Modeling water regulation ecosystem services: A review in the context of ecosystem accounting

Natural Capital Accounting (NCA) has evolved rapidly in recent years through substantial efforts of both international organizations and the scientific community. Water regulation ecosystem services (ES) are key elements of regulating services in ecosystem accounting, with most relevant studies strongly relying on models for ES quantification up to now. In this paper, we provide a review of modeling efforts for water regulation ES based on 148 scientific papers, properly systematized, analyzed and interpreted by using a detailed and structured original template. We examined emerging trends and gaps in model applications and the readiness to integrate them into the NCA and SEEA-EA frameworks. We propose a classification scheme which organizes the 92 different models and modeling approaches identified in the review process into eight model categories so that this scheme can be efficiently used in the water ES assessment of and for further integration into the accounting framework. Among the models, the hydrologic model SWAT and the modeling tool InVEST are by far the most popular. The results of the review revealed differences between the general ES literature and the accounting-related papers. Moreover, our analysis sets the basis for useful recommendations of which model categories are the most appropriate for the water regulation ES, included in the SEEA-EA reference list. Based on the number of relevant papers, the reliability and the confidence level of the recommendations for the use of models have been incorporated in our analysis. We highlight as model category with the highest confidence the ones relative to quantification water flow and flood control service aiming at ES accounting. Models for erosion control ES can only be recommended with a lower confidence, while for water purification the results lack clear evidence for using a particular group of models. Based on the research findings we identified the main research priorities on model integration in the accounting of water regulation ES: 1) further development of guidelines for the use of models in ecosystem accounting; 2) analyses of the spatial aspects of the model towards a clear distinction between ecosystem service supply and use; and 3) development of integrated modeling approaches for water regulation ES accounting. © 2022 The Author(s

“Magnetic Force Microscopy and Energy Loss Imaging of Superparamagnetic Iron Oxide Nanoparticles”

We present quantitative, high spatially resolved magnetic force microscopy imaging of samples based on 11 nm diameter superparamagnetic iron oxide nanoparticles in air at room temperature. By a proper combination of the cantilever resonance frequency shift, oscillation amplitude and phase lag we obtain the tip-sample interaction maps in terms of force gradient and energy dissipation. These physical quantities are evaluated in the frame of a tip-particle magnetic interaction model also including the tip oscillation amplitude. Magnetic nanoparticles are characterized both in bare form, after deposition on a flat substrate, and as magnetically assembled fillers in a polymer matrix, in the form of nanowires. The latter approach makes it possible to reveal the magnetic texture in a composite sample independently of the surface topography

Effect of the molecular structure of the polymer and nucleation on the optical properties of polypropylene homo- and copolymers.

Two soluble nucleating agents were used to modify the optical properties of nine PP homo- and random copolymers. The ethylene content of the polymers changed between 0 and 5.3 wt%. Chain regularity was characterized by the stepwise isothermal segregation technique (SIST), while optical properties by the measurement of the haze of injection molded samples. Crystallization and melting characteristics were determined by differential scanning calorimetry (DSC). The analysis of the results proved that lamella thickness and change in crystallinity influence haze only slightly. A model was introduced which describes quantitatively the dependence of nucleation efficiency and haze on the concentration of the nucleating agent. The model assumes that the same factors influence the peak temperature of crystallization and optical properties. The analysis of the results proved that the assumption is valid under the same crystallization conditions. The parameters of the model depend on the molecular architecture of the polymer. Chain regularity determines supermolecular structure and thus the dependence of optical properties on nucleation

European agricultural landscapes, common agricultural policy and ecosystem services: a review

Since the 1950s, intensification and scale enlargement of agriculture have changed agricultural landscapes across Europe. The intensification and scale enlargement of farming was initially driven by the large-scale application of synthetic fertilizers, mechanization and subsidies of the European Common Agricultural Policy (CAP). Then, after the 1990s, a further intensification and scale enlargement, and land abandonment in less favored areas was caused by globalization of commodity markets and CAP reforms. The landscape changes during the past six decades have changed the flows and values of ecosystem services. Here, we have reviewed the literature on agricultural policies and management, landscape structure and composition, and the contribution of ecosystem services to regional competitiveness. The objective was to define an analytical framework to determine and assess ecosystem services at the landscape scale. In contrast to natural ecosystems, ecosystem service flows and values in agricultural landscapes are often a result of interactions between agricultural management and ecological structures. We describe how land management by farmers and other land managers relates to landscape structure and composition. We also examine the influence of commodity markets and policies on the behavior of land managers. Additionally, we studied the influence of consumer demand on flows and values of the ecosystem services that originate from the agricultural landscape

Behavior of Co2+Co^{2+} Cations in the Aqueous and Alcoholic Solution of CoCl2⋅6H2OCoCl_2 \cdot 6H_2O

We investigated the optical properties of $Co^{2+}$ cations in the aqueous and alcoholic solution of $CoCl_2 \cdot 6H_2O$ at room temperature. We measured the absorption spectra of these solutions in the spectral region 395-800 nm. The Racah parameters and the exchange integrals of the aqueous complex $[Co(H_2O)_6]^{2+}$ are calculated. The parameters $D_{t}$ and $D_{s}$ are also calculated on the basis of our experimental data. The parameters δ σ and δπ which are connected with the symmetry of this complex are also determined

Urbach's Rule in Undoped and Co Doped (80−x)Sb2O3−20Na2O−xWO3(80-x)Sb_2O_3-20Na_2O-xWO_3 Glasses

We have analyzed the Co influence on the absorption spectra of $(80-x)Sb_2O_3-20Na_2O-xWO_3$ glasses in the Urbach rule region at room temperature. We present the comparison between Co and $WO_3$ manifestation in the spectral region 2.64-3.14 eV. The spectral characteristics of "crystalline" and "glassy" Urbach's rule are also calculated