Agglomerate properties

Modelling of wet granulation requires the rate of agglomerate coalescence to be estimated. Coalescence is dependent on the frequency of collisions that occur, and the fraction of collisions which result in coalescence. The collision rate is a function of granulator kinetics and powder properties, while the coalescence success rate is dependent on factors including the Stokes number and particle geometry. This work investigates an aspect of the geometry by examining the distribution of liquid on the surface of agglomerates in the capillary state. Agglomerates are created by adding particles, one at a time, about a central tetrahedral arrangement of four primary particles. For a given agglomerate, the wetted fraction of surface area, defined as the wetness, is evaluated using an approximate fluid surface. Packing density and binder saturation parameters are incorporated into the model. Given a number of primary particles and the volume of binder in a particle, the agglomerate wetness is able to be estimated using computational geometry

Solution of the Young-Laplace equation for three particles

This paper presents the solution to the liquid bridge profile formed between three equally sized spherical primary particles. The particles are equally separated, with sphere centres located on the vertices of an equilateral triangle. Equations for the problem are derived and solved numerically for given constant mean curvature H0, contact angle , and inter-particle separation distance S. The binding force between particles is calculated and plotted as a function of liquid bridge volume for a particular example. Agreement with experiment is provided

Comment on: Abou-Ali, H., El-Azony, H., El-Laithy, H., Haughton, J. and Khandker, S., 2010. Evaluating the impact of Egyptian Social Fund for Development Programmes. Journal of Development Effectiveness, 2 (4), 521–555

PRIFPRI3; ISIDG

Electrical activity of carbon-hydrogen centers in Si

The electrical activity of Cs-H defects in Si has been investigated in a combined modeling and experimental study. High-resolution Laplace capacitance spectroscopy with the uniaxial stress technique has been used to measure the stress-energy tensor and the results are compared with theoretical modeling. At low temperatures, implanted H is trapped as a negative-U center with a donor level in the upper half of the gap. However, at higher temperatures, H migrates closer to the carbon impurity and the donor level falls, crossing the gap. At the same time, an acceptor level is introduced into the upper gap making the defect a positive-U center

Short horizons and obesity futures: Disjunctures between public health interventions and everyday temporalities

This paper examines the spatio-temporal disjuncture between ‘the future’ in public health obesity initiatives and the embodied reality of eating. Drawing upon ethnographic fieldwork in a disadvantaged community in South Australia (August 2012–July 2014), we argue that the future oriented discourses of managing risk employed in obesity prevention programs have limited relevance to the immediacy of poverty, contingencies and survival that mark people's day to day lives. Extending Bourdieu's position that temporality is a central feature of practice, we develop the concept of short horizons to offer a theoretical framework to articulate the tensions between public health imperatives of healthy eating, and local ‘tastes of necessity’. Research undertaken at the time of Australia's largest obesity prevention program (OPAL) demonstrates that pre-emptive and risk-based approaches to health can fail to resonate when the future is not within easy reach. Considering the lack of evidence for success of obesity prevention programs, over-reliance on appeals to ‘the future’ may be a major challenge to the design, operationalisation and success of interventions. Attention to local rather than future horizons reveals a range of innovative strategies around everyday food and eating practices, and these capabilities need to be understood and supported in the delivery of obesity interventions. We argue, therefore, that public health initiatives should be located in the dynamics of a living present, tailored to the particular, localised spatio-temporal perspectives and material circumstances in which people live.Megan Warin, Tanya Zivkovic, Vivienne Moore, Paul R. Ward, Michelle Jone

Measurement of BOLD changes due to cued eye-closure and stopping during a continuous visuomotor task via model-based and model-free approaches

As a precursor for investigation of changes in neural activity underlying lapses of responsiveness, we set up a system to simultaneously record functional magnetic resonance imaging (fMRI), eye-video, EOG, and continuous visuomotor response inside an MRI scanner. The BOLD fMRI signal was acquired during a novel 2-D tracking task in which participants (10 males, 10 females) were cued to either briefly stop tracking and close their eyes (Stop Close) or to briefly stop tracking (Stop) only. The onset and duration of eye-closure and stopping were identified post hoc from eye-video, EOG, and visuomotor response. fMRI data were analyzed using a general linear model (GLM) and tensorial independent component analysis (TICA). The GLM-based analysis identified predominantly increased blood oxygenation level dependent (BOLD) activity during eye-closure and stopping in multisensory areas, sensory-motor integration areas, and default-mode regions. Stopping during tracking elicited increased activity in visual processing areas, sensory-motor integration areas, and premotor areas. TICA separated the spatio-temporal pattern of activity into multiple task-related networks including the 1) occipito-medial frontal eye-movement network, 2) sensory areas, 3) left-lateralized visuomotor network, and 4) fronto-parietal visuomotor network, which were modulated differently by Stop Close and Stop. The results demonstrate the merits of using simultaneous fMRI, behavioral, and physiological recordings to investigate the mechanisms underlying complex human behaviors in the human brain. Furthermore, knowledge of widespread modulations in brain activity due to voluntary eye-closure or stopping during a continuous visuomotor task is important for studies of the brain mechanisms underlying involuntary behaviors, such as microsleeps and attention lapses, which are often accompanied by brief eye-closure and/or response failures

Fracture toughness measurements on igneous rocks using a high-pressure, high-temperature rock fracture mechanics cell

A sound knowledge of mechanical properties of rocks at high temperatures and pressures is essential for modelling volcanological problems such as fracture of lava flows and dike emplacement. In particular, fracture toughness is a scale-invariant material property of a rock that describes its resistance to tensile failure. A new fracture mechanics apparatus has been constructed enabling fracture toughness measurements on large (60 mm diameter) rock core samples at temperatures up to 750–C and pressures up to 50 MPa. We present a full description of this apparatus and, by plotting fracture resistance as a function of crack length, show that the size of the samples is sufficient for reliable fracture toughness measurements. A series of tests on Icelandic, Vesuvian and Etnean basalts at temperatures from 30 to 600–C and confining pressures up to 30 MPa gave fracture toughness values between 1.4 and 3.8 MPa m1=2. The Icelandic basalt is the strongest material and the Etnean material sampled from the surface crust of a lava flow the weakest. Increasing temperature does not greatly affect the fracture toughness of the Etnean or Vesuvian material but the Icelandic samples showed a marked increase in toughness at around 150–C, followed by a return to ambient toughness levels. This material also became tougher under moderate confining pressure but the other two materials showed little change in toughness. We describe in terms of fracture mechanics probable causes for the changes in fracture toughness and compare our experimental results with values obtained from dike propagation modelling found in the literature

Multisensory cue combination after sensory loss: audio-visual localization in patients with progressive retinal disease

Human adults can combine perceptual estimates from different senses to minimize uncertainty, by taking a reliability-weighted average (the maximum likelihood estimate, MLE). Although research has shown that healthy human adults reweight estimates as their reliability changes from one trial to the next, less is known about how humans adapt to gradual long-term changes in sensory reliability. This study assessed whether individuals diagnosed with progressive visual deterioration, due to retinal disease, combined auditory and visual cues to location according to optimal (MLE) predictions. Twelve patients with central visual loss, 10 patients with peripheral visual loss, and 12 normally sighted adults were asked to localize visual and/or auditory targets in central (1°–18°) and peripheral (36°–53°) locations. Normally sighted adults and patients with peripheral visual loss showed multisensory uncertainty reduction and cue weighting in line with MLE predictions. In contrast, patients with central visual loss did not weight estimates appropriately in either the center or the periphery, and failed to meet MLE predictions in the periphery. Our results show that one visual loss patient group succeeded at optimal cue combination, whereas the other patient group (patients with central vision loss) did not. We propose that sensory remapping due to changes in fixation behavior may contribute to apparent failures in the latter group

Adatoms and nanoengineering of carbon

We present a new and general mechanism for inter-conversion of carbon structures via a catalytic exchange process, which operates under conditions of Frenkel pair generation. The mechanism typically lowers reaction barriers by a factor of four compared to equivilent uncatalysed reactions. We examine the relevance of this mechanism for fullerene growth, carbon onions and nanotubes, and dislocations in irradiated graphite.Comment: 3 Figures, 5 Page letter accepted for publication in Chemical Physics Letter

Characterisation, modification and mathematical modelling of sudsing

A programme of research is outlined which considers the foaming performance and foam behaviour of surfactant systems commonly encountered in hand-wash laundry detergent applications. An experimental study of the physical chemistry of foam generation indicates that precipitation of a typical anionic surfactant with calcium forms mesophase particles and causes a marked reduction in the rate of transport of surfactant to air–water surfaces and a concomitant reduction in foaming. Oily soil antifoam effects are however insensitive to the presence of calcium, being equally effective regardless of pH and calcium content. They may be reproduced by a simple particle–oil mixture of a saturated and an unsaturated triglyceride (e.g. tristearin and triolein respectively). A detailed foam rheometry study is performed using foam flowing through a constriction. Bubble shapes are used to deduce the normal and shear stresses across the foam flow field. Broad agreement between the experimental stress field and that obtained from quasistatic simulations is demonstrated. As foam flow-rate increases, a different model, which takes explicit account of viscous dissipative forces within the foam flow field is required. The dissipative foam flow model predicts differential shrinkage and stretch rates of foam films. Coupled to a model for surfactant transport, this shows the extent to which surfactant concentration accumulates in shrinking films and is depleted in stretching films. In addition to film stretching, it is also important to know about film bursting or failure rates. Here failure rates are estimated using capillary suction pressures exerted on the films by Plateau border channels around film edges. The failure rates can then be employed to predict the evolution of bubble size at various spatial locations in a foam: reasonable agreement with experimental bubble size distributions is obtained