Conformational Entropy as a Means to Control the Behavior of Poly(diketoenamine) Vitrimers In and Out of Equilibrium.

Control of equilibrium and non-equilibrium thermomechanical behavior of poly(diketoenamine) vitrimers is shown by incorporating linear polymer segments varying in molecular weight (MW) and conformational degrees of freedom into the dynamic covalent network. While increasing MW of linear segments yields a lower storage modulus at the rubbery plateau after softening above the glass transition (Tg ), both Tg and the characteristic time of stress relaxation are independently governed by the conformational entropy of the embodied linear segments. Activation energies for bond exchange in the solid state are lower for networks incorporating flexible chains; the network topology freezing temperature decreases with increasing MW of flexible linear segments but increases with increasing MW of stiff segments. Vitrimer reconfigurability is therefore influenced not only by the energetics of bond exchange for a given network density, but also the entropy of polymer chains within the network

The distributional consequences of tax reforms under capital-skill complementarity

This paper analyses wage inequality and the welfare effects of changes in capital and labour income tax rates for different types of agents. To achieve this, we develop a model that allows for capital–skill complementarity given non-uniform distributions of asset holdings and labour skills. We find that capital tax reductions lead to the highest aggregate welfare gains but are skill-biased and thus increase inequality. However, our analysis also shows that the inequality effects of capital tax reductions are lower over the transition period compared with the long run

Fretting of CoCrMo and Ti6Al4V Alloys in Modular Prostheses

Implantation of a total hip replacements (THR) is an effective intervention in the management of arthritis. Modularity at the taper junction of THR was introduced in order to improve the ease with which the surgeon could modify the length of the taper section and the overall length of the replacement. Cobalt chromium (Co–28Cr–6Mo) and titanium (Ti–6Al–4V) alloys are the most commonly used materials for the device. This study investigates the fretting behaviour of both CoCr–CoCr and CoCr–Ti couplings and analyses their damage mechanisms. A reciprocating tribometer ball on plate fretting contact was instrumented with in situ electrochemistry to characterise the damage inflicted by tribocorrosion on the two couplings. Fretting displacements amplitudes of 10, 25 and 50 mm at an initial contact pressure of 1 GPa were assessed. The results reveal larger metallic volume loss from the CoCr–CoCr alloy compared to the CoCr–Ti alloy, and the open circuit potential indicates a depassivation of the protective oxide layer at displacement amplitudes .25 mm. In conclusion, the damage mechanisms of CoCr–CoCr and CoCr–Ti fretting contacts were identified to be wear and fatigue dominated mechanisms respectively

Geoportal Usability Evaluation

GeoTest is a project initiated by Future Position X (a GIS cluster organization in Gävle, Sweden), the National Land Survey of Sweden (NLS) and the University of Gävle. The project aims to test Swedish geodata, services and geoportals and make sure they comply with the INSPIRE the other specifications. GeoTest has developed a method for testing the usability of geoportals. The method is based on the ISO 9241-11 framework, which splits the usability evaluation into three sub-parts consisting the effectiveness, efficiency and satisfaction. By providing feedbacks from users in an organized way, the usability test provides geoportal developers with tools to validate the functions and the layout and to find possible problematic parts to be able to make better applications to meet both the organization and the end users’ needs. As a pilot test, the Swedish national geoportal, Geodataportalen, was tested for the usability. It validated the suggested method for testing the usability of geoportals

Interference effects in two-color high-order harmonic generation

We study high-order harmonic generation in argon driven by an intense 800 nm laser field and a small fraction of its second harmonic. The intensity and divergence of the emitted even and odd harmonics are strongly modulated as a function of the relative delay between the two fields. We provide a detailed analysis of the underlying interference effects. The interference changes drastically when approaching the cutoff region due to a switch of the dominant trajectory responsible for harmonic generation

Static Friction between Elastic Solids due to Random Asperities

Several workers have established that the Larkin domains for two three dimensional nonmetallic elastic solids in contact with each other at a disordered interface are enormously large. This implies that there should be negligible static friction per unit area in the macroscopic solid limit. The present work argues that the fluctuations in the heights of the random asperities at the interface that occur in the Greenwood-Williamson model can account for static friction.Comment: Contains some improvements in the treatment of the subjec

Simulations of the Static Friction Due to Adsorbed Molecules

The static friction between crystalline surfaces separated by a molecularly thin layer of adsorbed molecules is calculated using molecular dynamics simulations. These molecules naturally lead to a finite static friction that is consistent with macroscopic friction laws. Crystalline alignment, sliding direction, and the number of adsorbed molecules are not controlled in most experiments and are shown to have little effect on the friction. Temperature, molecular geometry and interaction potentials can have larger effects on friction. The observed trends in friction can be understood in terms of a simple hard sphere model.Comment: 13 pages, 13 figure

Synthesis and characterization of Zr2Al3C4 thin films

Zr2Al3C4 is an inherently nanolaminated carbide where layers of ZrC alternatewith layers of Al3C2. Characterization of bulk samples has shown it has improved damage tolerance and oxidation resistance compared to its binary counterpart ZrC. Though a potential candidate for coatings applied for use in harsh environments, thin films of Zr2Al3C4 have not been reported.We have synthesized epitaxial Zr2Al3C4 thin films by pulsed cathodic arc deposition from three elemental cathodes, and have studied the effect of incident atomic flux ratio, deposition temperature, and choice of substrate on material quality. X-ray diffraction analysis showed that Zr2Al3C4 of the highest structural quality was obtained for growth on 4 H-SiC(001) substrate at 800 ^deg;C. Also, suppression of competing phases could be achieved on á-Al2O3(001) at elevated substrate temperatures. Very similar growth behavior to that of the well-known Mn+1AXn phases - Al supersaturation, binary carbide intergrowth and high sensitivity to choice of substrate - indicates a strong connection between the two families ofmaterials, despite their differences in structure and in chemistry

On the driven Frenkel-Kontorova model: II. Chaotic sliding and nonequilibrium melting and freezing

The dynamical behavior of a weakly damped harmonic chain in a spatially periodic potential (Frenkel-Kontorova model) under the subject of an external force is investigated. We show that the chain can be in a spatio-temporally chaotic state called fluid-sliding state. This is proven by calculating correlation functions and Lyapunov spectra. An effective temperature is attributed to the fluid-sliding state. Even though the velocity fluctuations are Gaussian distributed, the fluid-sliding state is clearly not in equilibrium because the equipartition theorem is violated. We also study the transition between frozen states (stationary solutions) and=7F molten states (fluid-sliding states). The transition is similar to a first-order phase transition, and it shows hysteresis. The depinning-pinning transition (freezing) is a nucleation process. The frozen state contains usually two domains of different particle densities. The pinning-depinning transition (melting) is caused by saddle-node bifurcations of the stationary states. It depends on the history. Melting is accompanied by precursors, called micro-slips, which reconfigurate the chain locally. Even though we investigate the dynamics at zero temperature, the behavior of the Frenkel-Kontorova model is qualitatively similar to the behavior of similar models at nonzero temperature.Comment: Written in RevTeX, 13 figures in PostScript, appears in PR