1,427 research outputs found
Line Shape Broadening in Surface Diffusion of Interacting Adsorbates with Quasielastic He Atom Scattering
The experimental line shape broadening observed in adsorbate diffusion on
metal surfaces with increasing coverage is usually related to the nature of the
adsorbate-adsorbate interaction. Here we show that this broadening can also be
understood in terms of a fully stochastic model just considering two noise
sources: (i) a Gaussian white noise accounting for the surface friction, and
(ii) a shot noise replacing the physical adsorbate-adsorbate interaction
potential. Furthermore, contrary to what could be expected, for relatively weak
adsorbate-substrate interactions the opposite effect is predicted: line shapes
get narrower with increasing coverage.Comment: 4 pages, 2 figures (slightly revised version
Quasi-elastic peak lineshapes in adsorbate diffusion on nearly flat surfaces at low coverages: the motional narrowing effect in Xe on Pt(111)
Quasi-elastic helium atom scattering measurements have provided clear
evidence for a two-dimensional free gas of Xe atoms on Pt(111) at low
coverages. Increasing the friction due to the surface, a gradual change of the
shape of the quasi-elastic peak is predicted and analyzed for this system in
terms of the so-called motional narrowing effect. The type of analysis
presented here for the quasi-elastic peak should be prior to any deconvolution
procedure carried out in order to better extract information from the process,
e.g. diffusion coefficients and jump distributions. Moreover, this analysis
also provides conditions for the free gas regime different than those reported
earlier.Comment: 12 pages, 4 figures (revised version
A generalized Chudley-Elliott vibration-jump model in activated atom surface diffusion
Here the authors provide a generalized Chudley-Elliott expression for
activated atom surface diffusion which takes into account the coupling between
both low-frequency vibrational motion (namely, the frustrated translational
modes) and diffusion. This expression is derived within the Gaussian
approximation framework for the intermediate scattering function at low
coverage. Moreover, inelastic contributions (arising from creation and
annihilation processes) to the full width at half maximum of the quasi-elastic
peak are also obtained.Comment: (5 pages, 2 figures; revised version
Quantum Zeno and anti-Zeno effects in surface diffusion of interacting adsorbates
Surface diffusion of interacting adsorbates is here analyzed within the
context of two fundamental phenomena of quantum dynamics, namely the quantum
Zeno effect and the anti-Zeno effect. The physical implications of these
effects are introduced here in a rather simple and general manner within the
framework of non-selective measurements and for two (surface) temperature
regimes: high and very low (including zero temperature). The quantum
intermediate scattering function describing the adsorbate diffusion process is
then evaluated for flat surfaces, since it is fully analytical in this case.
Finally, a generalization to corrugated surfaces is also discussed. In this
regard, it is found that, considering a Markovian framework and high surface
temperatures, the anti-Zeno effect has already been observed, though not
recognized as such.Comment: 17 pages, 1 figur
Tectonic implications of paleontologic dating of Cretaceous-Danian sections of Eastern Cuba
The sedimentary rocks intercalated in volcanic and metavolcanic sections of MayarÃ-Baracoa and Sierra del Purial Mountains (Eastern Cuba), yielded Cretaceous through Danian microfossils. In the Mayarà Mountains the Téneme Fm consists of basalts and hyaloclastites with minor intercalations of well-bedded foliated limestone and shaly limestone that in the type area contain a Turonian or early Coniacian planktonic foraminifera assemblage. In the Morel area (Moa-Baracoa massif), back-arc pillow basalts with ribbon cherts include a late Turonian or Coniacian limestone bed intercalated with interbedded organic-rich calcareous shales near the top. The upper part of the Coniacian (?)-Campanian Santo Domingo Fm crops out west of Moa and it consists of finegrained well-bedded volcaniclastic rocks with two intercalated lenses of coarse-grained impure biocalcirudites to biocalcarenites. These rocks yielded a mixed penecontemporaneous planktonic and benthonic microfossil assemblage attributed to the lower part of the late Campanian (Globotruncanita calcarata Zone). At Sierra del Purial, crystalline limestones embedded within the metavulcano-sedimentary RÃo Baracoa section (Purial metamorphic complex) yielded Campanian microfossils. The Maastrichtian Yaguaneque (=Cañas) limestones crop out extensively in both MayarÃ-Baracoa and Purial Mountains. All the formations previously mentioned unconformably overlie and tectonically intermingle with the late Maastrichtian-early Danian clastic rocks of the MÃcara and La Picota Fms. Our new dates demonstrate that in the Greater Antilles the PIA (Primitive Island Arc-tholeiite) recorded by the Téneme Fm would be Late Cretaceous in age in opposition to the Lower Cretaceous age proposed for the PIA basalts. The protolith of the Purial metamorphic complex is probably Maastrichtian-early Danian, but certainly Campanian and older in age. This fact suggests that the metamorphism that affected the Purial rocks took place probably in the late Maastrichtian and was coeval with the detachment, exhumation and emplacement of mafic-ultramafic thrust-sheet bodies. This event recorded in Eastern Cuba/Western Hispaniola and Guatemala might have been related to the insertion of thick oceanic ridges into the subduction zone
New non-unitary representations in a Dirac hydrogen atom
New non-unitary representations of the SU(2) algebra are introduced for the
case of the Dirac equation with a Coulomb potential; an extra phase, needed to
close the algebra, is also introduced. The new representations does not require
integer or half integer labels. The set of operators defined are used to span
the complete space of bound state eigenstates of the problem thus solving it in
an essentially algebraic way
Spin configuration in a frustrated ferromagnetic/antiferromagnetic thin film system
We have studied the magnetic configuration in ultrathin antiferromagnetic Mn
films grown around monoatomic steps on an Fe(001) surface by spin-polarized
scanning tunneling microscopy/spectroscopy and ab-initio-parametrized
self-consistent real-space tight binding calculations in which the spin
quantization axis is independent for each site thus allowing noncollinear
magnetism. Mn grown on Fe(001) presents a layered antiferromagnetic structure.
In the regions where the Mn films overgrows Fe steps the magnetization of the
surface layer is reversed across the steps. Around these defects a frustration
of the antiferromagnetic order occurs. Due to the weakened magnetic coupling at
the central Mn layers, the amount of frustration is smaller than in Cr and the
width of the wall induced by the step does not change with the thickness, at
least for coverages up to seven monolayers.Comment: 10 pages, 5 figure
Polarimetry of an Intermediate-age Open Cluster: NGC 5617
We present polarimetric observations in the UBVRI bands of 72 stars located
in the direction of the medium age open cluster NGC 5617. Our intention is to
use polarimetry as a tool membership identification, by building on previous
investigations intended mainly to determine the cluster's general
characteristics rather than provide membership suitable for studies such as
stellar content and metallicity, as well as study the characteristics of the
dust lying between the Sun and the cluster. The obsevations were carried out
using the five-channel photopolarimeter of the Torino Astronomical Observatory
attached to the 2.15m telescope at the Complejo Astron\'omico El Leoncito
(CASLEO; Argentina. We are able to add 32 stars to the list of members of NGC
5617, and review the situation for others listed in the literature. In
particular, we find that five blue straggler stars in the region of the cluster
are located behind the same dust as the member stars are and we confirm the
membership of two red giants. The proposed polarimetric memberships are
compared with those derived by photometric and kinematical methods, with
excellent results. Among the observed stars, we identify 10 with intrinsic
polarization in their light. NGC 5617 can be polarimetrically characterized
with and . The spread in polarization
values for the stars observed in the direction of the cluster seems to be
caused by the uneven distribution of dust in front of the cluster's face.
Finally, we find that in the direction of the cluster, the interstellar medium
is apparently free of dust, from the Sun's position up to the
Carina-Sagittarius arm, where NGC 5617 seems to be located at its farthest
border
Geochemical and geochronological constraints on the geologic evolution of the western Sonobari Complex, northwestern Mexico
In the southern Sierra Sonobari, NW Mexico, U-Pb and 40Ar/39Ar geochronology studies allowed to define the provenance and maximum depositional age of the Francisco Gneiss basement of the Sonobari terrane, and to establish the age of some magmatic events in that area. The youngest zircon cluster in paragneisses of the Francisco Gneiss indicates a maximum depositional age of 509 ± 29Ma. The main peaks of the relative probability plot yield ages of 1690 and 1404Ma with minor peaks at 1156, 921, and 517Ma. Major peaks suggest that the main source of sediments was the Paleo- and Mesoproterozoic crust of Laurentia. Orthogneiss from the Francisco Gneiss yields a U-Pb zircon upper intercept age of 248 ± 28Ma, which is interpreted as the crystallization age. Crosscutting dykes of metabasite yield an 40Ar/39Ar age of 67 ± 5Ma, which is interpreted as indicating cooling after either a latest Early Cretaceous orogenic event or Late Cretaceous contact metamorphism. Granodiorite intruding the Francisco Gneiss yields a U-Pb age of 64 ± 1Ma, which is interpreted as a magmatic age. The hornblende-plagioclase Macochin Gabbro yields 40Ar/39Ar isochron ages of 54 ± 10Ma and 47 ± 5Ma, which are interpreted as cooling ages after the gabbro intrusion. Geochemical data indicate that the mafic rocks of the Francisco Gneiss correspond to subalkaline basalts of tholeiitic affinity with concentrations of high field strength elements similar to oceanic basalts, suggesting an asthenospheric upper mantle source. However, according to the variation in Th/Yb and U/Yb, the amphibolites display a significant influence of the upper continental crust. The Macochin Gabbro also has a geochemical signature characteristic of subalkaline basalt with tholeiitic affinity, and high field strength elements similar to oceanic basalts. Tectonic discrimination diagrams and elemental distribution suggest that the mafic rocks of both the Francisco Gneiss and Macochin Gabbro were emplaced during rifting in a back-arc setting
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