Illuminating Flatland: Nonlinear and Nonequilibrium Optical Properties of Graphene

In this thesis the nonlinear and nonequilibrium properties of graphene are experimentally investigated using degenerate four--wave mixing and time--resolved pump--probe spectroscopy. High quality exfoliated natural graphite and large area epitaxial graphene on silicon carbide are investigated with femtosecond and picosecond ultrafast pulses in the near--infrared. A bespoke technique for suspending exfoliated graphene is also presented. In Chapter 3, the third--order nonlinear susceptibility of graphene is measured for the first time and shows a remarkably large response. Degenerate four--wave mixing at near--infrared wavelengths demonstrates an almost dispersionless emission over a broad spectral range. Quantum kinetic theory is employed to estimate the magnitude of the response and is in good agreement with the experimental data. The large susceptibility enables high contrast imaging, with a monolayer flake contrast of the order 10^{7} times higher than for standard reflection imaging. The degenerate four--wave mixing technique is utilised in Chapter 4 to measure the interface carbon signal of epitaxially grown graphene on silicon carbide. Comparable third--order signal from the silicon carbide bulk prevents true interface imaging. Excluding the third--order emission from detection by elongating the emission to outside a band--pass filter range allows for pure interfacial luminescence imaging. Features within the two growth faces are investigated with Raman spectroscopy. Nonlinear measurements are an increasingly popular tool for investigating fundamental properties of graphene. Chapter 5 investigates the influence of ultrafast pulses on the nonlinear response of graphene. High instantaneous intensities at the sample are shown to reduce the nonlinear emission by a factor or two. Comparing the Raman peak positions, widths and intensities before and after irradiation points to a huge doping of the samples, of the order 500 meV. In Chapter 6 the relaxation of photoexcited carriers is measured via time--resolved pump--probe spectroscopy, where a layer dependence of hot phonon decay is observed. Single layer flakes are observed to relax faster than bilayers and trilayers, with an asymptote reached at approximately four layers. Removing the substrate and measuring fully suspended samples reveals the same trend, suggesting that substrate interactions are not the cause of the enhanced decay. The decay mechanism is therefore intrinsic to graphene, perhaps due to coupling to out--of--plane, flexural phonons. The thickness dependence of epitaxial graphene on silicon carbide is compared to that of exfoliated flakes where the layer dependence is not observed. Phonon relaxation times, however, are in good agreement. Predictions for future investigations into this novel material based on the works here are suggested in Chapter 7. Preliminary pump--probe measurements at high carrier concentrations are an example of such progress, which will offer an insight into further decay mechanisms in graphene

User driven modelling: Visualisation and systematic interaction for end-user programming with tree-based structures

This thesis addresses certain problems encountered by teams of engineers when modelling complex structures and processes subject to cost and other resource constraints. The cost of a structure or process may be ‘read off’ its specifying model, but the language in which the model is expressed (e.g. CAD) and the language in which resources may be modelled (e.g. spreadsheets) are not naturally compatible. This thesis demonstrates that a number of intermediate steps may be introduced which enable both meaningful translation from one conceptual view to another as well as meaningful collaboration between team members. The work adopts a diagrammatic modelling approach as a natural one in an engineering context when seeking to establish a shared understanding of problems.Thus, the research question to be answered in this thesis is: ‘To what extent is it possible to improve user-driven software development through interaction with diagrams and without requiring users to learn particular computer languages?’ The goal of the research is to improve collaborative software development through interaction with diagrams, thereby minimising the need for end-users to code directly. To achieve this aim a combination of the paradigms of End-User Programming, Process and Product Modelling and Decision Support, and Semantic Web are exploited and a methodology of User Driven Modelling and Programming (UDM/P) is developed, implemented, and tested as a means of demonstrating the efficacy of diagrammatic modelling.In greater detail, the research seeks to show that diagrammatic modelling eases problems of maintenance, extensibility, ease of use, and sharing of information. The methodology presented here to achieve this involves a three step translation from a visualised ontology, through a modelling tool, to output to interactive visualisations. An analysis of users groups them into categories of system creator, model builder, and model user. This categorisation corresponds well with the three-step translation process where users develop the ontology, modelling tool, and visualisations for their problem.This research establishes and exemplifies a novel paradigm of collaborative end-user programming by domain experts. The end-user programmers can use a visual interface where the visualisation of the software exactly matches the structure of the software itself, making translation between user and computer, and vice versa, much more direct and practical. The visualisation is based on an ontology that provides a representation of the software as a tree. The solution is based on translation from a source tree to a result tree, and visualisation of both. The result tree shows a structured representation of the model with a full visualisation of all parts that leads to the computed result.In conclusion, it is claimed that this direct representation of the structure enables an understanding of the program as an ontology and model that is then visualised, resulting in a more transparent shared understanding by all users. It is further argued that our diagrammatic modelling paradigm consequently eases problems of maintenance, extensibility, ease of use, and sharing of information. This method is applicable to any problem that lends itself to representation as a tree. This is considered a limitation of the method to be addressed in a future project

Linguistic Organisation and Native Title

Classical Aboriginal societies in Australia have commonly been described in terms of social organisation and local organisation. This book presents rich detail on a third and related domain that has not been given the same kind of attention: linguistic organisation. Basing their analyses on fieldwork among the Wik peoples of Cape York Peninsula, north Australia, Peter Sutton and Ken Hale show how cosmology, linguistic variation, language prehistory, clan totemic identities, geopolitics, land use and land ownership created a vibrant linguistic organisation in a classical Aboriginal society. This has been a society long in love with language and languages. Its people have richly imbued the domain of rights and interests in country—the foundations of their native title as recognised in Australian law—with rights and interests in the abundance of languages and dialects given to them at the start of the world

Cognition: The New Frontier for Nuts and Berries

The inclusion of nuts in the diet is associated with a decreased risk of coronary artery disease, hypertension, gallstones, diabetes, cancer, metabolic syndrome, and visceral obesity. Frequent consumption of berries seems to be associated with improved cardiovascular and cancer outcomes, improved immune function, and decreased recurrence of urinary tract infections; the consumption of nuts and berries is associated with reduction in oxidative damage, inflammation, vascular reactivity, and platelet aggregation, and improvement in immune functions. However, only recently have the effects of nut and berry consumption on the brain, different neural systems, and cognition been studied. There is growing evidence that the synergy and interaction of all of the nutrients and other bioactive components in nuts and berries can have a beneficial effect on the brain and cognition. Regular nut consumption, berry consumption, or both could possibly be used as an adjunctive therapeutic strategy in the treatment and prevention of several neurodegenerative diseases and age-related brain dysfunction. A number of animal and a growing number of human studies show that moderate-duration dietary supplementation with nuts, berry fruit, or both is capable of altering cognitive performance in humans, perhaps forestalling or reversing the effects of neurodegeneration in aging. © 2014 American Society for Nutrition

Assessing the Persistence and Mobility of Organic Substances to Protect Freshwater Resources

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Effect of hydroperoxides on red blood cell membrane mechanical properties

Copyright © 2011 Biophysical SocietyWe investigate the effect of oxidative stress on red blood cell membrane mechanical properties in vitro using detailed analysis of the membrane thermal fluctuation spectrum. Two different oxidants, the cytosol-soluble hydrogen peroxide and the membrane-soluble cumene hydroperoxide, are used, and their effects on the membrane bending elastic modulus, surface tension, strength of confinement due to the membrane skeleton, and 2D shear elastic modulus are measured. We find that both oxidants alter significantly the membrane elastic properties, but their effects differ qualitatively and quantitatively. While hydrogen peroxide mainly affects the elasticity of the membrane protein skeleton (increasing the membrane shear modulus), cumene hydroperoxide has an impact on both membrane skeleton and lipid bilayer mechanical properties, as can be seen from the increased values of the shear and bending elastic moduli. The biologically important implication of these results is that the effects of oxidative stress on the biophysical properties, and hence the physiological functions, of the cell membrane depend on the nature of the oxidative agent. Thermal fluctuation spectroscopy provides a means of characterizing these different effects, potentially in a clinical milieu

Notional Scoring for Technical Review Weighting As Applied to Simulation Credibility Assessment

NASA's Modeling and Simulation Standard requires a credibility assessment for critical engineering data produced by models and simulations. Credibility assessment is thus a "qualifyingfactor" in reporting results from simulation-based analysis. The degree to which assessors should be independent of the simulation developers, users and decision makers is a recurring question. This paper provides alternative "weighting algorithms" for calculating the value-added for independence of the levels of technical review defined for the NASA Modeling and Simulation Standard