-oxyoctakis(μ-trifluoroacetate) (3) upon solidification. Reversible depolymerization occurred readily upon heating, making 3 a useful vapor phase precursor itself. Tin(IV) tetrakis(trifluoroacetate) (5) was also found to be polymeric in the solid state, but it evaporated as a monomer over 130 °C lower than 3. This counterintuitive improvement in volatility by polymerization was possibly due to the large entropy change during sublimation, which offers a strategic new design feature for vapor phase deposition precursors

Comparison between methods for creating DEMs of physical models

Within physical modelling, it is often necessary to create DEMs (digital elevation models) when testing the stability of rock structures or the filter layers and scour protection around foundations and other marine structures. These DEMs are used to detect changes in the position of the structure or surrounding protective material. Several methods are available to create these models, yet no one technique has been selected as an industry standard. A comparison between three widely used methods – terrestrial laser scanner (TLS), combined laser scanner (CLS) and structure from motion (SfM) – are presented within this paper. The CLS in underwater mode gave low measurement errors and can be deployed without having to drain the facility but requires a traverser system. An area of approximately 7 m by 4 m can be measured in half an hour. The TLS can survey a much larger area in the same time, but requires the facility to be drained. SfM is cheapest method, but struggles to create a full shape and more care must be taken. The CLS in underwater mode has been chosen for use in scour studies in the Fast Flow Facility, with high volumes of water but a relatively limited area