Upgrading biogas with novel composite carbon molecular sieve (CCMS) membranes: Experimental and techno-economic assessment

The use of biogas as feedstock for hydrogen production was widely proposed in the literature in the last years as a strategy to reduce anthropogenic carbon emissions. However, its lower heating value compared to natural gas hampers the revamping of existing reforming plants. The use of composite carbon molecular sieve membranes for biogas upgrading (CO2 removal from biogas) was investigated experimentally in this work. In particular, ideal perm-selectivities and permeabilities above the Robeson plot for CO2/CH4 mixtures have been obtained. These membranes show better performances compared to polymeric membranes, which are nowadays commercialized for CO2 separation in natural gas streams. Compared to polymeric membranes, carbon membranes do not show deactivation by plasticization when exposed to CO2, and thus can find industrial application. This work was extended with a techno-economic analysis where carbon membranes are installed in a steam methane reforming plant. Results have been first validated with data from literature and show that the use of biogas increases the costs of hydrogen production to a value of 0.25 €/Nm3 compared to the benchmark technology (0.21 €/Nm3). On the other hand, the use of biogas leads to a decrease in carbon emissions up to 95%, thus the use of biogas for hydrogen production is foreseen as a very interesting alternative to conventional technologies in view of the reduction in the carbon footprint in the novel technologies that are to be installed in the near future

A surface extraction analysis in a multi-material test part for computed tomography in metrology applications

The main advantage of Computed Tomography is the capability of making measurements of non-accessible internal features in a test piece. One of the cases that can usually be found in this sense is the contact zone between two elements that are forming a common surface boundary, where the main complexity is to determine which surface belongs to which piece. Nowadays, this kind of surfaces are measurable only by utilizing Computed Tomography, taking into account that the characteristics of the Tomography can significantly vary depending on the material of the elements that are in contact. In this article a piece that has two different interfaces is analyzed: a Piece in contact with Air, and Material A in contact with Material B. Three different surface extraction algorithms are analyzed for multi-material parts, Threshold, Canny and Deriche, and the results and conclusions obtained are presented

Refraction of Electromagnetic Energy for Wave Packets Incident on a Negative Index Medium is Always Negative

We analyze refraction of electromagnetic wave packets on passing from an isotropic positive to an isotropic negative refractive index medium. We definitively show that in all cases the energy is always refracted negatively. For localized wave packets, the group refraction is also always negative.Comment: 5 pages, 3 figure

Anti rickettsia-antibody for spotted fever group in horses and dogs in the North of Paraná Stated, Brazil

The Brazilian Spotted Fever (BSF) is a zoonosis that can be fatal if not trteated. As there are few studies of the BSF in the Paraná State, the occurrence of BSF was serologically investigated in dogs and horses by indirect immunofluorescence assay (IFA), in the North of that State, in animals that are regarded as sentinels for BSF. A total of 241 samples of sera of equine, four of asinine, and 29 of dogs were collected in nine farms of three municipalities in the North of Paraná: Arapongas, Douradina, and Umuarama. From fifteen samples of equine serum with positive titres for RIFI, eight (53.3 %) had titre of 64 against R. rickettsii, two (13.3 %) 128 against R. rickettsii, and five (33.3 %) were reactants for R. parkeri and R. rickettsii, with titres ranging from 64 to 2048, and 128 to 1024, respectively. The results showed that domestic animals, sentinels for BSF, are under low exposition to ticks infected with spotted fever group Rickettsia, indicating low risk of human infection by these agents in the studied area

Mass Determination of Groups of Galaxies: Effects of the Cosmological Constant

The spherical infall model first developed by Lema\^{i}tre and Tolman was modified in order to include the effects of a dark energy term. The resulting velocity-distance relation was evaluated numerically. This equation, when fitted to actual data, permits the simultaneous evaluation of the central mass and of the Hubble parameter. Application of this relation to the Local Group, when the dark energy is modeled by a cosmological constant, yields a total mass for the M31-Milky Way pair of (2.5 +/- 0.7) x 10^12 M\_sun, a Hubble parameter H\_0 = 74 +/- 4 km s^-1 Mpc^-1 and a 1-D velocity dispersion for the flow of about 39 km s^-1. The zero-velocity and the marginally bound surfaces of the Local Group are at about 1.0 and 2.3 Mpc respectively from the center of mass. A similar analysis for the Virgo cluster yields a mass of (1.10 +/- 0.12) x 10^15 M\_sun and H\_0 = 65 +/- 9 km s^-1 Mpc^-1. The zero-velocity is located at a distance of 8.6 +/- 0.8 Mpc from the center of the cluster. The predicted peculiar velocity of the Local Group towards Virgo is about 190 kms^-1, in agreement with other estimates. Slightly lower masses are derived if the dark energy is represented by a fluid with an equation of state P = w\epsilon with w = -2/3.Comment: 13 pages, 3 figures. Version to appear in New Astronomy. Typing errors corrected in relation (1) and in percentage value in page

MicroRNA Profiling and Bioinformatics Target Analysis in Dorsal Hippocampus of Chronically Stressed Rats: Relevance to Depression Pathophysiology

Indexación: Scopus.1Laboratory of Neuroplasticity and Neurogenetics, Faculty of Chemical and Pharmaceutical Sciences, Department of Biochemistry and Molecular Biology, Universidad de Chile, Santiago, Chile, 2National Institute of Environmental Health Sciences, National Institutes of Health, Department of Health and Human Services, Durham, NC, United States, 3Centro de Genómica y Bioinformática, Facultad de Ciencias, Universidad Mayor, Santiago, Chile, 4Millennium Institute for Integrative Biology (iBio), FONDAP Center for Genome Regulation, Departamento de Genética Molecular y Microbiología, Pontificia Universidad Católica de Chile, Santiago, Chile, 5Department of Kinesiology, Faculty of Health Sciences, Universidad Católica del Maule, Talca, Chile, 6Escuela de Química y Farmacia, Facultad de Medicina, Universidad Andres Bello, Santiago, Chile.This study was supported by the following grants: FONDECYT 1120528 (JLF), Fondo Central de Investigación, Universidad de Chile ENL025/16 (JLF), ES090079 (JAC). Research in RG and EV laboratories is funded by Instituto Milenio iBio – Iniciativa Científica Milenio MINECON.Studies conducted in rodents subjected to chronic stress and some observations in humans after psychosocial stress, have allowed to establish a link between stress and the susceptibility to many complex diseases, including mood disorders. The studies in rodents have revealed that chronic exposure to stress negatively affects synaptic plasticity by triggering changes in the production of trophic factors, subunit levels of glutamate ionotropic receptors, neuron morphology, and neurogenesis in the adult hippocampus. These modifications may account for the impairment in learning and memory processes observed in chronically stressed animals. It is plausible then, that stress modifies the interplay between signal transduction cascades and gene expression regulation in the hippocampus, therefore leading to altered neuroplasticity and functioning of neural circuits. Considering that miRNAs play an important role in post-transcriptional-regulation of gene expression and participate in several hippocampus-dependent functions; we evaluated the consequences of chronic stress on the expression of miRNAs in dorsal (anterior) portion of the hippocampus, which participates in memory formation in rodents. Here, we show that male rats exposed to daily restraint stress (2.5 h/day) during 7 and 14 days display a differential profile of miRNA levels in dorsal hippocampus and remarkably, we found that some of these miRNAs belong to the miR-379-410 cluster. We confirmed a rise in miR-92a and miR-485 levels after 14 days of stress by qPCR, an effect that was not mimicked by chronic administration of corticosterone (14 days). Our in silico study identified the top-10 biological functions influenced by miR-92a, nine of which were shared with miR-485: Nervous system development and function, Tissue development, Behavior, Embryonic development, Organ development, Organismal development, Organismal survival, Tissue morphology, and Organ morphology. Furthermore, our in silico study provided a landscape of potential miRNA-92a and miR-485 targets, along with relevant canonical pathways related to axonal guidance signaling and cAMP signaling, which may influence the functioning of several neuroplastic substrates in dorsal hippocampus. Additionally, the combined effect of miR-92a and miR-485 on transcription factors, along with histone-modifying enzymes, may have a functional relevance by producing changes in gene regulatory networks that modify the neuroplastic capacity of the adult dorsal hippocampus under stress. © 2018 Muñoz-Llanos, García-Pérez, Xu, Tejos-Bravo, Vidal, Moyano, Gutiérrez, Aguayo, Pacheco, García-Rojo, Aliaga, Rojas, Cidlowski and Fiedler.https://www.frontiersin.org/articles/10.3389/fnmol.2018.00251/ful

Neutrino magnetic moments and photo-disintegration of deuterium

Neutrinos with non-zero magnetic moments can dissociate deuterium nuclei by a photon exchange, in addition to the weak neutral current process. We calculate the neutrino-magnetic moment induced photo-dissociation cross section of deuterium using the equivalent photon method. This process would contribute extra events to the neutral current reaction which is observed with high precision in the salt-phase of SNO experiment. Using the SNO data and the recent laboratory measurements of the $^7 Be (p, \gamma) ^8 B$ reaction which give a more precise value of the solar $^8 B$ flux we find that the neutrino effective magnetic moment is $\mu_{eff}^2 = (-2.76 \pm 1.46) \times 10^{-16} \mu_B^2$ which can be interpreted as an upper bound $|\mu_{eff}| < 3.71 \times 10^{-9} \mu_B$ (at $95$) on the neutrino magnetic moments.Comment: 7 pages, new references and some comments adde

Unravelling the transport mechanism of pore-filled membranes for hydrogen separation

The permeation characteristics of palladium pore filled (PF) membranes have been investigated with gas permeation and structural characterization of the membranes. PF membranes have been prepared by filling with Pd the nanoporous γ-Al2O3/YSZ (or pure YSZ) layer supported onto porous α-Al2O3 and ZrO2. The number of nanoporous layers and the applied vacuum level during the electroless plating process have been studied. Gas permeation properties of the PF membranes have been determined in a temperature range of 300-550 °C. The measured hydrogen permeances have been found to be lower than previously reported for similar membranes. It has been found that the hydrogen fluxes do not depend on the thickness of the nanoporous layers (γ-Al2O3/YSZ or pure YSZ) or on the vacuum pump employed for filling with Pd. The physicochemical characterization performed showed that the palladium deposited does not form a percolated network across the mesoporous layer(s), leading to low hydrogen permeances and thus low H2/N2 perm-selectivities.The presented work is funded within FERRET project as part of European Union’s Seventh Framework Programme (FP7/2007-2013) for the Fuel Cells and Hydrogen Joint Technology Initiative under grant agreement n° 621181. The Talos TEM was funded as part of HEFCE funding in the UK Research Partnership Investment Funding (UKRPIF) Manchester RPIF Round 2