Simulation study of copper(I) and copper(II) species in ZSM-5 zeolite

Low energy configurations of CuI and CuII species in the ZSM-5 zeolite, probed by energy minimisation techniques, are found to be bound strongly to framework aluminium or copper species

Optical properties of irregular interstellar grains

In order to study the interaction of light with interstellar grains, the authors represent an irregular particle by a network of interacting dipoles whose polarizability is determined in a first approach by the Clausius-Mossoti relationship. Typically, 10,000 dipoles are considered. In the case of spherical particles, the results from Mie theory are fully recovered. The main interest of this method is to study with good accuracy the implications of surface roughness and/or inhomogeneities on optical properties in the infrared spectral range, particularly of the silicate emission features

Environmentally Adjusted Agricultural Productivity in the Great Plains

This study adjusts 1960-1996 agricultural productivity gains in a panel of Great Plains states to account for the discharge of pesticide and nitrogen effluents into the environment. The agricultural-environmental technology is approximated with translog distance functions that allow us to contrast traditional versus environmentally adjusted productivity gains. Findings indicate technical change has been increasingly biased toward environmentally friendly production. While the environmental adjustment reduced overall productivity gains during the sample period, in recent years adjusted productivity outpaced the traditional measure, reflecting the pro-environment bias in technical change.agricultural productivity, distance function, environmental externalities, nitrogen, pesticides, technical change bias, Environmental Economics and Policy, Productivity Analysis,

Pupil remapping for high contrast astronomy: results from an optical testbed

The direct imaging and characterization of Earth-like planets is among the most sought-after prizes in contemporary astrophysics, however current optical instrumentation delivers insufficient dynamic range to overcome the vast contrast differential between the planet and its host star. New opportunities are offered by coherent single mode fibers, whose technological development has been motivated by the needs of the telecom industry in the near infrared. This paper presents a new vision for an instrument using coherent waveguides to remap the pupil geometry of the telescope. It would (i) inject the full pupil of the telescope into an array of single mode fibers, (ii) rearrange the pupil so fringes can be accurately measured, and (iii) permit image reconstruction so that atmospheric blurring can be totally removed. Here we present a laboratory experiment whose goal was to validate the theoretical concepts underpinning our proposed method. We successfully confirmed that we can retrieve the image of a simulated astrophysical object (in this case a binary star) though a pupil remapping instrument using single mode fibers.Comment: Accepted in Optics Expres

Optimal estimates of the diffusion coefficient of a single Brownian trajectory

Modern developments in microscopy and image processing are revolutionizing areas of physics, chemistry and biology as nanoscale objects can be tracked with unprecedented accuracy. The goal of single particle tracking is to determine the interaction between the particle and its environment. The price paid for having a direct visualization of a single particle is a consequent lack of statistics. Here we address the optimal way of extracting diffusion constants from single trajectories for pure Brownian motion. It is shown that the maximum likelihood estimator is much more efficient than the commonly used least squares estimate. Furthermore we investigate the effect of disorder on the distribution of estimated diffusion constants and show that it increases the probability of observing estimates much smaller than the true (average) value.Comment: 8 pages, 5 figure

Updated results on prototype chalcogenide fibers for 10-um wavefront spatial filtering

The detection of terrestrial planets by Darwin/TPF missions will require extremely high quality wavefronts. Single-mode fibers have proven to be powerful beam cleaning components in the near-infrared, but are currently not available in the mid-infrared where they would be critically needed for Darwin/TPF. In this paper, we present updated measurements on the prototype chalcogenide fibers we are developing for the purpose of mid-infrared spatial filtering. We demonstrate the guiding property of our 3rd generation component and we characterize its filtering performances on a 4 mm length: the far-field radiation pattern matches a Gaussian profile at the level of 3% rms and 13% pk-pk.Comment: 4 pages, 5 figures, to appear in the proceedings of the conference "Toward Other Earths, Darwin/TPF and the search for extrasolar terrestrial planets", held in Heidelberg, Germany, 22-25 April 2003, ESA SP-53

Efficiency of New Ethanol Plants in the U.S. North-Central Region

Replaced with revised version of paper 07/29/09.Ethanol, Efficiency, DEA, Production Economics, Resource /Energy Economics and Policy,

Functional Methods and Effective Potentials for Nonlinear Composites

A formulation of variational principles in terms of functional integrals is proposed for any type of local plastic potentials. The minimization problem is reduced to the computation of a path integral. This integral can be used as a starting point for different approximations. As a first application, it is shown how to compute to second-order the weak-disorder perturbative expansion of the effective potentials in random composite. The three-dimensional results of Suquet and Ponte-Casta\~neda (1993) for the plastic dissipation potential with uniform applied tractions are retrieved and extended to any space dimension, taking correlations into account. In addition, the viscoplastic potential is also computed for uniform strain rates.Comment: 20 pages, accepted for publication in JMP