1,354 research outputs found
Pollinators, âmustard oilâ volatiles, and fruit production in flowers of the dioecious tree Drypetes natalensis (Putranjivaceae)
The Putranjivaceae is an enigmatic family, notable for being the only lineage outside the Capparales to possess the glucosinolate biochemical pathway, which forms the basis of an induced chemical defense system against herbivores (the â mustard oil bomb â ). We investigated the pollination biology and fl oral scent chemistry of Drypetes natalensis (Putranjivaceae), a dioecious subcanopy tree with fl owers borne on the stem (caulifl ory). Flowering male trees were more abundant than female ones and produced about 10-fold more fl owers. Flowers of both sexes produce copious amounts of nectar on disc-like nectaries accessible to short-tongued insects. The main fl ower visitors observed were cetoniid beetles, bees, and vespid wasps. Pollen load analysis indicated that these insects exhibit a high degree of fi delity to D. natalensis fl owers. Insects effectively transfer pollen from male to female plants resulting in about 31% of female fl owers developing fruits with viable seeds. Cetoniid beetles showed signifi cant orientation toward the scent of D. natalensis fl owers in a Y-maze olfactometer. The scents of male and female fl owers are similar in chemical composition and dominated by fatty acid derivatives and isothiocyanates from the glucosinolate pathway. The apparent constitutive emission of isothiocyanates raises interesting new questions about their functional role in flowers
Novel enantiopure bis(pyrrolo)tetrathiafulvalene donors exhibiting chiral crystal packing arrangements
Two novel enantiopure bis(pyrrolo[3,4-d])tetrathiafulvalene derivatives, substrates for preparing chiral conducting materials, show chiral crystal packing arrangements in which successive layers are rotated in accordance with an exact or approximate 43 axis. The corresponding donors containing fused dihydropyrrolegroups, and thus four more hydrogen atoms, form stacks along a crystal axis
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Surfactant modulated interactions of hydrophobically modified ethoxylated urethane (HEUR) polymers with penetrable surfaces
Hypothesis
Adsorption of hydrophobically modified ethoxylated urethane polymers (HEURs) at the soft colloid interfaces of emulsion droplets will stabilise oil-in-water emulsions (a) via steric stabilisation induced by adsorption of the polymer at the droplet surfaces through the hydrophobic groups, and (b) via continuous phase viscosity enhancement through polymer self-association. Both of these mechanisms will be modulated by the presence of the surfactant, sodium dodecylsulfate (SDS).
Experiments
Dodecane-in-water emulsions stabilised by three HEUR polymers with different structural composition were examined in the absence and presence of SDS by NMR spectroscopy and small-angle neutron scattering (SANS). The effect of adsorption of the polymer to the dodecane droplet surfaces, and the conformation of the self-associating polymer in the aqueous solution were quantified.
Findings
All emulsions were stable for days-weeks. Diffusion data showed the formation of oil droplets of hundreds of nm in size in the presence of all three HEURs, here denoted C6-L-(EO100-L)9-C6, C10-L-(EO200-L)4-C10, and C18-L-(EO200-L)7-C18, where EOx represents a block of ethylene oxide of x monomers, L denotes the linker group, and Cn the length of the hydrophobic end-group. No significant changes in droplet size across this series of polymers was observed. Collectively, the results point to adsorption of the polymer to the droplet surfaces, which results in a small decrease in the effective polymer solution concentration, thereby driving to significant changes in the structure and dynamics of the system. Evident in the SANS data in particular, is a subtle balance between the characteristic features reflecting polymer self-association, and those associated with polymer structures commensurate with a larger length-scale, dependent on the system composition. Surprisingly, the polymer and polymer/SDS complex in the presence of oil show slightly greater diffusive rates relative to the analogous systems in the absence of the oil. Finally, the partitioning of the three polymers in phase-separated samples was studied by 1H NMR, and it was shown that the C18-L-(EO200-L)7-C18 exhibited a greater partitioning in the oil phase compared with C6-L-(EO100-L)9-C6 and C10-L-(EO200-L)4-C10, an observation that may be understood in terms of the structural composition of the HEURs. The SDS showed a positive correlation between its partitioning in the two layers with the polymer partitioning, evidence of a strong interaction between the surfactant and the polymer, consistent with the behaviour observed in the oil-free system
How Fast is Your Detector? The Effect of Temporal Response on Image Quality
With increasing interest in high-speed imaging should come an increased
interest in the response times of our scanning transmission electron microscope
(STEM) detectors. Previous works have previously highlighted and contrasted
performance of various detectors for quantitative compositional or structural
studies, but here we shift the focus to detector temporal response, and the
effect this has on captured images. The rise and decay times of eight
detectors' single electron response are reported, as well as measurements of
their flatness, roundness, smoothness, and ellipticity. We develop and apply a
methodology for incorporating the temporal detector response into simulations,
showing that a loss of resolution is apparent in both the images and their
Fourier transforms. We conclude that the solid-state detector outperforms the
photomultiplier-tube (PMT) based detectors in all areas bar a slightly less
elliptical central hole and is likely the best detector to use for the majority
of applications. However, using tools introduced here we encourage users to
effectively evaluate what detector is most suitable for their experimental
needs
Synthesis of bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) derivatives functionalised with two, four or eight hydroxyl groups
Short synthetic routes to a range of BEDT-TTF derivatives functionalised with two, four or eight hydroxyl groups are reported, of interest because of their potential for introducing hydrogen bonding between donor and anion into their radical cation salts. The cycloaddition of 1,3-dithiole-2,4,5-trithione with alkenes to construct 5,6-dihydro-1,3-dithiolo[4,5-b]1,4-dithiin-2-thiones is a key step, with homo- or hetero-coupling procedures and O-deprotection completing the syntheses. The first synthesis of a single diastereomer of tetrakis(hydroxymethyl)BEDT-TTF, the cis, trans product, was achieved by careful choice of O-protecting groups to facilitate separation of homo- and hetero-coupled products. Cyclisation of the trithione with enantiopure 1R,2R,5R,6R-bis(O,O-isopropylidene)hex-3-ene-1,2,5,6-tetrol (from D-mannitol) gave two separable diastereomeric thiones, which can be transformed to enantiomeric BEDT-TTF derivatives with four or eight hydroxyl groups
The role of ferrite in Type 316H austenitic stainless steels on the susceptibility to creep cavitation
Precision Fe Kalpha and Fe Kbeta Line Spectroscopy of the Seyfert 1.9 Galaxy NGC 2992 with Suzaku
We present detailed time-averaged X-ray spectroscopy in the 0.5--10 keV band
of the Seyfert~1.9 galaxy NGC 2992 with the Suzaku X-ray Imaging Spectrometers
(XIS). We model the complex continuum in detail. There is an Fe K line emission
complex that we model with broad and narrow lines and we show that the
intensities of the two components are decoupled at a confidence level >3sigma.
The broad Fe K line has an EW of 118 (+32,-61) eV and could originate in an
accretion disk (with inclination angle greater than ~30 degrees). The narrow Fe
Kalpha line has an EW of 163 (+47,-26) eV and is unresolved FWHM <4090 km/s)
and likely originates in distant matter. The absolute flux in the narrow line
implies that the column density out of the line-of-sight could be much higher
than measured in the line-of-sight, and that the mean (historically-averaged)
continuum luminosity responsible for forming the line could be a factor of
several higher than that measured from the data. We also detect the narrow Fe
Kbeta line with a high signal-to-noise ratio and describe a new robust method
to constrain the ionization state of Fe responsible for the Fe Kalpha and Fe
Kbeta lines that does not require any knowledge of possible gravitational and
Doppler energy shifts affecting the line energies. For the distant
line-emitting matter (e.g. the putative obscuring torus) we deduce that the
predominant ionization state is lower than Fe VIII (at 99% confidence),
conservatively taking into account residual calibration uncertainties in the
XIS energy scale and theoretical and experimental uncertainties in the Fe K
fluorescent line energies. From the limits on a possible Compton-reflection
continuum it is likely that the narrow Fe Kalpha and Fe Kbeta lines originate
in a Compton-thin structure.Comment: Abstract is abridged. Accepted for publication in the Suzaku special
issue of PASJ (November 2006). 18 pages, 6 figure
Synthetic strategies for preparing BEDT-TTF derivatives functionalised with metal ion binding groups
The syntheses of BEDT-TTF (ET) derivatives with potential metal ion binding pyridyl, bipyridyl and terpyridyl groups are achieved either by stepwise construction of the organosulfur core or via reactions of hydroxymethyl-ET for which a cheap and efficient four step route is reported. The tosylate of hydroxymethyl-ET, reported for the first time, undergoes nucleophilic substitutions with pyridyl, bipyridyl- and terpyridyl-thiolates to give new donors. The X-ray crystal structures of two substituted ET derivatives show considerable deviation of the organosulfur donor system from planarity by bending about the short molecular axis of the ET group
pH-Dependent Chiral Recognition of D- and L-Arginine Derived Polyamidoamino Acids by Self-assembled Sodium Deoxycholate
D- and L-arginine-based polyamidoamino acids, called D- and L-ARGO7, retain the chirality and acid/base properties of the parent -amino acids and show pH-dependent self-structuring in water. The ability of the ARGO7 chiral isomers to selectively interact with chiral biomolecules and/or surfaces was studied by choosing sodium deoxycholate (NaDC) as a model chiral biomolecule for its ability to self-assembly into globular micelles, showing enantio-selectivity. To this purpose, mixtures of NaDC with D-, L- or D,L-ARGO7, respectively, in water were analysed by circular dichroism (CD) spectroscopy and small-angle neutron scattering (SANS) at different levels of acidity expressed in terms of pD and concentrations. Differences in the CD spectra indicated chiral discrimination for NaDC/ARGO7 mixtures in the gel phase (pD 7.30) but not in the solution phase (pD 9.06). SANS measurements confirmed large scale structural perturbation induced by this chiral discrimination in the gel phase yet no modulation of the structure in the solution phase. Together, these techniques shed light on the mechanism by which ARGO7 stereoisomers modify the morphology of NaDC micelles as a function of pH. This work demonstrates chirality-dependent interactions that drive structural evolution and phase behaviour of NaDC, opening the way for designing novel smart drug delivery systems
On the exact electric and magnetic fields of an electric dipole
We derive from Jefimenko's equations a multipole expansion in order to obtain
the exact expressions for the electric and magnetic fields of an electric
dipole with an arbitrary time dependence. A few comments are also made about
the usual expositions found in most common undergraduate and graduate textbooks
as well as in the literature on this topic
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