A Tylosaurine Mosasauridae (Squamata) from the Late Cretaceous of the Basque-Cantabrian Region

An isolated mosasaurid tooth from the Campanian of Alava (Basque Country), previously referred to as cf. Mosasaurus sp., is here reattributed to a tylosaurine. It may belong to Tylosaurus, a nearly cosmopolitan genus known from the Santonian-Maastrichtian. This is the first occurrence of a tylosaurine mosasaurid in the Iberian Peninsula. Moreover, it corresponds to the southernmost occurrence of this clade in the northern margin of the Mediterranean Tethys. ylosaurinae fossils are known from North America, Europe, New Zealand, Antarctica, Africa and Asia, but remain unknown from the southern Mediterranean Tethyan margin and from tropical palaeolatitudes.Un diente aislado de mosasaurio procedente del Campaniense de Álava (País Vasco), previamente asignado a cf. Mosasaurus sp., se atribuye en este trabajo a un tilosaurino. Podría pertenecer a Tylosaurus, un género cuasi cosmopolita del Santoniense-Maastrichtiense. Es la primera cita de un mosasáurido tilosaurino en la Península Ibérica. Además, se trata del registro más meridional de este clado en el margen norte del Tetis mediterráneo. Los Tylosaurinae están representados por fósiles en Norteamérica, Europa, Nueva Zelanda, Antártida, África y Asia, pero carecen de registro en el margen sur del Tetis mediterráneo y en paleolatitudes tropicales

Permeability and compressibility of wax-coated sands

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New ophthalmosaurid ichthyosaurs from the European lower cretaceous demonstrate extensive ichthyosaur survival across the Jurassic–Cretaceous boundary

Background Ichthyosauria is a diverse clade of marine amniotes that spanned most of the Mesozoic. Until recently, most authors interpreted the fossil record as showing that three major extinction events affected this group during its history: one during the latest Triassic, one at the Jurassic–Cretaceous boundary (JCB), and one (resulting in total extinction) at the Cenomanian-Turonian boundary. The JCB was believed to eradicate most of the peculiar morphotypes found in the Late Jurassic, in favor of apparently less specialized forms in the Cretaceous. However, the record of ichthyosaurs from the Berriasian–Barremian interval is extremely limited, and the effects of the end-Jurassic extinction event on ichthyosaurs remains poorly understood. Methodology/Principal Findings Based on new material from the Hauterivian of England and Germany and on abundant material from the Cambridge Greensand Formation, we name a new ophthalmosaurid, Acamptonectes densus gen. et sp. nov. This taxon shares numerous features with Ophthalmosaurus, a genus now restricted to the Callovian–Berriasian interval. Our phylogenetic analysis indicates that Ophthalmosauridae diverged early in its history into two markedly distinct clades, Ophthalmosaurinae and Platypterygiinae, both of which cross the JCB and persist to the late Albian at least. To evaluate the effect of the JCB extinction event on ichthyosaurs, we calculated cladogenesis, extinction, and survival rates for each stage of the Oxfordian–Barremian interval, under different scenarios. The extinction rate during the JCB never surpasses the background extinction rate for the Oxfordian–Barremian interval and the JCB records one of the highest survival rates of the interval. Conclusions/Significance There is currently no evidence that ichthyosaurs were affected by the JCB extinction event, in contrast to many other marine groups. Ophthalmosaurid ichthyosaurs remained diverse from their rapid radiation in the Middle Jurassic to their total extinction at the beginning of the Late Cretaceous

New data on the ichthyosaur Platypterygius hercynicus and its implications for the validity of the genus

The description of a nearly complete skull from the late Albian of northwestern France reveals previously unknown anatomical features of Platypterygius hercynicus (Kuhn 1946), and of European Cretaceous ichthyosaurs in general. These include a wide frontal forming the anteromedial border of the supratemporal fenestra, a parietal excluded from the parietal foramen, and the likely presence of a squamosal, inferred from a very large and deep facet on the quadratojugal. The absence of a squamosal has been considered as an autapomorphy of the genus Platypterygius for more than ten years and has been applied to all known species by default, but the described specimen casts doubt on this putative autapomorphy. Actually, it is shown that all characters that have been proposed previously as autapomorphic for the genus Platypterygius are either not found in all the species currently referred to this genus, or are also present in other Ophthalmosauridae. Consequently, the genus Platypterygius must be completely revised.Peer reviewe

Quenching dynamics in CdSe nanoparticles: surface-induced defects upon dilution

International audienceWe have analyzed the decays of the fluorescence of colloidal CdSe quantum dots (QDs) suspensions during dilution and titration by the ligands. A ligand shell made of a combination of trioctylphosphine (TOP), oleylamine (OA), and stearic acid (SA) stabilizes the as-synthesized QDs. The composition of the shell was analyzed and quantified using high resolution liquid state 1H nuclear magnetic resonance (NMR) spectroscopy. A quenching of the fluorescence of the QDs is observed upon removal of the ligands by diluting the stock solution of the QDs. The fluorescence is restored by the addition of TOP. We analyze the results by assuming a binomial distribution of quenchers among the QDs and predict a linear trend in the time-resolved fluorescence decays. We have used a nonparametric analysis to show that for our QDs, 3.0 0.1 quenching sites per QD on average are revealed by the removal of TOP. We moreover show that the quenching rates of the quenching sites add up. The decay per quenching site can be compared with the decay at saturation of the dilution effect. This provides a value of 2.88 0.02 for the number of quenchers per QD. We extract the quenching dynamics of one site. It appears to be a process with a distribution of rates that does not involve the ligands

Investigating Thermal Contrasts Between Jupiter's Belts, Zones, and Polar Vortices with VLT/VISIR

Using images at multiple mid-infrared wavelengths, acquired in May 2018 using the VISIR instrument on ESO's Very Large Telescope (VLT), we study Jupiter's pole-to-pole thermal, chemical and aerosol structure in the troposphere and stratosphere. We confirm that the pattern of cool and cloudy anticyclonic zones and warm cloud-free cyclonic belts persists throughout the mid-latitudes, up to the polar boundaries, and evidence a strong correlation with the vertical maximum windshear and the locations of Jupiter's zonal jets. At high latitudes, VISIR images reveal a large region of mid-infrared cooling poleward $\sim$64$^{\circ}$N and $\sim$67$^{\circ}$S extending from the upper troposphere to the stratosphere, co-located with the reflective aerosols observed by JunoCam, and suggesting that aerosols play a key role in the radiative cooling at the poles. Comparison of zonal-mean thermal properties and high-resolution visible imaging from Juno allows us to study the variability of atmospheric properties as a function of altitude and jet boundaries, particularly in the cold southern polar vortex. However, the southern stratospheric polar vortex is partly masked by a warm mid-infrared signature of the aurora. Co-located with the southern main auroral oval, this warming results from the auroral precipitation and/or joule heating which heat the atmosphere and thus cause a significant stratospheric emission. This high emission results from a large enhancement of both ethane and acetylene in the polar region, reinforcing the evidence of enhanced ion-related chemistry in Jupiter's auroral regions

Saturn's Seasonal Variability from Four Decades of Ground-Based Mid-Infrared Observations

A multi-decade record of ground-based mid-infrared (7-25 $\mu$m) images of Saturn is used to explore seasonal and non-seasonal variability in thermal emission over more than a Saturnian year (1984-2022). Thermal emission measured by 3-m and 8-m-class observatories compares favourably with synthetic images based on both Cassini-derived temperature records and the predictions of radiative climate models. 8-m class facilities are capable of resolving thermal contrasts on the scale of Saturn's belts, zones, polar hexagon, and polar cyclones, superimposed onto large-scale seasonal asymmetries. Seasonal changes in brightness temperatures of $\sim30$ K in the stratosphere and $\sim10$ K in the upper troposphere are observed, as the northern and southern polar stratospheric vortices (NPSV and SPSV) form in spring and dissipate in autumn. The timings of the first appearance of the warm polar vortices is successfully reproduced by radiative climate models, confirming them to be radiative phenomena, albeit entrained within sharp boundaries influenced by dynamics. Axisymmetric thermal bands (4-5 per hemisphere) display temperature gradients that are strongly correlated with Saturn's zonal winds, indicating winds that decay in strength with altitude, and implying meridional circulation cells forming the system of cool zones and warm belts. Saturn's thermal structure is largely repeatable from year to year (via comparison of infrared images in 1989 and 2018), with the exception of low-latitudes. Here we find evidence of inter-annual variations because the equatorial banding at 7.9 $\mu$m is inconsistent with a $\sim15$-year period for Saturn's equatorial stratospheric oscillation, i.e., it is not strictly semi-annual. Finally, observations between 2017-2022 extend the legacy of the Cassini mission, revealing the continued warming of the NPSV during northern summer. [Abr.]Comment: 25 pages, 15 figures, accepted for publication in Icaru

Markers of criticality in phase synchronization

The concept of the brain as a critical dynamical system is very attractive because systems close to criticality are thought to maximize their dynamic range of information processing and communication. To date, there have been two key experimental observations in support of this hypothesis: (i) neuronal avalanches with power law distribution of size and (ii) long-range temporal correlations (LRTCs) in the amplitude of neural oscillations. The case for how these maximize dynamic range of information processing and communication is still being made and because a significant substrate for information coding and transmission is neural synchrony it is of interest to link synchronization measures with those of criticality. We propose a framework for characterizing criticality in synchronization based on an analysis of the moment-to-moment fluctuations of phase synchrony in terms of the presence of LRTCs. This framework relies on an estimation of the rate of change of phase difference and a set of methods we have developed to detect LRTCs. We test this framework against two classical models of criticality (Ising and Kuramoto) and recently described variants of these models aimed to more closely represent human brain dynamics. From these simulations we determine the parameters at which these systems show evidence of LRTCs in phase synchronization. We demonstrate proof of principle by analysing pairs of human simultaneous EEG and EMG time series, suggesting that LRTCs of corticomuscular phase synchronization can be detected in the resting state and experimentally manipulated. The existence of LRTCs in fluctuations of phase synchronization suggests that these fluctuations are governed by non-local behavior, with all scales contributing to system behavior. This has important implications regarding the conditions under which one should expect to see LRTCs in phase synchronization. Specifically, brain resting states may exhibit LRTCs reflecting a state of readiness facilitating rapid task-dependent shifts toward and away from synchronous states that abolish LRTCs