6,925 research outputs found

    Observation of liquid–liquid phase transitions in ethane at 300 K

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    We have conducted Raman spectroscopy experiments on liquid ethane (C2H6) at 300 K, obtaining a large amount of data at very high resolution. This has enabled the observation of Raman peaks expected but not previously observed in liquid ethane and a detailed experimental study of the liquid that was not previously possible. We have observed a transition between rigid and nonrigid liquid states in liquid ethane at ca. 250 MPa corresponding to the recently proposed Frenkel line, a dynamic transition between rigid liquid (liquidlike) and nonrigid liquid (gaslike) states beginning in the subcritical region and extending to arbitrarily high pressure and temperature. The observation of this transition in liquid (subcritical) ethane allows a clear differentiation to be made between the Frenkel line (beginning in the subcritical region at higher density than the boiling line) and the Widom lines (emanating from the critical point and not existing in the subcritical region). Furthermore, we observe a narrow transition at ca. 1000 MPa to a second rigid liquid state. We propose that this corresponds to a state in which orientational order must exist to achieve the expected density and can view the transition in analogy to the transition in the solid state away from the orientationally disordered phase I to the orientationally ordered phases II and III

    Laser Spectroscopic Measurement of Helium Isotope Ratios

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    A sensitive laser spectroscopic method has been applied to the quantitative determination of the isotope ratio of helium at the level of 3He/4He = 10^-7 - 10^-5. The resonant absorption of 1083 nm laser light by the metastable 3He atoms in a discharge cell was measured with the frequency modulation saturation spectroscopy technique while the abundance of 4He was measured by a direct absorption technique. The results on three different samples extracted from the atmosphere and commercial helium gas were in good agreement with values obtained with mass spectrometry. The achieved 3-sigma detection limit of 3He in helium is 4 x 10^-9. This demonstration required a 200 micro-L STP sample of He. The sensitivity can be further improved, and the required sample size reduced, by several orders of magnitude with the addition of cavity enhanced spectroscopy

    Modeling Count Outcomes from HIV Risk Reduction Interventions: A Comparison of Competing Statistical Models for Count Responses

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    Modeling count data from sexual behavioral outcomes involves many challenges, especially when the data exhibit a preponderance of zeros and overdispersion. In particular, the popular Poisson log-linear model is not appropriate for modeling such outcomes. Although alternatives exist for addressing both issues, they are not widely and effectively used in sex health research, especially in HIV prevention intervention and related studies. In this paper, we discuss how to analyze count outcomes distributed with excess of zeros and overdispersion and introduce appropriate model-fit indices for comparing the performance of competing models, using data from a real study on HIV prevention intervention. The in-depth look at these common issues arising from studies involving behavioral outcomes will promote sound statistical analyses and facilitate research in this and other related areas

    A Disc-Corona Model for a Rotating Black Hole

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    We propose a disc-corona model in which a geometrically thin, optically thick disc surrounds a Kerr black hole, and magnetic fields exert a time-steady torque on the inner edge of the accretion disc. The analytical expression of the total gravitational power is derived from the thin-disc dynamics equations by using this new boundary condition. It is shown that the magnetic torque can considerably enhance the amount of energy released in the disc-corona system. Furthermore, the global solutions of this disc-corona system are obtained numerically. We find that the fraction of the power dissipated into the corona in the total for such disc-corona system increases with the increasing dimensionless black hole spin parameter aa_\ast , but is insensitive on the Δε\Delta \varepsilon which is the additional radiative efficiency parameter relevant to magnetic torque, for Δε>1\Delta\varepsilon > 1. In addition, the emerged spectra from this disc-corona system are simulated by using Monte-Carlo method, and the effect of the different parameters on the output spectra is discussed
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