264 research outputs found

    New Labour ambiguity, or Neo-liberal consistency? The debate about racial inequality in employment and the use of contract compliance

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    Many historical studies, some of them comparative, have explored the foundations of welfare states and the birth of unemployment policies in Europe in the late nineteenth century. Nearly all have focused on political debate at national level. This paper bases its analysis on labour market reforms initiated in Strasbourg and Liverpool in the decades preceding World War I. It explores how bona fide unemployed workers, the proper clients of official help, were distinguished from the mass of the poor and indigent. The labour market had to be defined and organized before policies for the unemployed could be put in place. The object is to demonstrate not only how this was done, but also how different perceptions of social justice and economic efficiency influenced both the process and the outcomes of public interventions, in this instance undermining attempts to transfer specific policies from one country to another

    Hysteretic thermal spin-crossover in heteroleptic Fe(II) complexes using alkyl chain substituted 2,2’-dipyridylamine ligands

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    The alkyl chain carrying ligands N,N-di(pyridin-2-yl)butanamide (LC4) and N,N-di(pyridin-2-yl)decanamide (LC10) were combined with NCS− co-ligands to form the neutral heteroleptic Fe(II) complexes trans-[FeII(LC4)2(NCS)2] (1C4) and trans-[FeII(LC10)2(NCS)2] (1C10). Variable temperature crystallographic studies revealed that 1C4 is in the orthorhombic space group Pna21 between 85–200 K whereas 1C10 is in the monoclinic space group P21/c between 85–140 K. The average Fe–N bond lengths suggest that at 85 K 1C4 contains LS Fe(II) centres; however, the ca. 0.18 Å increase in the average Fe–N bond lengths between 85 and 120 K suggests a spin-transition to the HS state occurs within this temperature interval. 1C10 contains LS Fe(II) centres between 85 and 105 K. Upon warming from 105 to 140 K the average Fe–N bond lengths increase by ca. 0.19 Å, which suggests a spin-transition to the HS state. Solid-state magnetic susceptibility measurements showed that 1C4 undergoes semi-abrupt spin-crossover with T1/2 = 127.5 K and a thermal hysteresis of ca. 13 K whereas, 1C10 undergoes an abrupt spin-crossover with T1/2 = 119.0 K, and is also accompanied by thermal hysteresis of ca. 4 K. The crystallographic and magnetic data show that the length of the complex's alkyl chain substituents can have a large impact on the structure of the crystal lattice as well as a subtle effect on the T1/2 value for thermal spin-crossover

    Supercritical Fluids for Higher Extraction Yields of Lipids from Archeological Ceramics

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    The extraction and study of organic residues from ceramics has been a subject of interest for the last 50 years in archeology and archeological science. Lipids are among the best-preserved organic substances in archeological contexts and can provide information about the diets of ancient populations as well as past environments. Here, we present a method which demonstrates significantly improved extraction of lipids from archeological pots by replacing liquid organic solvents with supercritical fluids. Optimization of the procedure using response surface methodology (RSM) approach showed that, on our system, optimal conditions for supercritical extraction of lipids from synthetic fired clay ceramics could be achieved using carbon dioxide with 16 vol % of cosolvent EtOH–H2O (95:5 v/v) in 90 min at a flow rate of 2.3 mL/min, for a pressure of 30 MPa and a temperature of 50 °C. For all reference and archeological samples included in this study, lipid yields obtained by supercritical fluid extraction under these optimal conditions were systematically higher than by conventional solvent extraction. This study also highlighted a variability of the ratio of unsaturated versus saturated fatty acids depending on the extraction method. This can have important implications in the identification of the residue(s). The increased extraction efficiency provided by supercritical fluids, as well as their minimally destructive nature, enable new and refined approaches to residue analysis and dating of archeological ceramics

    Dynamics of Jupiter’s atmosphere

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    Giant planet atmospheres provided many of the surprises and remarkable discoveries of planetary exploration during the past few decades. Studying Jupiter's atmosphere and comparing it with Earth's gives us critical insight and a broad understanding of how atmospheres work that could not be obtained by studying Earth alone

    ICTV Virus Taxonomy Profile: Bromoviridae

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    [EN] Bromoviridae is a family of plant viruses with tri-segmented, positive-sense, single-stranded RNA genomes of about 8 kb in total. Genomic RNAs are packaged in separate virions that may also contain subgenomic, defective or satellite RNAs. Virions are variable in morphology (spherical or bacilliform) and are transmitted between hosts mechanically, in/on the pollen and non-persistently by insect vectors. Members of the family are responsible for major disease epidemics in fruit, vegetable and fodder crops such as tomato, cucurbits, bananas, fruit trees and alfalfa. This is a summary of the International Committee on Taxonomy of Viruses (ICTV) Report on the family Bromoviridae, which is available at www.ictv.global/report/bromoviridae.Production of this summary, the online chapter and associated resources was funded by a grant from the Wellcome Trust (WT108418AIA). Members of the ICTV (10th) Report Consortium are Elliot J. Lefkowitz, Andrew J. Davison, Stuart G. Siddell, Peter Simmonds, Sead Sabanadzovic, Donald B. Smith, Richard J. Orton and F. Murilo Zerbini.Bujarski, J.; Gallitelli, D.; Garcia, F.; PallĂĄs Benet, V.; Palukaitis, P.; Reddy, M.; Wang, A.... (2019). ICTV Virus Taxonomy Profile: Bromoviridae. Journal of General Virology. 100(8):1206-1207. https://doi.org/10.1099/jgv.0.001282S120612071008Pallas, V., Aparicio, F., Herranz, M. C., Sanchez-Navarro, J. A., & Scott, S. W. (2013). The Molecular Biology of Ilarviruses. Advances in Virus Research, 139-181. doi:10.1016/b978-0-12-407698-3.00005-3Hanssen, I. M., & Lapidot, M. (2012). Major Tomato Viruses in the Mediterranean Basin. Viruses and Virus Diseases of Vegetables in the Mediterranean Basin, 31-66. doi:10.1016/b978-0-12-394314-9.00002-6Jacquemond, M. (2012). Cucumber Mosaic Virus. Viruses and Virus Diseases of Vegetables in the Mediterranean Basin, 439-504. doi:10.1016/b978-0-12-394314-9.00013-0Pallas, V., Aparicio, F., Herranz, M. C., Amari, K., Sanchez-Pina, M. A., Myrta, A., & Sanchez-Navarro, J. A. (2012). Ilarviruses of Prunus spp.: A Continued Concern for Fruit Trees. PhytopathologyÂŽ, 102(12), 1108-1120. doi:10.1094/phyto-02-12-0023-rv

    Bisimulation as path type for guarded recursive types

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    In type theory, coinductive types are used to represent processes, and are thus crucial for the formal verification of non-terminating reactive programs in proof assistants based on type theory, such as Coq and Agda. Currently, programming and reasoning about coinductive types is difficult for two reasons: The need for recursive definitions to be productive, and the lack of coincidence of the built-in identity types and the important notion of bisimilarity. Guarded recursion in the sense of Nakano has recently been suggested as a possible approach to dealing with the problem of productivity, allowing this to be encoded in types. Indeed, coinductive types can be encoded using a combination of guarded recursion and universal quantification over clocks. This paper studies the notion of bisimilarity for guarded recursive types in Ticked Cubical Type Theory, an extension of Cubical Type Theory with guarded recursion. We prove that, for any functor, an abstract, category theoretic notion of bisimilarity for the final guarded coalgebra is equivalent (in the sense of homotopy type theory) to path equality (the primitive notion of equality in cubical type theory). As a worked example we study a guarded notion of labelled transition systems, and show that, as a special case of the general theorem, path equality coincides with an adaptation of the usual notion of bisimulation for processes. In particular, this implies that guarded recursion can be used to give simple equational reasoning proofs of bisimilarity. This work should be seen as a step towards obtaining bisimilarity as path equality for coinductive types using the encodings mentioned above

    Emitted Power Of Jupiter Based On Cassini CIRS And VIMS Observations

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    The emitted power of Jupiter and its meridional distribution are determined from observations by the Composite Infrared Spectrometer (CIRS) and Visual and Infrared Spectrometer (VIMS) onboard Cassini during its flyby en route to Saturn in late 2000 and early 2001. Jupiter's global- average emitted power and effective temperature are measured to be 14.10+/-0.03 W/sq m and 125.57+/-0.07 K, respectively. On a global scale, Jupiter's 5-micron thermal emission contributes approx. 0.7+/-0.1 % to the total emitted power at the global scale, but it can reach approx. 1.9+/-0.6% at 15degN. The meridional distribution of emitted power shows a significant asymmetry between the two hemispheres with the emitted power in the northern hemisphere 3.0+/-0.3% larger than that in the southern hemisphere. Such an asymmetry shown in the Cassini epoch (2000-01) is not present during the Voyager epoch (1979). In addition, the global-average emitted power increased approx. 3.8+/-1.0% between the two epochs. The temporal variation of Jupiter's total emitted power is mainly due to the warming of atmospheric layers around the pressure level of 200 mbar. The temporal variation of emitted power was also discovered on Saturn (Li et al., 2010). Therefore, we suggest that the varying emitted power is a common phenomenon on the giant planets
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