256 research outputs found
Role of covalency in the ground state properties of perovskite ruthenates: A first principle study using local spin density approximations
We investigate the electronic structure of SrRuO3 and CaRuO3 using full
potential linearized augmented plane wave method within the local spin density
approximations. The ferromagnetic ground state in SrRuO3 could exactly be
described in these calculations and the calculated spin magnetic moment is
found to be close to the experimentally observed values. Interestingly, the
spin polarized calculations for CaRuO3 exhibit large spin moment as observed in
the experiments but the magnetic ground state has higher energy than that in
the non-magnetic solution. Various calculations for different structural
configurations indicate that Ca-O covalency plays the key role in determining
the electronic structure and thereby the magnetic ground state in this system.Comment: 8 figure
TiOCl, an orbital-ordered system?
We present first principles density functional calculations and downfolding
studies of the electronic and magnetic properties of the layered quantum spin
system
TiOCl. We discuss explicitely the nature of the exchange pathes and attempt
to clarify the concept of orbital ordering in this material. An analysis of the
electronic structure of slightly distorted structures according to the phononic
modes allowed in this material suggests that this system is subject to large
orbital fluctuations driven by the electron-phonon coupling. Based on these
results, we propose a microscopic explanation of the behavior of TiOCl near the
phase transition to a spin-gapped system.Comment: Some figures are compressed, for higher quality please contact the
author
Magnetic Field Effect on the Pseudogap Temperature within Precursor Superconductivity
We determine the magnetic field dependence of the pseudogap closing
temperature T* within a precursor superconductivity scenario. Detailed
calculations with an anisotropic attractive Hubbard model account for a
recently determined experimental relation in BSCCO between the pseudogap
closing field and the pseudogap temperature at zero field, as well as for the
weak initial dependence of T* at low fields. Our results indicate that the
available experimental data are fully compatible with a superconducting origin
of the pseudogap in cuprate superconductors.Comment: 4 pages, 3 figure
Materials Design using Correlated Oxides: Optical Properties of Vanadium Dioxide
Materials with strong electronic Coulomb interactions play an increasing role
in modern materials applications. "Thermochromic" systems, which exhibit
thermally induced changes in their optical response, provide a particularly
interesting case. The optical switching associated with the metal-insulator
transition of vanadium dioxide (VO2), for example, has been proposed for use in
"intelligent" windows, which selectively filter radiative heat in hot weather
conditions. In this work, we develop the theoretical tools for describing such
a behavior. Using a novel scheme for the calculation of the optical
conductivity of correlated materials, we obtain quantitative agreement with
experiments for both phases of VO2. On the example of an optimized
energy-saving window setup, we further demonstrate that theoretical materials
design has now come into reach, even for the particularly challenging class of
correlated electron systems.Comment: 4+x pages, 2 figure
Maximally localized Wannier functions in LaMnO3 within PBE+U, hybrid functionals, and partially self-consistent GW: an efficient route to construct ab-initio tight-binding parameters for e_g perovskites
Using the newly developed VASP2WANNIER90 interface we have constructed
maximally localized Wannier functions (MLWFs) for the e_g states of the
prototypical Jahn-Teller magnetic perovskite LaMnO3 at different levels of
approximation for the exchange-correlation kernel. These include conventional
density functional theory (DFT) with and without additional on-site Hubbard U
term, hybrid-DFT, and partially self-consistent GW. By suitably mapping the
MLWFs onto an effective e_g tight-binding (TB) Hamiltonian we have computed a
complete set of TB parameters which should serve as guidance for more elaborate
treatments of correlation effects in effective Hamiltonian-based approaches.
The method-dependent changes of the calculated TB parameters and their
interplay with the electron-electron (el-el) interaction term are discussed and
interpreted. We discuss two alternative model parameterizations: one in which
the effects of the el-el interaction are implicitly incorporated in the
otherwise "noninteracting" TB parameters, and a second where we include an
explicit mean-field el-el interaction term in the TB Hamiltonian. Both models
yield a set of tabulated TB parameters which provide the band dispersion in
excellent agreement with the underlying ab initio and MLWF bands.Comment: 30 pages, 7 figure
Chiral d+is superconducting state in the two dimensional t-t' Hubbard model
Applying the recently developed variational approach to Kohn-Luttinger
superconductivity to the t-t' Hubbard model in two dimensions, we have found,
for sizeable next-nearest neighbor hopping, an electron density controlled
quantum phase transition between a d-wave superconducting state close to half
filling and an s-wave superconductor at lower electron density. The transition
occurs via an intermediate time reversal breaking d+is superconducting phase,
which is characterized by nonvanishing chirality and density-current
correlation. Our results suggest the possibility of a bulk time reversal
symmetry breaking state in overdoped cuprates
Static overscreening and nonlinear response in the Hubbard Model
We investigate the static charge response for the Hubbard model. Using the
Slave-Boson method in the saddle-point approximation we calculate the charge
susceptibility. We find that RPA works quite well close to half-filling,
breaking, of course, down close to the Mott transition. Away from half filling
RPA is much less reliable: Already for very small values of the Hubbard
interaction U, the linear response becomes much more efficient than RPA,
eventually leading to overscreening already beyond quite moderate values of U.
To understand this behavior we give a simple argument, which implies that the
response to an external perturbation at large U should actually be strongly
non-linear. This prediction is confirmed by the results of exact
diagonalization.Comment: 10 pages, 7 figures, RevTe
Electronic States in the Antiferromagnetic Phase of Electron-Doped High-Tc Cuprates
We investigate the electronic states in the antiferromagnetic (AF) phase of
electron-doped cuprates by using numerically exact diagonalization technique
for a t-t'-t''-J model. When AF correlation develops with decreasing
temperature, a gaplike behavior emerges in the optical conductivity.
Simultaneously, the coherent motion of carriers due to the same sublattice
hoppings is enhanced. We propose that the phase is characterized as an AF state
with small Fermi surface around the momentum k=(\pi,0) and (0,\pi). This is a
remarkable contrast to the behavior of hole-doped cuprates.Comment: RevTeX, 5 pages, 4 figures, to appear in Phys. Rev. B Brief Report
Winding number order in the Haldane model with interactions
We study the Haldane model with nearest–neighbor interactions. This model is physically motivated by the associated implementation with ultracold atoms. We show that the topological phase of the interacting model can be characterized by a physically observable winding number. The robustness of this number extends well beyond the topological insulator phase towards attractive and repulsive interactions that are comparable to the kinetic energy scale of the model. We identify and characterize the relevant phases of the model as a function of the interaction strength
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