Flow Blurring-Enabled Production of Polymer Filaments from Poly(ethylene oxide) Solutions

Flow blurring (FB) atomizers are relatively simple yet robust devices used for the generation of sprays from solutions of a wide range of viscosities. In this work, we have demonstrated that FB devices may also be applied for massive production of liquid filaments from polymeric solutions. They can later be transformed into solid filaments and fibers, leading to the production of so-called fiber mats. The liquid precursors consisted of poly(ethylene oxide) (PEO) solutions of varying molecular weights (105 [100k] to 4 × 106 g/mol [4M]) and concentrations. The FB device was operated in the gas pressure range of 3−6 bar. Except for solutions of PEO 100k, all solutions exhibited a shear thinning behavior. For massive filament production, a threshold polymer concentration (ct) was identified for each molecular weight. Below such concentration, the atomization resulted in droplets (the classical FB functioning mode). Such a threshold value decreased as the PEO molecular weight increased, and it coincides with the polymer coil overlap concentration, c*. The viscoelastic nature of the solutions was also observed to increase with the molecular weight. A 3.2 dependency of the zero-shear rate viscosity on a so-called Bueche parameter was found for filament production, whereas a nearly linear dependency was found for droplet production. In general, the mean diameter of the filaments decreased as they traveled downstream from the atomization point. Furthermore, at a given distance from the atomizer outlet and gas pressure, the mean filament diameter slightly shifted toward larger sizes with increasing PEO molecular weight. The tendency agrees well with the calculated filaments’ Deborah number, which increases with PEO molecular weight. The approach presented herein describes a highthroughput and efficient method for the massive production of viscous filaments. These may be transformed into fibers by an on-line drying step.Ministerio de Economía y Competitividad DPI2016-78887-C3-1-

Using artificial neural networks to predict impingement and dislocation in total hip arthroplasty

Dislocation after total hip arthroplasty (THA) remains a major issue and an important post-surgical complication. Impingement and subsequent dislocation are influenced by the design (head size) and position (anteversion and abduction angles) of the acetabulum and different movements of the patient, with external extension and internal flexion the most critical movements. The aim of this study is to develop a computational tool based on a three-dimensional (3D) parametric finite element (FE) model and an artificial neural network (ANN) to assist clinicians in identifying the optimal prosthesis design and position of the acetabular cup to reduce the probability of impingement and dislocation. A 3D parametric model of a THA was used. The model parameters were the femoral head size and the acetabulum abduction and anteversion angles. Simulations run with this parametric model were used to train an ANN, which predicts the range of movement (ROM) before impingement and dislocation. This study recreates different configurations and obtains absolute errors lower than 5.5° between the ROM obtained from the FE simulations and the ANN predictions. The ROM is also predicted for patients who had already suffered dislocation after THA, and the computational predictions confirm the patient’s dislocations. Summarising, the combination of a 3D parametric FE model of a THA and an ANN is a useful computational tool to predict the ROM allowed for different designs of prosthesis heads

Structure and mineralogy of a gold ore body of shear zone origin: the Fosas de Vila ore. La Coruña. Spain

[Abstract] This paper studies a shear zone containing a gold-bearing milonitic body, in which, evidences of several mining works are still visible. The geometry of the structure is described, as well as the different evolutive stages of the milonitic body and the mineralizations associated with them

Nonlinear Interaction of Transversal Modes in a CO2 Laser

We show the possibility of achieving experimentally a Takens-Bogdanov bifurcation for the nonlinear interaction of two transverse modes ($l = \pm 1$) in a $CO_2$ laser. The system has a basic O(2) symmetry which is perturbed by some symmetry-breaking effects that still preserve the $Z_2$ symmetry. The pattern dynamics near this codimension two bifurcation under such symmetries is described. This dynamics changes drastically when the laser properties are modified.Comment: 16 pages, 0 figure

Detection and identification methods and new tests as developed and used in the framework of cost 873 for bacteria pathogenic to stone fruits and nuts

Xanthomonas arboricola pv. pruni (Xap), the causal agent of bacterial spot disease of stone fruits and almond, is regulated as a quarantine pathogen in the European Union and the European and Mediterranean Plant Protection Organization (EPPO). Xap can have an epiphytic phase and/or be latent and, consequently, it can be transmitted by different types of plant material. Effective quarantine measures require specific, sensitive and rapid methods to detect Xap in propagative material or new reservoirs. Laborious and time-consuming methods for the diagnosis of Xap are recommended in the current EPPO standard protocol. However, new several pathogen-specific PCR and quantitative realtime PCR assays have been developed that enable direct detection of Xap in symptomatic and symptomless plant samples. A concise resource of current methods for Xap detection and identification, based on assessment and development activities within the framework of COST 873, is presented

Assessing children's interpersonal emotion regulation with virtual agents: The serious game Emodiscovery

publisher: Elsevier articletitle: Assessing children's interpersonal emotion regulation with virtual agents: The serious game Emodiscovery journaltitle: Computers & Education articlelink: http://dx.doi.org/10.1016/j.compedu.2018.04.005 content_type: article copyright: © 2018 Elsevier Ltd. All rights reserved

Modification of characters linked to Cucurbita maxima domestication. Using morphometry as a tool for identification

El objetivo de este trabajo consiste en reconocer patrones de variación morfométrica –mediante la aplicación de análisis multivariado para tamaño y forma- en semillas de C. maxima que sean diagnósticos para formas domesticadas, silvestres e híbridas actuales, a fin de aplicarlos a la identificación de semillas arqueológicas. Para lograr este objetivo se midieron con calibre digital 1317 semillas de las formas antedichas y de nueve sitios arqueológicos de Argentina y Perú. Se exploró el patrón de variación entre las mismas en tamaño y forma mediante análisis multivariado. Se identificó una tendencia general hacia la disminución de la variabilidad en forma y tamaño a lo largo del tiempo, con una primera etapa donde se mantuvieron ejemplares híbridos, generándose nuevas formas y una segunda donde se mantuvieron los rasgos de momentos previos y el aumento del tamaño de las semillas

Late Quaternary tectono-sedimentary processes on an isolated offshore high marginal platform (NW Iberian Continental Margin)

Studies of the most surficial sedimentary record from passive continental margins provide crucial knowledge about sedimentary dynamics and its changes through recent geological times. These studies allow understanding in detail the influence of both tectonic activity and long-term bottom-current circulation over the Late Quaternary sedimentary dynamics. Using a large dataset of multibeam bathymetry, chirp and multi-channel seismic (MCS) records, ROV seabed direct observations and a magneto-chemical facies characterisation, we provide a well-dated record of the tectono-sedimentary processes on an isolated high marginal platform over the Late Quaternary. Our results display several structural and geomorphological features and tectonic pulses that indicate intense faulting, folding, and deformation of the most recent sedimentary cover. Furthermore, we document four main sedimentary systems acting at the study area and controlled by different water masses (MOW, LSW and NADW): the (hemi)pelagic, bottom current-controlled (hemi)pelagic, contourite and downslope sedimentary systems; as well as a new typology of contourite associated to giant depressions, named as pockmarks-related drift. The record also shows erosive features and extremely low sedimentation rates for the last 172 cal ka BP. Results suggest that the topographic configuration of the high marginal platform and reorganizations of the water masses associated to climate changes causes a constriction of the water masses that induce an enhancement of the bottom-current activity, favouring erosion, winnowing and redistribution of sediments. Therefore, this study provides new insight into the tectonic control and bottom current activity effect over the Late Quaternary sedimentary cover from an isolated and elevate offshore morphostructural province, located at the Galician Continental Margin.publishe

Application of multivariate statistical analyses to Itrax core scanner data for the identification of deep-marine sedimentary facies: a case study in the Galician Continental Margin

The validity and usefulness of multivariate statistical tools for the facies characterization in deep-marine environments have been applied on the geochemical, sedimentological and magnetic data from a piston core extracted from the Transitional Zone in the Galician Continental Margin. The combination of geochemical profiles of Fe, Mn, Ti, Ba and Ca and magnetic susceptibility (MS) obtained using the ItraxTM Core Scanner at the University of Vigo, together with the grain-size, grey level and R (red) G (green) B (blue) colour analyses have allowed characterizing and classifying the sediments of the core PC13-3 using SPSS package v. 23. Cluster Analysis (CA) displays, in the first level of the hierarchy, two major groups that correspond with clay-silt and sand facies. In a second level, it is possible to observe six subfacies that match de visu preliminary classification and allowed us to complete and improve the characterization and the facies limits in the whole core. Discriminant Analysis (DA) confirmed the validity of the cluster analyses and enhanced the results of the classification. The Principal Component Analysis (PCA) shows four principal components: coarse lithogenic fraction (PC1), fine lithogenic fraction (PC2), high density fraction (PC3) and biogenic fraction (PC4). These results are in concordance with the Pearson correlation coefficient and the SEM observations. In general terms, the results confirm the utility of the multivariate statistical methods applied on high resolution geochemical and magnetic data acquired with ItraxTM corer scanner, as a quick and complementary tool in sedimentary facies analysis and description in deep marine environments.publishe

Threading Through Macrocycles Enhances the Performance of Carbon Nanotubes as Polymer Fillers

In this work we study the reinforcement of polymers by mechanically interlocked derivatives of single-walled carbon nanotubes (SWNTs). We compare the mechanical properties of fibers made of polymers and of composites with pristine single-walled carbon nanotubes (SWNTs), mechanically interlocked derivatives of SWNTs (MINTs) and the corresponding supramolecular models. Improvements of both Young's modulus and tensile strength of up to 200 % were observed for the polystyrene-MINTs samples with an optimized loading of just 0.01 wt.%, while the supramolecular models with identical chemical composition and loading showed negligible or even detrimental influence. This behavior is found for three different types of SWNTs and two types of macrocycles. Molecular dynamics simulations show that the polymer adopts an elongated conformation parallel to the SWNT when interacting with MINT fillers, irrespective of the macrocycle chemical nature, whereas a more globular structure is taken upon facing with either pristine SWNTs or supramolecular models. The MINT composite architecture thus leads to a more efficient exploitation of the axial properties of the SWNTs and of the polymer chain at the interface, in agreement with experimental results. Our findings demonstrate that the mechanical bond imparts distinctive advantageous properties to SWNT derivatives as polymer fillers.Comment: 39 pages, 19 figure