Combustion within Porous Waste

Flammable gases (primarily hydrogen and nitrous oxide but also ammonia and methane) are continuously being generated within the waste contained in the tank farms at Hanford Site. Some portions of the waste are porous and conceivably, a combustion event could occur within the waste due to accidental ignition. This has been postulated as a potential hazard since deflagrations and detonations are observed in laboratory experiments to propagate through combustible gases in porous materials, or through interconnected flammable gas voids. The waste in Hanford storage tanks are mainly in three different forms, a: salt cake, b: sludge, c: supernatant. Formation of a crust layer on the top of the waste is also observed in some tanks. The salt cake waste and crust resemble porous materials while sludge and supernatant looks like highly viscous fluids retaining flammable gas as bubbles or inclusions. Although laboratory experiments showed the possibility of propagation of deflagration or detonation in waste-like porous materials filled by flammable gases, the relevance of this issue to safety evaluations at Hanford is a matter of contention. In order to clarify this issue, we have reviewed the relevant data on laboratory experiments related to combustion in porous material. in doing this, we have concentrated on the flame literature rather than the detonation literature, since Makris et al. (1995) have already examined that. Further, significant mechanisms for the initiation of detonation (i.e., geometries resulting in strong flame acceleration within the dome) have not been identified therefore making flames a much more likely outcome of accidental ignition than detonation. ignition of flammable waste gases in the waste or the dome space of a tank can occur during intrusive operations into the waste or dome. External events which are not foreseeable such as lightning can also ignite the flammable gas retained in the waste. The present report only examines the basic issues in propagation of deflagration or detonation within waste. The process or probability of combustion ignition and other combustion events such as burns in the dome are not considered. After our review of the literature, some simple estimates of the potential for flame and detonation propagation are given. We conclude with a discussion of the uncertainties and measurements required to resolve this issue

Теоретична сутність та складові механізму логістичного управління ресурсним забезпеченням силових структур

Розглянута сутність та визначені складові механізму логістичного управління ресурсним забезпеченням силових структур. Запропоновані показники оцінювання ефективності механізму управління.Considered essence and the constituents of mechanism of logistic management the resource providing of power structures are certain. Offered indexes of evaluation of efficiency of mechanism of management

Sensitivity studies with the regional climate model COSMO-CLM 5.0 over the CORDEX Central Asia Domain

Due to its extension, geography and the presence of several underdeveloped or developing economies, the Central Asia domain of the Coordinated Regional Climate Downscaling Experiment (CORDEX) is one of the most vulnerable regions on Earth to the effects of climate changes. Reliable information on potential future changes with high spatial resolution acquire significant importance for the development of effective adaptation and mitigation strategies for the region. In this context, regional climate models (RCMs) play a fundamental role. In this paper, the results of a set of sensitivity experiments with the regional climate model COSMO-CLM version 5.0, for the Central Asia CORDEX domain, are presented. Starting from a reference model setup, general model performance is evaluated for the present day, testing the effects of singular changes in the model physical configuration and their mutual interaction with the simulation of monthly and seasonal values of three variables that are important for impact studies: near-surface temperature, precipitation and diurnal temperature range. The final goal of this study is two-fold: having a general overview of model performance and its uncertainties for the considered region and determining at the same time an optimal model configuration. Results show that the model presents remarkable deficiencies over different areas of the domain. The combined change of the albedo, taking into consideration the ratio of forest fractions, and the soil conductivity, taking into account the ratio of liquid water and ice in the soil, allows one to achieve the best improvements in model performance in terms of climatological means. Importantly, the model seems to be particularly sensitive to those parameterizations that deal with soil and surface features, and that could positively affect the repartition of incoming radiation. The analyses also show that improvements in model performance are not achievable for all domain subregions and variables, and they are the result of a compensation effect in the different cases. The proposed better performing configuration in terms of mean climate leads to similar positive improvements when considering different observational data sets and boundary data employed to force the simulations. On the other hand, due to the large uncertainties in the variability estimates from observations, the use of different boundaries and the model internal variability, it has not been possible to rank the different simulations according to their representation of the monthly variability. This work is the first ever sensitivity study of an RCM for the CORDEX Central Asia domain and its results are of fundamental importance for further model development and for future climate projections over the area

Precipitation Over Southern Africa: Moisture Sources and Isotopic Composition

Southern Africa, with its vast arid to semiarid areas, is considered vulnerable to precipitation changes and amplifying weather extremes. However, during the last 100 ka, huge lakes existed in the currently dry central Kalahari. It has been suggested that these lakes could have existed due to altered atmospheric circulation pattern, leading to an increase in precipitation or to changes in the annual precipitation distribution. Past climate changes are recorded in paleo-archives, yet, for a proper interpretation of paleo-records, for example, from sedimentological archives or fossils, it is essential to put them in a context with recent observations. This study’s objective is, therefore, to analyze spatially differing annual precipitation distributions at multiple locations in southern Africa with respect to their stable water isotope composition, moisture transport pathways, and sources. Five different precipitation distributions are identified by end-member modeling and respective rainfall zones are inferred, which differ significantly in their isotopic compositions. By calculating backward trajectories, different moisture source regions are identified for the rainfall zones and linked to typical circulation patterns. Our results furthermore show the importance of the seasonality, the amount effect, and the traveled distance of the moisture for the general isotopic composition over the entire southern Africa. The identified pattern and relationships can be useful in the evaluation of isotope-enabled climate models for the region and are potentially of major importance for the interpretation of stable water isotope composition in paleo-records in future research

Populating the Galaxy with pulsars I: stellar & binary evolution

The computation of theoretical pulsar populations has been a major component of pulsar studies since the 1970s. However, the majority of pulsar population synthesis has only regarded isolated pulsar evolution. Those that have examined pulsar evolution within binary systems tend to either treat binary evolution poorly or evolve the pulsar population in an ad-hoc manner. Thus no complete and direct comparison with observations of the pulsar population within the Galactic disk has been possible to date. Described here is the first component of what will be a complete synthetic pulsar population survey code. This component is used to evolve both isolated and binary pulsars. Synthetic observational surveys can then be performed on this population for a variety of radio telescopes. The final tool used for completing this work will be a code comprised of three components: stellar/binary evolution, Galactic kinematics and survey selection effects. Results provided here support the need for further (apparent) pulsar magnetic field decay during accretion, while they conversely suggest the need for a re-evaluation of the assumed \textit{typical} MSP formation process. Results also focus on reproducing the observed $P\dot{P}$ diagram for Galactic pulsars and how this precludes short timescales for standard pulsar exponential magnetic field decay. Finally, comparisons of bulk pulsar population characteristics are made to observations displaying the predictive power of this code, while we also show that under standard binary evolutionary assumption binary pulsars may accrete much mass.Comment: 26 pages, 16 figures, 1 table, accepted for publication in MNRA