Assessment of alternative land management practices using hydrological simulation and a decision support tool: Arborea agricultural region, Sardinia

Quantifying the impact of land use on water supply and quality is a primary focus of environmental management. In this work we apply a semidistributed hydrological model (SWAT) to predict the impact of different land management practices on water and agricultural chemical yield over a long period of time for a study site situated in the Arborea region of central Sardinia, Italy. The physical processes associated with water movement, crop growth, and nutrient cycling are directly modeled by SWAT. The model simulations are used to identify indicators that reflect critical processes related to the integrity and sustainability of the ecosystem. Specifically we focus on stream quality and quantity indicators associated with anthropogenic and natural sources of pollution. A multicriteria decision support system is then used to develop the analysis matrix where water quality and quantity indicators for the rivers, lagoons, and soil are combined with socio-economic variables. The DSS is used to assess four options involving alternative watersheds designated for intensive agriculture and dairy farming and the use or not of treated wastewater for irrigation. Our analysis suggests that of the four options, the most widely acceptable consists in the transfer of intensive agricultural practices to the larger watershed, which is less vulnerable, in tandem with wastewater reuse, which rates highly due to water scarcity in this region of the Mediterranean. More generally, the work demonstrates how both qualitative and quantitative methods and information can assist decision making in complex settings

Numerical tests of the lookup table method in solving richards' equation for infiltration and drainage in heterogeneous soils

The lookup table option, as an alternative to analytical calculation for evaluating the nonlinear heterogeneous soil characteristics, is introduced and compared for both the Picard and Newton iterative schemes in the numerical solution of Richards\u2019 equation. The lookup table method can be a cost-effective alternative to analytical evaluation in the case of heterogeneous soils, but it has not been examined in detail in the hydrological modeling literature. Three layered soil test problems are considered, and the robustness and accuracy of the lookup table approach are assessed for uniform and non-uniform distributions of lookup points in the soil moisture retention curves. Results from the three one-dimensional test simulations show that the uniform distributed option gives improved convergence and robustness for the drainage problem compared to the non-uniform strategy. On the other hand, the non-uniform technique can be chosen for test problems involving flow into initially dry layered soils

Investigating parameter transferability across models and events for a Semiarid Mediterranean Catchment

Physically based distributed hydrologic models (DHMs) simulate watershed processes by applying physical equations with a variety of simplifying assumptions and discretization approaches. These equations depend on parameters that, in most cases, can be measured and, theoretically, transferred across different types of DHMs. The aim of this study is to test the potential of parameter transferability in a real catchment for two contrasting periods among three DHMs of varying complexity. The case study chosen is a small Mediterranean catchment where the TIN-based Real-time Integrated Basin Simulator (tRIBS) model was previously calibrated and tested. The same datasets and parameters are used here to apply two other DHMs-the TOPographic Kinematic Approximation and Integration model (TOPKAPI) and CATchment HYdrology (CATHY) models. Model performance was measured against observed discharge at the basin outlet for a one-year period (1930) corresponding to average wetness conditions for the region, and for a much drier two-year period (1931-1932). The three DHMs performed comparably for the 1930 period but showed more significant differences (the CATHY model in particular for the dry period. In order to improve the performance of CATHY for this latter period, an hypothesis of soil crusting was introduced, assigning a lower saturated hydraulic conductivity to the top soil layer. It is concluded that, while the physical basis for the three models allowed transfer of parameters in a broad sense, transferability can break down when simulation conditions are greatly altered

A modeling study of heterogeneity and surface water-groundwater interactions in the Thomas Brook catchment, Annapolis Valley (Nova Scotia, Canada)

A modelling study of the impacts of subsurface\ud heterogeneity on the hydrologic response of a small catchment\ud is reported. The study is focused in particular on the\ud hydraulic connection and interactions between surface water\ud and groundwater. A coupled (1-D surface/3-D subsurface)\ud numerical model is used to investigate, for a range of scenarios,\ud the spatio-temporal patterns of response variables such\ud as return flow, recharge, groundwater levels, surface saturation,\ud and streamflow. Eight scenarios of increasing geological\ud complexity are simulated for an 8 km2 catchment in\ud the Annapolis Valley (eastern Canada), introducing at each\ud step more realistic representations of the geological strata\ud and corresponding hydraulic properties. In a ninth scenario\ud the effects of snow accumulation and snowmelt are also considered.\ud The results show that response variables and significant\ud features of the catchment (e.g. springs) can be adequately\ud reproduced using a representation of the geology and\ud model parameter values that are based on targeted fieldwork\ud and existing databases, and that reflect to a sufficient degree\ud the geological and hydrological complexity of the study area.\ud The hydraulic conductivity values of the thin surficial sediment\ud cover (especially till) and of the basalts in the upstream\ud reaches emerge as key elements of the basin’s heterogeneity\ud for properly capturing the overall catchment response

Low-dimensional modeling of hillslope subsurface flow: Relationship between rainfall, recharge, and unsaturated storage dynamics

We present a coupling between the one-dimensional Richards equation for vertical unsaturated flow and the one-dimensional hillslope-storage Boussinesq equation (HSB) for lateral saturated flow along complex hillslopes. Here the capillary fringe is included in the flow domain as an integral part of the Boussinesq aquifer. The coupling allows quantitative investigation of the role of unsaturated storage in the relationship between rainfall and recharge. The coupled model (HSB coupled) is compared to the original HSB model (HSB original) and a three-dimensional Richards equation (RE) based model (taken to be the benchmark) on a set of seven synthetic hillslopes, ranging from convergent to divergent. Using HSB original, the water tables are overestimated and the outflow rates are generally underestimated, and there is no delay between rainfall and recharge. The coupled model, however, shows a remarkably good match with the RE model in terms of outflow rates, and the delay between rainfall and recharge is captured well. We also see a clear improvement in the match to the water tables, even though the values are still overestimated for some hillslope shapes, in particular the convergent slopes. We show that for the hillslope configurations and scenarios examined in this paper it is possible to reproduce hydrographs and water table dynamics with a good degree of accuracy using a low-dimensional hydrological model

Groundwater resources assessment using numerical model : a case study in low-lying coastal area.

The impacts of climate change and human pressure in groundwater have been greatest threats facing small islands. This paper represents a case study of groundwater responses towards the climate change and human pressures in Manukan Island Malaysia. SEAWAT-2000 was used for the simulations of groundwater response in study area. Simulations of six scenarios representing climate change and human pressures showed changes in hydraulic heads and chloride concentrations. Reduction in pumping rate and an increase in recharge rate can alter the bad effects of overdrafts in Manukan Island. In general, reduction in pumping rate and an increase in recharge rate are capable to restore and protect the groundwater resources in Manukan Island. Thus, for groundwater management options in Manukan Island, scenario 2 is capable to lessen the seawater intrusion into the aquifer and sustain water resources on a long-term basis. The selection of scenario 6 is the preeminent option during wet season. The output of this study provides a foundation which can be used in other small islands of similar hydrogeological condition for the purpose of groundwater resources protection

Перспективи інформаційної економіки

Метою доповіді є дослідження впливу інформаційних технологій на розвиток таких категорій сучасності як перехід сучасної економіки до інформаційного етапу, а також становлення інформаційного суспільства на основі сучасного пост промислового суспільства споживання

Preparation and Instability of Nanocrystalline Cuprous Nitride

Low-dimensional cuprous nitride (Cu3N) was synthesized by nitridation (ammonolysis) of cuprous oxide (Cu2O) nanocrystals using either ammonia (NH3) or urea (H2NCONH2) as the nitrogen source. The resulting nanocrystalline Cu3N spontaneously decomposes to nanocrystalline CuO in the presence of both water and oxygen from air at room temperature. Ammonia was produced in 60% chemical yield during Cu3N decomposition, as measured using the colorimetric indophenol method. Because Cu3N decomposition requires H2O and produces substoichiometric amounts of NH3\u3e, we conclude that this reaction proceeds through a complex stoichiometry that involves the concomitant release of both N2 and NH3. This is a thermodynamically unfavorable outcome, strongly indicating that H2O (and thus NH3 production) facilitate the kinetics of the reaction by lowering the energy barrier for Cu3N decomposition. The three different Cu2O, Cu3N, and CuO nanocrystalline phases were characterized by a combination of optical absorption, powder X-ray diffraction, transmission electron microscopy, and electronic density of states obtained from electronic structure calculations on the bulk solids. The relative ease of interconversion between these interesting and inexpensive materials bears possible implications for catalytic and optoelectronic applications

The importance of hydraulic groundwater theory in catchment hydrology: The legacy of Wilfried Brutsaert and Jean-Yves Parlange

Based on a literature overview, this paper summarizes the impact and legacy of the contributions of Wilfried Brutsaert and Jean-Yves Parlange (Cornell University) with respect to the current state-of-the-art understanding in hydraulic groundwater theory. Forming the basis of many applications in catchment hydrology, ranging from drought flow analysis to surface water-groundwater interactions, hydraulic groundwater theory simplifies the description of water flow in unconfined riparian and perched aquifers through assumptions attributed to Dupuit and Forchheimer. Boussinesq (1877) derived a general equation to study flow dynamics of unconfined aquifers in uniformly sloping hillslopes, resulting in a remarkably accurate and applicable family of results, though often challenging to solve due to its nonlinear form. Under certain conditions, the Boussinesq equation can be solved analytically allowing compact representation of soil and geomorphological controls on unconfined aquifer storage and release dynamics. The Boussinesq equation has been extended to account for flow divergence/convergence as well as for nonuniform bedrock slope (concave/convex). The extended Boussinesq equation has been favorably compared to numerical solutions of the three-dimensional Richards equation, confirming its validity under certain geometric conditions. Analytical solutions of the linearized original and extended Boussinesq equations led to the formulation of similarity indices for baseflow recession analysis, including scaling rules, to predict the moments of baseflow response. Validation of theoretical recession parameters on real-world streamflow data is complicated due to limited measurement accuracy, changing boundary conditions, and the strong coupling between the saturated aquifer with the overlying unsaturated zone. However, recent advances are shown to have mitigated several of these issues. The extended Boussinesq equation has been successfully applied to represent baseflow dynamics in catchment-scale hydrological models, and it is currently considered to represent lateral redistribution of groundwater in land surface schemes applied in global circulation models. From the review, it is clear that Wilfried Brutsaert and Jean-Yves Parlange stimulated a body of research that has led to several fundamental discoveries and practical applications with important contributions in hydrological modeling.Keywords: Parlange, hillslope, catchment, groundwater, Brutsaert, Boussines