A Kinetic Study of Hydrogen Peroxide Decomposition in Presence of Pyrite

The kinetics of hydrogen peroxide decomposition in presence of pyrite has been investigated in aqueous acidic media. It was found that hydrogen peroxide decomposition is double catalyzed by iron sites found on pyrite surface (a heterogeneous reaction) and aqueous ferric iron (a homogenous reaction). The heterogeneous reaction is first order with respect to [H2O2], and homogeneous reaction is first order with respect to [H2O2] and [Fe(aq)]. The rate is proportional to a fractional power of the geometric surface area (0.77) and [H+] (–0.55). The apparent activation energy of the hydrogen peroxide decomposition into oxygen and water at a temperature range of 25 to 45 °C was found to be 79.5 kJ mol–1

Interest-based RDF Update Propagation

Many LOD datasets, such as DBpedia and LinkedGeoData, are voluminous and process large amounts of requests from diverse applications. Many data products and services rely on full or partial local LOD replications to ensure faster querying and processing. While such replicas enhance the flexibility of information sharing and integration infrastructures, they also introduce data duplication with all the associated undesirable consequences. Given the evolving nature of the original and authoritative datasets, to ensure consistent and up-to-date replicas frequent replacements are required at a great cost. In this paper, we introduce an approach for interest-based RDF update propagation, which propagates only interesting parts of updates from the source to the target dataset. Effectively, this enables remote applications to `subscribe' to relevant datasets and consistently reflect the necessary changes locally without the need to frequently replace the entire dataset (or a relevant subset). Our approach is based on a formal definition for graph-pattern-based interest expressions that is used to filter interesting parts of updates from the source. We implement the approach in the iRap framework and perform a comprehensive evaluation based on DBpedia Live updates, to confirm the validity and value of our approach.Comment: 16 pages, Keywords: Change Propagation, Dataset Dynamics, Linked Data, Replicatio

Phase Diagram of Multilayer Magnetic Structures

Multilayer "ferromagnet-layered antiferromagnet" (Fe/Cr) structures frustrated due to the roughness of layer interfaces are studied by numerical modeling methods. The "thickness-roughness" phase diagrams for the case of thin ferromagnetic film on the surface of bulk antiferromagnet and for two ferromagnetic layers separated by an antiferromagnetic interlayer are obtained and the order parameter distributions for all phases are found. The phase transitions nature in such systems is considered. The range of applicability for the "magnetic proximity model" proposed by Slonczewski is evaluated.Comment: 8 pages, 8 figure

Prolate spheroidal hematite particles equatorially belt with drug-carrying layered double hydroxide disks: Ring Nebula-like nanocomposites

A new nanocomposite architecture is reported which combines prolate spheroidal hematite nanoparticles with drug-carrying layered double hydroxide [LDH] disks in a single structure. Spindle-shaped hematite nanoparticles with average length of 225 nm and width of 75 nm were obtained by thermal decomposition of hydrothermally synthesized hematite. The particles were first coated with Mg-Al-NO3-LDH shell and then subjected to anion exchange with salicylate ions. The resulting bio-nanohybrid displayed a close structural resemblance to that of the Ring Nebula. Scanning electron microscope and transmission electron microscopy images showed that the LDH disks are stacked around the equatorial part of the ellipsoid extending along the main axis. This geometry possesses great structural tunability as the composition of the LDH and the nature of the interlayer region can be tailored and lead to novel applications in areas ranging from functional materials to medicine by encapsulating various guest molecules

Time-Sensitive User Profile for Optimizing Search Personlization

International audienceThanks to social Web services, Web search engines have the opportunity to afford personalized search results that better fit the user’s information needs and interests. To achieve this goal, many personalized search approaches explore user’s social Web interactions to extract his preferences and interests, and use them to model his profile. In our approach, the user profile is implicitly represented as a vector of weighted terms which correspond to the user’s interests extracted from his online social activities. As the user interests may change over time, we propose to weight profiles terms not only according to the content of these activities but also by considering the freshness. More precisely, the weights are adjusted with a temporal feature. In order to evaluate our approach, we model the user profile according to data collected from Twitter. Then, we rerank initial search results accurately to the user profile. Moreover, we proved the significance of adding a temporal feature by comparing our method with baselines models that does not consider the user profile dynamics

A randomized controlled trial for overweight and obesity in preschoolers: the More and Less Europe study- an intervention within the STOP project

Background Childhood overweight and obesity is a serious public health issue with an increase being observed in preschool-aged children. Treating childhood obesity is difficult and few countries use standardized treatments. Therefore, there is a need to find effective approaches that are feasible for both health care providers and families. Thus, the overall aim of this study is to assess the acceptance and effectiveness of a parent support program (the More and Less, ML) for the management of overweight and obesity followed by a mobile health (mHealth) program (the MINISTOP application) in a socially diverse population of families. Methods/design A two-arm, parallel design randomized controlled trial in 300 2-to 6-year-old children with overweight and obesity from Romania, Spain and Sweden (n = 100 from each). Following baseline assessments children are randomized into the intervention or control group in a 1:1 ratio. The intervention, the ML program, consists of 10-weekly group sessions which focus on evidence-based parenting practices, followed by the previously validated MINISTOP application for 6-months to support healthy eating and physical activity behaviors. The primary outcome is change in body mass index (BMI) z-score after 9-months and secondary outcomes include: waist circumference, eating behavior (Child Eating Behavior Questionnaire), parenting behavior (Comprehensive Feeding Practices Questionnaire), physical activity (ActiGraph wGT3x-BT), dietary patterns (based on metabolic markers from urine and 24 h dietary recalls), epigenetic and gut hormones (fasting blood samples), and the overall acceptance of the overweight and obesity management in young children (semi-structured interviews). Outcomes are measured at baseline and after: 10-weeks (only BMI z-score, waist circumference), 9-months (all outcomes), 15- and 21-months (all outcomes except physical activity, dietary patterns, epigenetics and gut hormones) post-baseline. Discussion This study will evaluate a parent support program for weight management in young children in three European countries. To boost the effect of the ML program the families will be supported by an app for 6-months. If the program is found to be effective, it has the potential to be implemented into routine care to reduce overweight and obesity in young children and the app could prove to be a viable option for sustained effects of the care provided. Trial registration ClinicalTrials.gov NCT03800823; 11 Jan 2019

Fibrillization of Human Tau Is Accelerated by Exposure to Lead via Interaction with His-330 and His-362

and its mutants at physiological pH. interaction with His-330 and His-362, with sub-micromolar affinity. in the pathogenesis of Alzheimer disease and provide critical insights into the mechanism of lead toxicity