5,910 research outputs found
Investigation of the surface structure and activity of molybdenum oxide-containing catalysts : I. An infrared study of the surface structure of molybdena-alumina catalysts
A comparison has been made of the infrared spectra of alumina with molybdenum oxide-alumina in both the oxidized and reduced forms. In the case of molybdena-alumina prepared via adsorption of gaseous MoO2(OH)2, the spectra show that a practically complete monolayer of Mo6+ oxide covers the alumina. After reduction with hydrogen the hydroxyls of the carrier appear. From the reversibility of reduction and oxidation under mild conditions it has been established that the reduced oxide is present as an interrupted monolayer
Spatially encoded light for Large-alphabet Quantum Key Distribution
Most Quantum Key Distribution protocols use a two-dimensional basis such as
HV polarization as first proposed by Bennett and Brassard in 1984. These
protocols are consequently limited to a key generation density of 1 bit per
photon. We increase this key density by encoding information in the transverse
spatial displacement of the used photons. Employing this higher-dimensional
Hilbert space together with modern single-photon-detecting cameras, we
demonstrate a proof-of-principle large-alphabet Quantum Key Distribution
experiment with 1024 symbols and a shared information between sender and
receiver of 7 bit per photon.Comment: 9 pages, 6 figures, Added references, Updated Fig. 1 in the main
text, Updated Fig.1 in supplementary material, Added section Trojan-horse
attacks in supplementary material, title changed, Added paragraphs about
final key rate and overfilling the detector to result sectio
Een patiënt met Legionairsziekte in Nederland
Contains fulltext :
4301.pdf (publisher's version ) (Open Access
Temperature anisotropy in a driven granular gas
When smooth granular material is fluidized by vertically shaking a container, we find that the temperature in the direction of energy input always exceeds the temperature in the other directions. An analytical model is presented which shows how the anisotropy can be traced back to the inelasticity of the interparticle collisions and the collisions with the wall. For a dilute granular gas, the model compares very well with molecular-dynamics simulations. It is concluded that any non-isotropic driving of a granular gas in a steady state necessarily causes anisotropy of the granular temperature
Surface structure and catalytic activity of a reduced molybdenum oxide-alumina catalyst. 1. The adsorption of pyridine in relation with the molybdenum valence
Longtitudinal electron beam diagnostics via upconversion of THz to visible radiation
Longitudinal electro-optic electron bunch diagnostics has been successfully applied at several accelerators. The electro-optic effect can be seen as an upconversion of the Coulomb field of the relativistic electron bunch (THz radiation) to the visible spectral range, where a variety of standard diagnostic tools are available. Standard techniques to characterise femtosecond optical laser pulses (auto- and cross-correlators) have led to the schemes that can measure electron bunch profiles with femtosecond resolution. These techniques require, however, well synchronized femtosecond laser pulses, in order to obtain the desired temporal resolution. Currently, we are exploring other electro-optic variants which require less advanced laser systems and will be more amenable to beam based longitudinal feedback applications. The first results of one such new scheme will be presented in this paper
Modeling Transverse Cracking in Laminates With a Single Layer of Elements Per Ply
The objective of the present paper is to investigate the ability of mesolevel X-FEM models with a single layer of elements per ply to capture accurately all aspects of matrix cracking. In particular, we examine whether the model can predict the insitu ply thickness effect on crack initiation and propagation, the crack density as a function of strain, the strain for crack saturation, and the interaction between delamination and transverse cracks. Results reveal that the simplified model does not capture correctly the shear-lag relaxation of the stress field on either side of a crack, which leads to an overprediction of the crack density. It is also shown, however, that after onset of delamination many of the inserted matrix cracks close again, and that the density of open cracks becomes similar to the density predicted by the detailed model. The degree to which the spurious cracks affect the global response is quantified and the reliability of the mesolevel approach with a single layer of elements per ply is discussed
Above-ground biomass and productivity in a rain forest of eastern South America
Abstract: The dynamics of tropical forest woody plants was studied at the Nouragues Field Station, central French Guiana. Stem density, basal area, above-ground biomass and above-ground net primary productivity, including the contribution of litterfall, were estimated from two large permanent census plots of 12 and 10 ha, established on contrasting soil types, and censused twice, first in 1992¿1994, then again in 2000¿2002. Mean stem density was 512 stems ha¿1 and basal area, 30m2 ha¿1. Stem mortality rate ranged between 1.51% and 2.06% y¿1. In both plots, stem density decreased over the study period. Using a correlation between wood density and wood hardness directly measured by a Pilodyn wood tester,we found that the mean wood densitywas 0.63 g cm¿3, 12% smaller than the mean of wood density estimated from the literature values for the species occurring in our plot. Above-ground biomass ranged from 356 to 398Mgha¿1 (oven-dry mass), and it increased over the census period. Leaf biomass was 6.47Mg ha¿1. Our total estimate of aboveground net primary productivity was 8.81 MgC ha¿1 y¿1 (in carbon units), not accounting for loss to herbivory, branchfalls, or biogenic volatile organic compounds, whichmay altogether account for an additional 1MgC ha¿1 y¿1. Coarse wood productivity (stem growth plus recruitment) contributed to 4.16 MgC ha¿1 y¿1. Litterfall contributed to 4.65MgC ha¿1 y¿1 with 3.16 MgC ha¿1 y¿1 due to leaves, 1.10 MgC ha¿1 y¿1 to twigs, and 0.39MgC ha¿1 y¿1 to fruits and flowers. The increase in above-ground biomass for both trees and lianas is consistentwith the hypothesis of a shift in the functioning of Amazonian rain forests driven by environmental changes, although alternative hypotheses such as a recovery from past disturbances cannot be ruled out at our site, as suggested by the observed decrease in stem density. Key Words: above-ground biomass, carbon, French Guiana, net primary productivity, tropical fores
A numerical investigation on the vortex formation and flow separation of the oscillatory flow in jet pumps
A two-dimensional computational fluid dynamics model is used to predict the
oscillatory flow through a tapered cylindrical tube section (jet pump) placed
in a larger outer tube. Due to the shape of the jet pump, there will exist an
asymmetry in the hydrodynamic end effects which will cause a time-averaged
pressure drop to occur that can be used to cancel Gedeon streaming in a
closed-loop thermoacoustic device. The performance of two jet pump geometries
with different taper angles is investigated. A specific time-domain impedance
boundary condition is implemented in order to simulate traveling acoustic wave
conditions. It is shown that by scaling the acoustic displacement amplitude to
the jet pump dimensions, similar minor losses are observed independent of the
jet pump geometry. Four different flow regimes are distinguished and the
observed flow phenomena are related to the jet pump performance. The simulated
jet pump performance is compared to an existing quasi-steady approximation
which is shown to only be valid for small displacement amplitudes compared to
the jet pump length.Comment: The following article has been accepted by the Journal of the
Acoustical Society of America. After it is published, it will be found at:
http://scitation.aip.org/JAS
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