Selective conversion of nitroarenes using a carbon nanotube-ruthenium nanohybrid

International audienceRuthenium nanoparticles were assembled on carbon nanotubes and the resulting nanohybrid was used in the hydrazine-mediated catalytic hydrogenation of various nitroarenes, at room temperature. Depending on the solvent, a selective transformation occurred, giving either access to the corresponding aniline or hydroxylamine derivative

Room temperature Suzuki coupling of aryl iodides, bromides, and chlorides using a heterogeneous carbon nanotube-palladium nanohybrid catalyst

International audiencePalladium nanoparticles were immobilized on multi-walled carbon nanotubes by a layer-by-layer approach, resulting in a well-defined assembly. The nanohybrid was found effective in promoting Suzuki cross couplings of various halogenated aromatics, including chlorinated ones, with arylboronic acids under sustainable conditions. The heterogeneous catalyst could also easily be recovered from the reaction mixture and reused with no loss of activity over several cycles

Continuum field description of crack propagation

We develop continuum field model for crack propagation in brittle amorphous solids. The model is represented by equations for elastic displacements combined with the order parameter equation which accounts for the dynamics of defects. This model captures all important phenomenology of crack propagation: crack initiation, propagation, dynamic fracture instability, sound emission, crack branching and fragmentation.Comment: 4 pages, 5 figures, submitted to Phys. Rev. Lett. Additional information can be obtained from http://gershwin.msd.anl.gov/theor

Submillimetre point sources from the Archeops experiment: Very Cold Clumps in the Galactic Plane

Archeops is a balloon-borne experiment, mainly designed to measure the Cosmic Microwave Background (CMB) temperature anisotropies at high angular resolution (~ 12 arcminutes). By-products of the mission are shallow sensitivity maps over a large fraction of the sky (about 30 %) in the millimetre and submillimetre range at 143, 217, 353 and 545 GHz. From these maps, we produce a catalog of bright submillimetre point sources. We present in this paper the processing and analysis of the Archeops point sources. Redundancy across detectors is the key factor allowing to sort out glitches from genuine point sources in the 20 independent maps. We look at the properties of the most reliable point sources, totalling 304. Fluxes range from 1 to 10,000 Jy (at the frequencies covering 143 to 545 GHz). All sources are either planets (2) or of galactic origin. Longitude range is from 75 to 198 degrees. Some of the sources are associated with well-known Lynds Nebulae and HII compact regions in the galactic plane. A large fraction of the sources have an IRAS counterpart. Except for Jupiter, Saturn, the Crab and Cas A, all sources show a dust-emission-like modified blackbody emission spectrum. Temperatures cover a range from 7 to 27 K. For the coldest sources (T<10 K), a steep nu^beta emissivity law is found with a surprising beta ~ 3 to 4. An inverse relationship between T and beta is observed. The number density of sources at 353 GHz with flux brighter than 100 Jy is of the order of 1 per degree of Galactic longitude. These sources will provide a strong check for the calibration of the Planck HFI focal plane geometry as a complement to planets. These very cold sources observed by Archeops should be prime targets for mapping observations by the Akari and Herschel space missions and ground--based observatories.Comment: Version matching the published article (English improved). Published in Astron. Astrophys, 21 pages, 13 figures, 4 tables Full article (with complete tables) can be retrieved at http://www.archeops.org/Archeops_Publicatio

Submillimeter dust emission of the M17 complex measured with PRONAOS

We map a 50' x 30' area in and around the M17 molecular complex with the French submillimeter balloon-borne telescope PRONAOS, in order to better understand the thermal emission of cosmic dust and the structure of the interstellar medium. The PRONAOS-SPM instrument has an angular resolution of about 3', corresponding to a size of 2 pc at the distance of this complex, and a high sensitivity up to 0.8 MJy/sr. The observations are made in four wide submillimeter bands corresponding to effective wavelengths of 200, 260, 360 and 580 um. Using an improved map-making method for PRONAOS data, we map the M17 complex and faint condensations near the dense warm core. We derive maps of both the dust temperature and the spectral index, which vary over a wide range, from about 10 K to 100 K for the temperature and from about 1 to 2.5 for the spectral index. We show that these parameters are anticorrelated, the cold areas (10-20 K) having a spectral index around 2, whereas the warm areas have a spectral index between 1 and 1.5. We discuss possible causes of this effect, and we propose an explanation involving intrinsic variations of the grain properties. Indeed, to match the observed spectra with two dust components having a spectral index equal to 2 leads to very large and unlikely amounts of cold dust. We also give estimates of the column densities and masses of the studied clumps. Three cold clumps (14-17 K) could be gravitationally unstable.Comment: 16 pages, 4 figures, accepted June 2002 in Astronomy & Astrophysic

XPAD: pixel detector for material sciences

Currently available 2D detectors do not make full use of the high flux and high brilliance of third generation synchrotron sources. The XPAD prototype, using active pixels, has been developed to fulfil the needs of materials science scattering experiments. At the time, its prototype is build of eight modules of eight chips. The threshold calibration of /spl ap/4 10/sup 4/ pixels is discussed. Applications to powder diffraction or SAXS experiments prove that it allows to record high quality data

Submillimeter Emission from Water in the W3 Region

We have mapped the submillimeter emission from the 1(10)-1(01) transition of ortho-water in the W3 star-forming region. A 5'x5' map of the W3 IRS4 and W3 IRS5 region reveals strong water lines at half the positions in the map. The relative strength of the Odin lines compared to previous observations by SWAS suggests that we are seeing water emission from an extended region. Across much of the map the lines are double-peaked, with an absorption feature at -39 km/s; however, some positions in the map show a single strong line at -43 km/s. We interpret the double-peaked lines as arising from optically thick, self-absorbed water emission near the W3 IRS5, while the narrower blue-shifted lines originate in emission near W3 IRS4. In this model, the unusual appearance of the spectral lines across the map results from a coincidental agreement in velocity between the emission near W3 IRS4 and the blue peak of the more complex lines near W3 IRS5. The strength of the water lines near W3 IRS4 suggests we may be seeing water emission enhanced in a photon-dominated region.Comment: Accepted to A&A Letters as part of the special Odin issue; 4 page