Effect of hydrogen ions and inorganic complexing on the uptake of copper by the brine shrimp <i>Artemia franciscana</i>

The effect of hydrogen ions and inorganic complexing on copper uptake in the brine shrimp Artemia franciscana has been studied in chemically defined saltwater solutions. Uptake increases with decreasing hydrogen ion concentration and decreases with increasing carbonate complexation. A simple non-linear model that combines the effect of hydrogen ions on the transport of the metal across the solution-body interface and the effect of hydrogen ions and complexation on the speciation of the metal provided a close functional description of the observed variation in copper uptake by brine shrimp

Studies of the use of high-temperature nuclear heat from an HTGR for hydrogen production

The results of a study which surveyed various methods of hydrogen production using nuclear and fossil energy are presented. A description of these methods is provided, and efficiencies are calculated for each case. The process designs of systems that utilize the heat from a general atomic high temperature gas cooled reactor with a steam methane reformer and feed the reformer with substitute natural gas manufactured from coal, using reforming temperatures, are presented. The capital costs for these systems and the resultant hydrogen production price for these cases are discussed along with a research and development program

Signatures of electron-boson coupling in half-metallic ferromagnet Mn5_5Ge3_3: study of electron self-energy Σ(ω)\Sigma(\omega) obtained from infrared spectroscopy

We report results of our infrared and optical spectroscopy study of a half-metallic ferromagnet Mn$_5$Ge$_3$. This compound is currently being investigated as a potential injector of spin polarized currents into germanium. Infrared measurements have been performed over a broad frequency (50 - 50000 cm$^{-1}$) and temperature (10 - 300 K) range. From the complex optical conductivity $\sigma(\omega)$ we extract the electron self-energy $\Sigma(\omega)$. The calculation of $\Sigma(\omega)$ is based on novel numerical algorithms for solution of systems of non-linear equations. The obtained self-energy provides a new insight into electron correlations in Mn$_5$Ge$_3$. In particular, it reveals that charge carriers may be coupled to bosonic modes, possibly of magnetic origin

Diluted Random Fields in Mixed Cyanide Crystals

A percolation argument and a dilute compressible random field Ising model are used to present a simple model for mixed cyanide crystals. The model reproduces quantitatively several features of the phase diagrams altough some crude approximations are made. In particular critical thresholds x_c at which ferroelastic first order transitions disappear, are calculated. Moreover, transitions are found to remain first order down to x_c for all mixtures except for bromine, for which the transition becomes continuous. All the results are in full agreement with experimental data.Comment: 8 pages, late

Hybrid expansions for local structural relaxations

A model is constructed in which pair potentials are combined with the cluster expansion method in order to better describe the energetics of structurally relaxed substitutional alloys. The effect of structural relaxations away from the ideal crystal positions, and the effect of ordering is described by interatomic-distance dependent pair potentials, while more subtle configurational aspects associated with correlations of three- and more sites are described purely within the cluster expansion formalism. Implementation of such a hybrid expansion in the context of the cluster variation method or Monte Carlo method gives improved ability to model phase stability in alloys from first-principles.Comment: 8 pages, 1 figur

Multiwavelength Observations of the Hot DB Star PG 0112+104

We present a comprehensive multiwavelength analysis of the hot DB white dwarf PG 0112+104. Our analysis relies on newly-acquired FUSE observations, on medium-resolution FOS and GHRS data, on archival high-resolution GHRS observations, on optical spectrophotometry both in the blue and around Halpha, as well as on time-resolved photometry. From the optical data, we derive a self-consistent effective temperature of 31,300+-500 K, a surface gravity of log g = 7.8 +- 0.1 (M=0.52 Msun), and a hydrogen abundance of log N(H)/N(He) < -4.0. The FUSE spectra reveal the presence of CII and CIII lines that complement the previous detection of CII transitions with the GHRS. The improved carbon abundance in this hot object is log N(C)/N(He) = -6.15 +- 0.23. No photospheric features associated with other heavy elements are detected. We reconsider the role of PG 0112+104 in the definition of the blue edge of the V777 Her instability strip in light of our high-speed photometry, and contrast our results with those of previous observations carried out at the McDonald Observatory.Comment: 10 pages in emulateapj, 9 figures, accepted for publication in Ap

Hot DAVs : a probable new class of pulsating white dwarf stars

We have discovered a pulsating DA white dwarf at the lower end of the temperature range 45 000–30 000 K where a few helium atmosphere white dwarfs are known. There are now three such pulsators known, suggesting that a new class of theoretically predicted pulsating white dwarf stars exists. We name them the hot DAV stars. From high-speed photometric observations with the ULTRACAM photometer on the 4.2-m William Herschel Telescope, we show that the hydrogen atmosphere white dwarf star WD1017−138 pulsates in at least one mode with a frequency of 1.62 mHz (a period of 624 s). The amplitude of that mode was near 1 mmag at a 10σ confidence level on one night of observation and an 8.4σ confidence level on a second night. The combined data have a confidence level of 11.8σ. This supports the two other detections of hot DAV stars previously reported. From three Very Large Telescope Ultraviolet and Visual Echelle Spectrograph spectra we confirm also that WD1017−138 is a hydrogen atmosphere white dwarf with no trace of helium or metals with Teff = 32 600 K, log g = 7.8 (cgs) and M = 0.55 M⊙. The existence of pulsations in these DA white dwarfs at the cool edge of the 45 000–30 000 K temperature range supports the thin hydrogen layer model for the deficit of helium atmosphere white dwarfs in this range. DA white dwarfs with thick hydrogen layers do not have the superadiabatic, chemically inhomogeneous (μ-gradient) zone that drives pulsation in this temperature range. The potential for higher amplitude hot DAV stars exists; their discovery would open the possibility of a direct test of the explanation for the deficit of helium atmosphere white dwarfs at these temperatures by asteroseismic probing of the atmospheric layers of the hot DAV stars. A search for pulsation in a further 22 candidates with ULTRACAM on the European Southern Observatory New Technology Telescope gave null results for pulsation at precisions in the range 0.5–3 mmag, suggesting that the pulsation amplitudes in such stars are relatively low, hence near the detection limit with the ground-based telescopes used in the surve

A 4-unit-cell superstructure in optimally doped YBa2Cu3O6.92 superconductor

Using high-energy diffraction we show that a 4-unit-cell superstructure, q0=(1/4,0,0), along the shorter Cu-Cu bonds coexists with superconductivity in optimally doped YBCO. A complex set of anisotropic atomic displacements on neighboring CuO chain planes, BaO planes, and CuO2 planes, respectively, correlated over ~3-6 unit cells gives rise to diffuse superlattice peaks. Our observations are consistent with the presence of Ortho-IV nanodomains containing these displacements.Comment: Corrected typo in abstrac

Lattice-gas model for alkali-metal fullerides: face-centered-cubic structure

A lattice-gas model is suggested for describing the ordering phenomena in alkali-metal fullerides of face-centered-cubic structure assuming the electric charge of alkali ions residing in either octahedral or tetrahedral interstitial sites is completely screened by the first-neighbor C_60 molecules. This approximation allows us to derive an effective ion-ion interaction. The van der Waals interaction between the ion and C_60 molecule is characterized by introducing an additional energy at the tetrahedral sites. This model is investigated by using a three-sublattice mean-field approximation and a simple cluster-variation method. The analysis shows a large variety of phase diagrams when changing the site energy parameter.Comment: 10 twocolumn pages (REVTEX) including 12 PS figure

On a Conjecture of Rapoport and Zink

In their book Rapoport and Zink constructed rigid analytic period spaces $F^{wa}$ for Fontaine's filtered isocrystals, and period morphisms from PEL moduli spaces of $p$-divisible groups to some of these period spaces. They conjectured the existence of an \'etale bijective morphism $F^a \to F^{wa}$ of rigid analytic spaces and of a universal local system of $Q_p$-vector spaces on $F^a$. For Hodge-Tate weights $n-1$ and $n$ we construct in this article an intrinsic Berkovich open subspace $F^0$ of $F^{wa}$ and the universal local system on $F^0$. We conjecture that the rigid-analytic space associated with $F^0$ is the maximal possible $F^a$, and that $F^0$ is connected. We give evidence for these conjectures and we show that for those period spaces possessing PEL period morphisms, $F^0$ equals the image of the period morphism. Then our local system is the rational Tate module of the universal $p$-divisible group and enjoys additional functoriality properties. We show that only in exceptional cases $F^0$ equals all of $F^{wa}$ and when the Shimura group is $GL_n$ we determine all these cases.Comment: v2: 48 pages; many new results added, v3: final version that will appear in Inventiones Mathematica