Transition metal catalyzed element–element′ additions to alkynes

The efficient and stereoselective synthesis of, or precursors to, multi-substituted alkenes has attracted substantial interest due to their existence in various industrially and biologically important compounds. One of the most atom economical routes to such alkenes is the transition metal catalyzed hetero element–element′ π-insertion into alkynes. This article provides a thorough up-to-date review on this area of chemistry, including discussions on the mechanism, range of Esingle bondE′ bonds accessible and the stoichiometric/catalytic transition metal mediators employed

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京都大学0048新制・課程博士工学博士甲第1663号工博第437号新制||工||316(附属図書館)4473UT51-50-I114京都大学大学院工学研究科合成化学専攻(主査)教授 熊田 誠, 教授 古川 淳二, 教授 三枝 武夫学位規則第5条第1項該当Kyoto UniversityDA