99 research outputs found

    Proposal for creating a centre for research in solar-terrestrial physics as an interdepartmental activity during IHY at Shivaji University, Kolhapur (16.40°N, 74.15°E)

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    This note describes teaching and R & D activities presently being carried out in the solar-terrestrial Physics at the Space Science laboratory, Department of Physics, Shivaji University, Kolhapur. A variety of solar and geophysical ground based experiments are available, which can be operated on a regular basis during IHY, with financial help from the government funding agencies in India. The main purpose of this note is to briefly describe our experimental research facilities of relevance to IHY

    Photoelectrochemical properties of mesoporous NiOx deposited on technical FTO via nanopowder sintering in conventional and plasma atmospheres

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    Nanoporous nickel oxide (NiO x ) has been deposited with two different procedures of sintering (CS and RDS). Both samples display solid state oxidation at about 3.1 V vs Li+/Li. Upon sensitization of CS/RDS NiO x with erythrosine b (ERY), nickel oxide oxidation occurs at the same potential. Impedance spectroscopy revealed a higher charge transfer resistance for ERY-sensitized RDS NiO x with respect to sensitized CS NiO x . This was due to the chemisorption of a larger amount of ERY on RDS with respect to CS NiO x . Upon illumination the photoinduced charge transfer between ERY layer and NiO x could be observed only with oxidized CS. Photoelectrochemical effects of sensitized RDS NiO x were evidenced upon oxide reduction. With the addition of iodine RDS NiOx electrodes could give the reduction iodine → iodide in addition to the reduction of RDS NiO x . p-type dye sensitized solar cells were assembled with RDS NiO x photocathodes sensitized either by ERY or Fast Green. Resulting overall efficiencies ranged between 0.02 and 0.04 % upon irradiation with solar spectrum simulator (Iin : 0.1 W cm −2 )

    Increasing p-type dye sensitised solar cell photovoltages using polyoxometalates

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    Lindqvist polyoxometalate (POM) additives increase VOC in p-type DSSCs by up to 140%, yielding substantial efficiency gains for poorly matched dyes and redox mediators. For better dye/electrolyte combinations, these gains are typically outweighed by losses in JSC. Charge lifetime and transient IR measurements show that this is due to retardation of both recombination and electron transfer to the mediator, and a positive shift in the NiO valence band edge. The POMs also show their own, limited sensitizing effect

    African Students in India: Patterns of Mobility

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    Buckling and free vibrations behaviour through differential quadrature method for foamed composites

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    The current work focuses on predicting the buckling and free vibration frequencies (fn) of cenosphere reinforced epoxy based syntactic foam beam under varying loads. Critical buckling loads (Ncr) and fn are predicted using the differential quadrature method (DQM). Ncr and fn have been calculated for beams of varying cenosphere volume fractions subjected to axial load under clamped-clamped (CC), clamped-simply (CS), simply-simply (SS), and clamped-free (CF) boundary conditions (BC′s). Upon increasing the cenosphere volume fraction, Ncr and fn of syntactic foam composites increases. These numerical outcomes are compared with the theoretical values evaluated through the Euler-Bernoulli hypothesis and further compared with experimental outcomes. Results are observed to be in precise agreement. The results of the DQM numerical analysis are given out for the different BC′s, aspect ratios, cenosphere volume fractions, and varying loads. It is perceived that depending on the BC′s, the type of axial varying loads and aspect ratios has a substantial effect on the Ncr and fn behaviour of the syntactic foam beams. A comparative study of the obtained results showed that the beam subjected to parabolic load under CC boundary conditions exhibited a higher buckling load. © 2023 The Author
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