Donor/acceptor heterojunction organic solar cells

Organic solar cells (OSCs) have made very good improvements in recent years, reaching power conversion efficiencies above 10% [1]. This have been achieved through chemical synthesis of new organic materials with improved properties and also by new and more or less complex structures such as donor/acceptor (D/A) or bulk heterojunction OSCs. Here we report the results of initial development of OSCs based on the simple D/A heterojunction [2]. Copper phtalocyanine (CuPc) is used as donor organic material, whereas perylenetetracarboxylic dianhydride (PTCDA) and fullerene (C60) as acceptor organic materials. Moreover bathocuproine (BCP) is used as exciton blocking layer. Devices are fabricated by vacuum thermal deposition on ITO coated glass substrates with the layers thickness and structure as follows: a) ITO/CuPc (45 nm)/PTCDA (40 nm)/LiF (1 nm)/Al (80nm); b) ITO/CuPc (20 nm)/C60 (40 nm)/BCP (12 nm)/Al (80 nm). Their band diagram is shown in Fig.1. The BCP layer of the device b), inserted between the acceptor layer and the metal cathode, acts as exciton blocking layer preventing excitons photogenerated in the C60 layer from diffusing towards the Al cathode and being lost by nonradiative recombination. The OSCs are tested in ambient atmosphere without encapsulation by using a calibrated halide lamp as a light source and varying the incident optical power density by simply changing the distance between the lamp and the solar cells [3]. The illumination condition used is AM1.0, i.e. vertical incidence and a standard value of 100 mW/cm2 for the optical power density. The J-V characteristics under illumination of the OSCs are reported in Fig. 2 for increasing incident optical power density. The Fig. 2(a) is for the OSC with structure a) and shows that the photovoltaic effect is not very strong. The OSC exhibits an open circuit voltage VOC of 80 mV and a short circuit current density JSC of about 40 \uf06dA/cm2 at 100 mW/cm2 incident optical power density. The Fig. 2(b) is for the OSC with structure b). This OSC shows a much better photovoltaic effect as compared to that of the OSC with structure a), due to the fullerene layer used as acceptor and, more important, to the insertion of the exciton blocking layer. The OSC exhibits VOC = 0,43 V and JSC = 2,35 mA/cm2 (again AM1.0 with 100 mW/cm2) with a fill factor FF 48 50%, an external quantum efficiency (electrons/s over incident photons/s) EQE 48 5% and a power conversion efficiency \uf068 48 0,5%. These results are certainly a good starting point for further improvement

Donor/Acceptor Heterojunction Organic Solar Cells

The operation and the design of organic solar cells with donor/acceptor heterojunction structure and exciton blocking layer is outlined and results of their initial development and assessment are reported. Under halogen lamp illumination with 100 mW/cm2 incident optical power density, the devices exhibits an open circuit voltage VOC = 0.45 V, a short circuit current density JSC between 2 and 2.5 mA/cm2 with a fill factor FF ≈ 50%, an external quantum efficiency (electrons/s over incident photons/s) EQE ≈ 5% and a power conversion efficiency of about 0.5%. Measurements of the photoelectrical characteristics with time are also reported, confirming that non encapsulated organic solar cells have limited stability in ambient atmosphere

Entropy production and asymptotic factorization via thermalization: a collisional model approach

The Markovian evolution of an open quantum system is characterized by a positive entropy production, while the global entropy gets redistributed between the system and the environment degrees of freedom. Starting from these premises, we analyze the entropy variation of an open quantum system in terms of two distinct relations: the Clausius inequality, that provides an intrinsic bound for the entropy variation in terms of the heat absorbed by the system, and an extrinsic inequality, which instead relates the former to the corresponding entropy increment of the environment. By modeling the thermalization process with a Markovian collisional model, we compare and discuss the two bounds, showing that the latter is asymptotically saturated in the limit of large interaction time. In this regime not only the reduced density matrix of the system reaches an equilibrium configuration, but it also factorizes from the environment degrees of freedom. This last result is proven analytically when the system-bath coupling is sufficiently strong and through numerical analysis in the weak-coupling regime.Comment: 10 pages, 2 figure

Geometric phase through spatial potential engineering

We propose a spatial analog of the Berry's phase mechanism for the coherent manipulation of states of non-relativistic massive particles moving in a two-dimensional landscape. In our construction the temporal modulation of the system Hamiltonian is replaced by a modulation of the confining potential along the transverse direction of the particle propagation. By properly tuning the model parameters the resulting scattering input-output relations exhibit a Wilczek-Zee non-abelian phase shift contribution that is intrinsically geometrical, hence insensitive to the specific details of the potential landscape. A theoretical derivation of the effect is provided together with practical examples.Comment: 10 pages, 5 figure

Stretching potential engineering

As the possibility to decouple temporal and spatial variations of the electromagnetic field, leading to a wavelength stretching, has been recognized to be of paramount importance for practical applications, we generalize the idea of stretchability from the framework of electromagnetic waves to massive particles. A necessary and sufficient condition which allows one to identify energetically stable configuration of a 1D quantum particle characterized by arbitrary large spatial regions where the associated wave-function exhibit a flat, non-zero profile is presented, together with examples on well-known and widely used potential profiles and an application to 2D models

Implementation and Comparison of SiC and GaN switches for EV Fast Recharging Systems

Wide bandgap material-based devices allow faster switching frequency and exhibit smaller losses than traditional Si devices; nevertheless, a complete understanding of the functioning of these new devices remains poorly understood. A fast battery charger for electric vehicles based on a converter employing SiC and GaN devices is here reported Besides, these two technologies are experimentally compared, in the same layout, to highlights their performance in terms of electrical dynamic and electromagnetic compatibility

Evidence for chromatic X-ray light-curve breaks in Swift GRB afterglows and their theoretical implications

The power-law decay of the X-ray emission of GRB afterglows 050319, 050401, 050607, 050713A, 050802 and 050922C exhibits a steepening at about 1--4 hours after the burst which, surprisingly, is not accompanied by a break in the optical emission. If it is assumed that both the optical and X-ray afterglows arise from the same outflow then, in the framework of the standard forward shock model, the chromaticity of the X-ray light-curve breaks indicates that they do not arise solely from a mechanism related to the outflow dynamics (e.g. energy injection) or the angular distribution of the blast-wave kinetic energy (structured outflows or jets). The lack of a spectral evolution accompanying the X-ray light-curve breaks shows that these breaks do not arise from the passage of a spectral break (e.g. the cooling frequency) either. Under these circumstances, the decoupling of the X-ray and optical decays requires that the microphysical parameters for the electron and magnetic energies in the forward shock evolve in time, whether the X-ray afterglow is synchrotron or inverse-Compton emission. For a steady evolution of these parameters with the Lorentz factor of the forward shock and an X-ray light-curve break arising from cessation of energy injection into the blast-wave, the optical and X-ray properties of the above six Swift afterglows require a circumburst medium with a r^{-2} radial stratification, as expected for a massive star origin for long GRBs. Alternatively, the chromatic X-ray light-curve breaks may indicate that the optical and X-ray emissions arise from different outflows. Neither feature (evolution of microphysical parameters or the different origin of the optical and X-ray emissions) were clearly required by pre-Swift afterglows.Comment: 6 pages, sumbitted to MNRA

Shallow decay phase of GRB X-ray afterglows from relativistic wind bubbles

The postburst object of a GRB is likely to be a highly magnetized, rapidly rotating compact object (e.g., a millisecond magnetar), which could produce an ultrarelativistic electron-positron-pair wind. The interaction of such a wind with an outwardly expanding fireball ejected during the burst leads to a relativistic wind bubble (RWB). We numerically calculate the dynamics and radiative properties of RWBs and use this model to explain the shallow decay phase of the early X-ray afterglows observed by Swift. We find that RWBs can fall into two types: forward-shock-dominated and reverse-shock-dominated bubbles. Their radiation during a period of $\sim 10^{2}-10^{5}$ seconds is dominated by the shocked medium and the shocked wind, respectively, based on different magnetic energy fractions of the shocked materials. For both types, the resulting light curves always have a shallow decay phase. In addition, we provide an example fit to the X-ray afterglows of GRB 060813 and GRB 060814 and show that they could be produced by forward-shock-dominated and reverse-shock-dominated bubbles, respectively. This implies that, for some early afterglows (e.g., GRB 060814), the long-lasting reverse shock emission is strong enough to explain their shallow decay phase.Comment: 5 pages, 4 figures, Accepted for Publication in A&

Jet breaks at the end of the slow decline phase of Swift GRB lightcurves

The Swift mission has discovered an intriguing feature of Gamma-Ray Burst (GRBs) afterglows, a phase of shallow decline of the flux in the X-ray and optical lightcurves. This behaviour is typically attributed to energy injection into the burst ejecta. At some point this phase ends, resulting in a break in the lightcurve, which is commonly interpreted as the cessation of the energy injection. In a few cases, however, while breaks in the X-ray lightcurve are observed, optical emission continues its slow flux decline. This behaviour suggests a more complex scenario. In this paper, we present a model that invokes a double component outflow, in which narrowly collimated ejecta are responsible for the X-ray emission while a broad outflow is responsible for the optical emission. The narrow component can produce a jet break in the X-ray lightcurve at relatively early times, while the optical emission does not break due to its lower degree of collimation. In our model both components are subject to energy injection for the whole duration of the follow-up observations. We apply this model to GRBs with chromatic breaks, and we show how it might change the interpretation of the GRBs canonical lightcurve. We also study our model from a theoretical point of view, investigating the possible configurations of frequencies and the values of GRB physical parameters allowed in our model.Comment: 19 pages, 3 figures. To be published by MNRA

United classification of cosmic gamma-ray bursts and their counterparts

United classification of gamma-ray bursts and their counterparts is established on the basis of measured characteristics: photon energy E and emission duration T. The founded interrelation between the mentioned characteristics of events consists in that, as the energy increases, the duration decreases (and vice versa). The given interrelation reflects the nature of the phenomenon and forms the E-T diagram, which represents a natural classification of all observed events in the energy range from 10E9 to 10E-6 eV and in the corresponding interval of durations from about 10E-2 up to 10E8 s. The proposed classification results in the consequences, which are principal for the theory and practical study of the phenomenon.Comment: Keywords Gamma rays: burst