433 research outputs found
Expansion Potential for Irrigation within the Mississippi Delta Region
17.6 million acres, or 73 percent, of the Mississippi Delta Region is currently cropland and possesses the physical characteristics of slope, texture and soil type which are recommended for irrigation. Economic feasibility of expanding irrigation by flood, furrow and center pivot methods were examined under 24 scenarios representing two sets of crop prices, yield levels, production costs, opportunity costs and six crop rotations. Irrigation was economically feasible for 56 to 100 percent of the cropland across all scenarios. Approximately 88 percent of the cropland can be economically irrigated with flood or furrow in its present form, 8 percent yield highest net returns if furrow irrigated following land forming and 4 percent can be economically irrigated only with center pivot systems
Interferometric imaging of the sulfur-bearing molecules H2S, SO and CS in comet C/1995 O1 (Hale-Bopp)
We present observations of rotational lines of H2S, SO and CS performed in
comet C/1995 O1 (Hale-Bopp) in March 1997 with the Plateau de Bure
interferometer (IRAM). The observations provide informations on the spatial and
velocity distributions of these molecules. They can be used to constrain their
photodissociation rate and their origin. We use a radiative transfer code which
allows us to compute synthetic line profiles and interferometric maps, to be
compared to the observations. Both single-dish spectra and interferometric
spectral maps show a day/night asymmetry in the outgassing. From the analysis
of the spectral maps, including the astrometry, we show that SO and CS present
in addition a jet-like structure that may be the gaseous counterpart of the
dust high-latitude jet observed in optical images. A CS rotating jet is also
observed. Using the astrometry provided by continuum radio maps obtained in
parallel, we conclude that there is no need to invoke of nongravitational
forces acting on this comet, and provide an updated orbit. The radial extension
of H2S is found to be consistent with direct release from the nucleus. SO
displays an extended radial distribution. Assuming that SO2 is the parent of
SO, the photodissociation rate of SO is measured to be 1.5 E-4 s-1 at 1 AU from
the Sun. This is lower than most laboratory-based estimates and may suggest
that SO is not solely produced by SO2 photolysis. From the observations of
J(2-1) and J(5-4) CS lines, we deduce a CS photodissociation rate of 1 to 5 E-5
s-1. The photodissociation rate of CS2, the likely parent of CS, cannot be
constrained due to insufficient resolution, but our data are consistent with
published values. These observations illustrate the cometary science that will
be performed with the future ALMA interferometer.Comment: Accepted for publication in Astronomy & Astrophysic
Searches for HCl and HF in comets 103P/Hartley 2 and C/2009 P1 (Garradd) with the Herschel space observatory
HCl and HF are expected to be the main reservoirs of fluorine and chlorine
wherever hydrogen is predominantly molecular. They are found to be strongly
depleted in dense molecular clouds, suggesting freeze-out onto grains in such
cold environments. We can then expect that HCl and HF were also the major
carriers of Cl and F in the gas and icy phases of the outer solar nebula, and
were incorporated into comets. We aimed to measure the HCl and HF abundances in
cometary ices as they can provide insights on the halogen chemistry in the
early solar nebula. We searched for the J(1-0) lines of HCl and HF at 626 and
1232 GHz, respectively, using the HIFI instrument on board the Herschel Space
Observatory. HCl was searched for in comets 103P/Hartley 2 and C/2009 P1
(Garradd), whereas observations of HF were conducted in comet C/2009 P1. In
addition, observations of HO and HO lines were performed in C/2009
P1 to measure the HO production rate. Three lines of CHOH were
serendipitously observed in the HCl receiver setting. HCl is not detected,
whereas a marginal (3.6-) detection of HF is obtained. The upper limits
for the HCl abundance relative to water are 0.011% and 0.022%, for 103P and
C/2009 P1, respectively, showing that HCl is depleted with respect to the solar
Cl/O abundance by a factor more than 6 in 103P, where the error is
related to the uncertainty in the chlorine solar abundance. The marginal HF
detection obtained in C/2009 P1 corresponds to an HF abundance relative to
water of (1.80.5) 10, which is approximately consistent
with a solar photospheric F/O abundance. The observed depletion of HCl suggests
that HCl was not the main reservoir of chlorine in the regions of the solar
nebula where these comets formed. HF was possibly the main fluorine compound in
the gas phase of the outer solar nebula.Comment: Accepted for publication in Astronomy & Astrophysic
Substrate-Assisted Catalysis Unifies Two Families of Chitinolytic Enzymes
Hen egg-white lysozyme has long been the paradigm for enzymatic glycosyl hydrolysis with retention of configuration, with a protonated carboxylic acid and a deprotonated carboxylate participating in general acid-base catalysis. In marked contrast, the retaining chitin degrading enzymes from glycosyl hydrolase families 18 and 20 all have a single glutamic acid as the catalytic acid but lack a nucleophile on the enzyme. Both families have a catalytic (βα)8-barrel domain in common. X-ray structures of three different chitinolytic enzymes complexed with substrates or inhibitors identify a retaining mechanism involving a protein acid and the carbonyl oxygen atom of the substrate’s C2 N-acetyl group as the nucleophile. These studies unambiguously demonstrate the distortion of the sugar ring toward a sofa conformation, long postulated as being close to that of the transition state in glycosyl hydrolysis.
Herschel observations of EXtra-Ordinary Sources: The Terahertz spectrum of Orion KL seen at high spectral resolution
We present the first high spectral resolution observations of Orion KL in the
frequency ranges 1573.4 - 1702.8 GHz (band 6b) and 1788.4 - 1906.8 GHz (band
7b) obtained using the HIFI instrument on board the Herschel Space Observatory.
We characterize the main emission lines found in the spectrum, which primarily
arise from a range of components associated with Orion KL including the hot
core, but also see widespread emission from components associated with
molecular outflows traced by H2O, SO2, and OH. We find that the density of
observed emission lines is significantly diminished in these bands compared to
lower frequency Herschel/HIFI bands.Comment: Accepted for publication in the Herschel HIFI special issue of
Astronomy and Astrophysics Letters, 5 pages, 3 figure
Optical Lightcurve & Cooling Break of GRB 050502A
We present lightcurves of the afterglow of GRB050502A, including very early
data at t-t_{GRB} < 60s. The lightcurve is composed of unfiltered ROTSE-IIIb
optical observations from 44s to 6h post-burst, R-band MDM observations from
1.6 to 8.4h post-burst, and PAIRITEL J H K_s observations from 0.6 to 2.6h
post-burst. The optical lightcurve is fit by a broken power law, where
t^{alpha} steepens from alpha = -1.13 +- 0.02 to alpha = -1.44 +- 0.02 at
\~5700s. This steepening is consistent with the evolution expected for the
passage of the cooling frequency nu_c through the optical band. Even in our
earliest observation at 44s post-burst, there is no evidence that the optical
flux is brighter than a backward extrapolation of the later power law would
suggest. The observed decay indices and spectral index are consistent with
either an ISM or a Wind fireball model, but slightly favor the ISM
interpretation. The expected spectral index in the ISM interpretation is
consistent within 1 sigma with the observed spectral index beta = -0.8 +- 0.1;
the Wind interpretation would imply a slightly (~2 sigma) shallower spectral
index than observed. A small amount of dust extinction at the source redshift
could steepen an intrinsic spectrum sufficiently to account for the observed
value of beta. In this picture, the early optical decay, with the peak at or
below 4.7e14 Hz at 44s, requires very small electron and magnetic energy
partitions from the fireball.Comment: 22 pages, including 3 tables and 1 figure, Accepted by Ap
Herschel observations of extra-ordinary sources: Detection of Hydrogen Fluoride in absorption towards Orion~KL
We report a detection of the fundamental rotational transition of hydrogen
fluoride in absorption towards Orion KL using Herschel/HIFI. After the removal
of contaminating features associated with common molecules ("weeds"), the HF
spectrum shows a P-Cygni profile, with weak redshifted emission and strong
blue-shifted absorption, associated with the low-velocity molecular outflow. We
derive an estimate of 2.9 x 10^13 cm^-2 for the HF column density responsible
for the broad absorption component. Using our best estimate of the H2 column
density within the low-velocity molecular outflow, we obtain a lower limit of
~1.6 x 10^-10 for the HF abundance relative to hydrogen nuclei, corresponding
to 0.6% of the solar abundance of fluorine. This value is close to that
inferred from previous ISO observations of HF J=2--1 absorption towards Sgr B2,
but is in sharp contrast to the lower limit of 6 x 10^-9 derived by Neufeld et
al. (2010) for cold, foreground clouds on the line of sight towards G10.6-0.4.Comment: 5 pages, 3 figures, paper to be published in the Herschel special
issue of A&A letter
Reversal of infall in SgrB2(M) revealed by Herschel/HIFI observations of HCN lines at THz frequencies
To investigate the accretion and feedback processes in massive star
formation, we analyze the shapes of emission lines from hot molecular cores,
whose asymmetries trace infall and expansion motions. The high-mass star
forming region SgrB2(M) was observed with Herschel/HIFI (HEXOS key project) in
various lines of HCN and its isotopologues, complemented by APEX data. The
observations are compared to spherically symmetric, centrally heated models
with density power-law gradient and different velocity fields (infall or
infall+expansion), using the radiative transfer code RATRAN. The HCN line
profiles are asymmetric, with the emission peak shifting from blue to red with
increasing J and decreasing line opacity (HCN to HCN). This is most
evident in the HCN 12--11 line at 1062 GHz. These line shapes are reproduced by
a model whose velocity field changes from infall in the outer part to expansion
in the inner part. The qualitative reproduction of the HCN lines suggests that
infall dominates in the colder, outer regions, but expansion dominates in the
warmer, inner regions. We are thus witnessing the onset of feedback in massive
star formation, starting to reverse the infall and finally disrupting the whole
molecular cloud. To obtain our result, the THz lines uniquely covered by HIFI
were critically important.Comment: A&A, HIFI special issue, accepte
Herschel observations of deuterated water towards Sgr B2(M)
Observations of HDO are an important complement for studies of water, because
they give strong constraints on the formation processes -- grain surfaces
versus energetic process in the gas phase, e.g. in shocks. The HIFI
observations of multiple transitions of HDO in Sgr~B2(M) presented here allow
the determination of the HDO abundance throughout the envelope, which has not
been possible before with ground-based observations only. The abundance
structure has been modeled with the spherical Monte Carlo radiative transfer
code RATRAN, which also takes radiative pumping by continuum emission from dust
into account. The modeling reveals that the abundance of HDO rises steeply with
temperature from a low abundance () in the outer envelope
at temperatures below 100~K through a medium abundance () in
the inner envelope/outer core, at temperatures between 100 and 200~K, and
finally a high abundance () at temperatures above 200~K in
the hot core.Comment: A&A HIFI special issue, accepte
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