A compact holographic optical tweezers instrument

Holographic optical tweezers have found many applications including the construction of complex micron-scale 3D structures and the control of tools and probes for position, force, and viscosity measurement. We have developed a compact, stable, holographic optical tweezers instrument which can be easily transported and is compatible with a wide range of microscopy techniques, making it a valuable tool for collaborative research. The instrument measures approximately 30×30×35 cm and is designed around a custom inverted microscope, incorporating a fibre laser operating at 1070 nm. We designed the control software to be easily accessible for the non-specialist, and have further improved its ease of use with a multi-touch iPad interface. A high-speed camera allows multiple trapped objects to be tracked simultaneously. We demonstrate that the compact instrument is stable to 0.5 nm for a 10 s measurement time by plotting the Allan variance of the measured position of a trapped 2 μm silica bead. We also present a range of objects that have been successfully manipulated

Strain Relaxation in Core-Shell Pt-Co Catalyst Nanoparticles

Surface strain plays a key role in enhancing the activity of Pt-alloy nanoparticle oxygen reduction catalysts. However, the details of strain effects in real fuel cell catalysts are not well-understood, in part due to a lack of strain characterization techniques that are suitable for complex supported nanoparticle catalysts. This work investigates these effects using strain mapping with nanobeam electron diffraction and a continuum elastic model of strain in simple core-shell particles. We find that surface strain is relaxed both by lattice defects at the core-shell interface and by relaxation across particle shells caused by Poisson expansion in the spherical geometry. The continuum elastic model finds that in the absence of lattice dislocations, geometric relaxation results in a surface strain that scales with the average composition of the particle, regardless of the shell thickness. We investigate the impact of these strain effects on catalytic activity for a series of Pt-Co catalysts treated to vary their shell thickness and core-shell lattice mismatch. For catalysts with the thinnest shells, the activity is consistent with an Arrhenius dependence on the surface strain expected for coherent strain in dislocation-free particles, while catalysts with thicker shells showed greater activity losses indicating strain relaxation caused by dislocations as well.Comment: 23 pages,7 figures, includes appendi

The Metallicity of the HD 98800 System

Pre-main sequence (PMS) binaries and multiples enable critical tests of stellar models if masses, metallicities, and luminosities of the component stars are known. We have analyzed high-resolution, high signal-to-noise echelle spectra of the quadruple-star system HD 98800 and using spectrum synthesis, computed fits to the composite spectrum for a full range of plausible stellar parameters for the components. We consistently find that sub-solar metallicity yields fits with lower $\chi^2$ values, with an overall best-fit of $[M/H] = -0.20\pm0.10$. This metallicity appears to be consistent with PMS evolutionary tracks for the measured masses and luminosities of the components of HD 98800 but additional constraints on the system and modelling are needed.Comment: 6 pages, 3 figures, 5 tables. Online-only material: color figure. Accepted in Ap

Real-time imaging of activation and degradation of carbon supported octahedral Pt–Ni alloy fuel cell catalysts at the nanoscale using in situ electrochemical liquid cell STEM

Octahedrally shaped Pt–Ni alloy nanoparticles on carbon supports have demonstrated unprecedented electrocatalytic activity for the oxygen reduction reaction (ORR), sparking interest as catalysts for low-temperature fuel cell cathodes. However, deterioration of the octahedral shape that gives the catalyst its superior activity currently prohibits the use of shaped catalysts in fuel cell devices, while the structural dynamics of the overall catalyst degradation are largely unknown. We investigate the time-resolved degradation pathways of such a Pt–Ni alloy catalyst supported on carbon during cycling and startup/shutdown conditions using an in situ STEM electrochemical liquid cell, which allows us to track changes happening over seconds. Thereby we can precisely correlate the applied electrochemical potential with the microstructural response of the catalyst. We observe changes of the nanocatalysts’ structure, monitor particle motion and coalescence at potentials that corrode carbon, and investigate the dissolution and redeposition processes of the nanocatalyst under working conditions. Carbon support motion, particle motion, and particle coalescence were observed as the main microstructural responses to potential cycling and holds in regimes where carbon corrosion happens. Catalyst motion happened more severely during high potential holds and sudden potential changes than during cyclic potential sweeps, despite carbon corrosion happening during both, as suggested by ex situ DEMS results. During an extremely high potential excursion, the shaped nanoparticles became mobile on the carbon support and agglomerated facet-to-facet within 10 seconds. These experiments suggest that startup/shutdown potential treatments may cause catalyst coarsening on a much shorter time scale than full collapse of the carbon support. Additionally, the varying degrees of attachment of particles on the carbon support indicates that there is a distribution of interaction strengths, which in the future should be optimized for shaped particles. We further track the dissolution of Ni nanoparticles and determine the dissolution rate as a function of time for an individual nanoparticle – which occurs over the course of a few potential cycles for each particle. This study provides new visual understanding of the fundamental structural dynamics of nanocatalysts during fuel cell operation and highlights the need for better catalyst-support anchoring and morphology for allowing these highly active shaped catalysts to become useful in PEM fuel cell applications.TU Berlin, Open-Access-Mittel - 201

KENDALA-KENDALA GURU FISIKA DALAM PENYUSUNAN DAN PELAKSANAAN PERANGKAT PEMBELAJARAN KURIKULUM 2013RN DI SMA SE-GAYO LUES

Salah satu aspek penting dalam meningkatkan mutu pendidikan fisika adalah proses penyusunan dan pelaksanaan perangkat pembelajaran yang dibuat oleh guru. Seorang guru dalam melaksanakan pembelajaran dituntut harus membuat dan merancang program pembelajaran. Guru sebelum melaksanakan tugasnya di kelas, guru harus menyiapkan perangkat pembelajaran yang di susun secara terencana dan bertahap. Salah satu yang harus disusun oleh guru adalah perangkat pembelajaran berkarakter harus sederhana dan fleksibel, serta dapat dilaksanakan dalam kegiatan pembelajaran, dan pembentukan karakter peserta didik. Dari hasil wawancara dengan beberapa orang guru timbul suatu permasalahan, sejauh manakah sebenarnya guru mengenal bentuk perangkat pembelajaran kurikulum 2013, dan apa saja kendala yang dihadapi oleh guru ketika menyusun perangkat pembelajaran kurikulum 2013. Penelitian ini bertujuan untuk mengetahui kendala apa saja yang dialami oleh guru fisika dalam menyusun perangkat pembelajaran kurikulum 2013. Metode penelitian yang digunakan adalah deskripstif kualitatif, dimana peneliti menyebarkan angket kepada guru bidang studi fisika yang ada di SMA SE-GAYO LUES dan melakukan wawancara terhadap beberapa orang guru bidang studi fisika. Hasil penelitian ini menunjukkan bahwa, adanya kendala yang dialami guru bidang studi fisika dalam menyusun perangkat pembelajaran kurikulum 2013, khususya pada kompetensi inti 47,5%, kompetensi dasar 47,5%, indikator pembelajaran 70%, tujuan pembelajaran 60%, strategi pembelajaran (metode, model dan pendekatan) sebanyak 64,8 %, kegiatan pembelajaran sebanyak 63% dan penilaian sebanyak 58,1%.Banda Ace

Materials for phantoms for terahertz pulsed imaging

Phantoms are commonly used in medical imaging for quality assurance, calibration, research and teaching. They may include test patterns or simulations of organs, but in either case a tissue substitute medium is an important component of the phantom. The aim of this work was to identify materials suitable for use as tissue substitutes for the relatively new medical imaging modality terahertz pulsed imaging. Samples of different concentrations of the candidate materials TX151 and napthol green dye were prepared, and measurements made of the frequency-dependent absorption coefficient (0.5 to 1.5 THz) and refractive index (0.5 to 1.0 THz). These results were compared qualitatively with measurements made in a similar way on samples of excised human tissue (skin, adipose tissue and striated muscle). Both materials would be suitable for phantoms where the dominant mechanism to be simulated is absorption (similar to ∼100 cm(-1) at 1 THz) and where simulation of the strength of reflections from boundaries is not important; for example, test patterns for spatial resolution measurements. Only TX151 had a frequency-dependent refractive index close to that of tissue, and could therefore be used to simulate the layered structure of skin, the complexity of microvasculature or to investigate frequency-dependent interference effects that have been noted in terahertz images

From Molecular Cores to Planet-forming Disks: An SIRTF Legacy Program

Crucial steps in the formation of stars and planets can be studied only at mid‐ to far‐infrared wavelengths, where the Space Infrared Telescope (SIRTF) provides an unprecedented improvement in sensitivity. We will use all three SIRTF instruments (Infrared Array Camera [IRAC], Multiband Imaging Photometer for SIRTF [MIPS], and Infrared Spectrograph [IRS]) to observe sources that span the evolutionary sequence from molecular cores to protoplanetary disks, encompassing a wide range of cloud masses, stellar masses, and star‐forming environments. In addition to targeting about 150 known compact cores, we will survey with IRAC and MIPS (3.6–70 μm) the entire areas of five of the nearest large molecular clouds for new candidate protostars and substellar objects as faint as 0.001 solar luminosities. We will also observe with IRAC and MIPS about 190 systems likely to be in the early stages of planetary system formation (ages up to about 10 Myr), probing the evolution of the circumstellar dust, the raw material for planetary cores. Candidate planet‐forming disks as small as 0.1 lunar masses will be detectable. Spectroscopy with IRS of new objects found in the surveys and of a select group of known objects will add vital information on the changing chemical and physical conditions in the disks and envelopes. The resulting data products will include catalogs of thousands of previously unknown sources, multiwavelength maps of about 20 deg^2 of molecular clouds, photometry of about 190 known young stars, spectra of at least 170 sources, ancillary data from ground‐based telescopes, and new tools for analysis and modeling. These products will constitute the foundations for many follow‐up studies with ground‐based telescopes, as well as with SIRTF itself and other space missions such as SIM, JWST, Herschel, and TPF/Darwin