Estimating retention potential of headwater catchment using Tritium time series

Headwater catchments provide substantial streamflow to rivers even during long periods of drought. Documenting the mean transit times (MTT) of stream water in headwater catchments and therefore the retention capacities of these catchments is crucial for water management. This study uses time series of H-3 activities in combination with major ion concentrations, stable isotope ratios and radon activities (Rn-222) in the Lyrebird Creek catchment in Victoria, Australia to provide a unique insight into the mean transit time distributions and flow systems of this small temperate headwater catchment. At all streamflows, the stream has H-3 activities (< 2.4 TU) that are significantly below those of rainfall (similar to 3.2 TU), implying that most of the water in the stream is derived from stores with long transit times. If the water in the catchment can be represented by a single store with a continuum of ages, mean transit times of the stream water range from similar to 6 up to 40 years, which indicates the large retention potential for this catchment. Alternatively, variations of H-3 activities, stable isotopes and major ions can be explained by mixing between of young recent recharge and older water stored in the catchment. While surface runoff is negligible, the variation in stable isotope ratios, major ion concentrations and radon activities during most of the year is minimal (+/- 12%) and only occurs during major storm events. This suggests that different subsurface water stores are activated during the storm events and that these cease to provide water to the stream within a few days or weeks after storm events. The stores comprise micro and macropore flow in the soils and saprolite as well as the boundary between the saprolite and the fractured bed rock. Hydrograph separations from three major storm events using Tritium, electrical conductivity and selected major ions as well a delta O-18 suggest a minimum of 50% baseflow at most flow conditions.We demonstrate that headwater catchments can have a significant storage capacity and that the relationship between long-water stores and fast storm event subsurface flow is complex. The study also illustrates that using H-3 to determine mean transit times is probably only valid for baseflow conditions where the catchment can be represented as a single store.The results of this study reinforce the need to protect headwater catchments from contamination and extreme land use changes

Femtosecond electron transfer dynamics across the D2_2O/Cs+^+/Cu(111) interface: The impact of hydrogen bonding

Hydrogen bonding is essential in electron transfer processes at water-electrode interfaces. We study the impact of the H-bonding of water as a solvent molecule on real-time electron transfer dynamics across a Cs+-Cu(111) ion-metal interface using femtosecond time-resolved two-photon photoelectron spectroscopy. We distinguish in the formed water-alkali aggregates two regimes below and above two water molecules per ion. Upon crossing the boundary of these regimes, the lifetime of the excess electron localized transiently at the Cs+ ion increases from 40 to 60 femtoseconds, which indicates a reduced alkali-metal interaction. Furthermore, the energy transferred to a dynamic structural rearrangement due to hydration is reduced from 0.3 to 0.2 eV concomitantly. These effects are a consequence of H-bonding and the beginning formation of a nanoscale water network. This finding is supported by real-space imaging of the solvatomers and vibrational frequency shifts of the OH stretch and bending modes calculated for these specific interfaces.Comment: 8 pages, 5 figure

Assessing the controls and uncertainties on mean transit times in contrasting headwater catchments

© 2017 Elsevier. This manuscript version is made available under the CC-BY-NC-ND 4.0 license: http://creativecommons.org/licenses/by-nc-nd/4.0/ This author accepted manuscript is made available following 24 month embargo from date of publication (Dec 2017) in accordance with the publisher’s archiving policyEstimating the time required for water to travel through headwater catchments from where it recharges to where it discharges into streams (the transit time) is important for understanding catchment behaviour. This study uses tritium (3H) activities of stream water to estimate the mean transit times of water in the upper Latrobe and Yarra catchments, southeast Australia, at different flow conditions. The 3H activities of the stream water were between 1.26 and 1.99 TU, which are lower than those of local rainfall (2.6 to 3.0 TU). 3H activities in individual subcatchments are almost invariably lowest at low streamflows. Mean transit times calculated from the 3H activities using a range of lumped parameter models are between 7 and 62 years and are longest during low streamflows. Uncertainties in the estimated mean transit times result from uncertainties in the geometry of the flow systems, uncertainties in the 3H input, and macroscopic mixing. In addition, simulation of 3H activities in FEFLOW indicates that heterogeneous hydraulic conductivities increase the range of mean transit times corresponding to a specific 3H activity. The absolute uncertainties in the mean transit times may be up to ±30 years. However, differences between mean transit times at different streamflows in the same catchment or between different subcatchments in the same area are more reliably estimated. Despite the uncertainties, the conclusions that the mean transit times are years to decades and decrease with increasing streamflow are robust. The seasonal variation in major ion geochemistry and 3H activities indicate that the higher general streamflows in winter are sustained by water displaced from shallower younger stores (e.g., soils or regolith). Poor correlations between 3H activities and catchment area, drainage density, mean slope, distance to stream, and landuse, imply that mean transit times are controlled by a variety of factors including the hydraulic properties of the soils and aquifers that are difficult to characterise spatially. The long mean transit times imply that there are long-lived stores of water in these catchments that may sustain streamflow over drought periods. Additionally, there may be considerable delay in contaminants reaching the stream

Solar Forcing Recorded by Aerosol Concentrations in Coastal Antarctic Glacier Ice, McMurdo Dry Valleys

Ice-core chemistry data from Victoria Lower Glacier, Antarctica, suggest, at least for the last 50 years, a direct influence of solar activity variations on the McMurdo Dry Valleys (MDV) climate system via controls on air-mass input from two competing environments: the East Antarctic ice sheet and the Ross Sea. During periods of increased solar activity, when total solar irradiance is relatively high, the MDV climate system appears to be dominated by air masses originating from the Ross Sea, leading to higher aerosol deposition. During reduced solar activity, the Antarctic interior seems to be the dominant air-mass source, leading to lower aerosol concentration in the ice-core record. We propose that the sensitivity of the MDV to variations in solar irradiance is caused by strong albedo differences between the ice-free MDV and the ice sheet

Twentieth-century warming preserved in a Geladaindong mountain ice core, central Tibetan Plateau

High-resolution δ18O records from a Geladaindong mountain ice core spanning the period 1477-1982 were used to investigate past temperature variations in the Yangtze River source region of the central Tibetan Plateau (TP). Annual ice-core δ18O records were positively correlated with temperature data from nearby meteorological stations, suggesting that the δ18O record represented the air temperature in the region. A generally increasing temperature trend over the past 500 years was identified, with amplified warming during the 20th century. A colder stage, spanning before the 1850s, was found to represent the Little Ice Age with colder periods occurring during the 1470s–1500s, 1580s–1660s, 1700s–20s and 1770s–1840s. Compared with other temperature records from the TP and the Northern Hemisphere, the Geladaindong ice-core record suggested that the regional climate of the central TP experienced a stronger warming trend during the 20th century than other regions. In addition, a positive relationship between the Geladaindong δ18O values and the North Atlantic Oscillation index, combined with a wavelet analysis of δ18O records, indicated that there was a potential atmospheric teleconnection between the North Atlantic and the central TP

The MOSAiC ice floe: sediment-laden survivor from the Siberian shelf

In September 2019, the research icebreaker Polarstern started the largest multidisciplinary Arctic expedition to date, the MOSAiC (Multidisciplinary drifting Observatory for the Study of Arctic Climate) drift experiment. Being moored to an ice floe for a whole year, thus including the winter season, the declared goal of the expedition is to better understand and quantify relevant processes within the atmosphere–ice–ocean system that impact the sea ice mass and energy budget, ultimately leading to much improved climate models. Satellite observations, atmospheric reanalysis data, and readings from a nearby meteorological station indicate that the interplay of high ice export in late winter and exceptionally high air temperatures resulted in the longest ice-free summer period since reliable instrumental records began. We show, using a Lagrangian tracking tool and a thermodynamic sea ice model, that the MOSAiC floe carrying the Central Observatory (CO) formed in a polynya event north of the New Siberian Islands at the beginning of December 2018. The results further indicate that sea ice in the vicinity of the CO (<40 km distance) was younger and 36 % thinner than the surrounding ice with potential consequences for ice dynamics and momentum and heat transfer between ocean and atmosphere. Sea ice surveys carried out on various reference floes in autumn 2019 verify this gradient in ice thickness, and sediments discovered in ice cores (so-called dirty sea ice) around the CO confirm contact with shallow waters in an early phase of growth, consistent with the tracking analysis. Since less and less ice from the Siberian shelves survives its first summer (Krumpen et al., 2019), the MOSAiC experiment provides the unique opportunity to study the role of sea ice as a transport medium for gases, macronutrients, iron, organic matter, sediments and pollutants from shelf areas to the central Arctic Ocean and beyond. Compared to data for the past 26 years, the sea ice encountered at the end of September 2019 can already be classified as exceptionally thin, and further predicted changes towards a seasonally ice-free ocean will likely cut off the long-range transport of ice-rafted materials by the Transpolar Drift in the future. A reduced long-range transport of sea ice would have strong implications for the redistribution of biogeochemical matter in the central Arctic Ocean, with consequences for the balance of climate-relevant trace gases, primary production and biodiversity in the Arctic Ocean

MOSAiC Extended Acknowledgement

For years, the Alfred Wegener Institute, Helmholtz Centre for Polar and Marine Research (AWI), together with the international MOSAiC partners, had been planning and developing the scientific, logistical and financial concept for the implementation of the MOSAiC expedition. The planning and organization of this endeavor was an enormous e˙ort, involving more than 80 institutions from 20 countries. The number of groups and individuals that significantly contributed to the success of the drift observatory goes far beyond the scope of usual polar expeditions

Modulation of Cosmogenic Tritium in Meteoric Precipitation by the 11-year Cycle of Solar Magnetic Field Activity

The relationship between the atmospheric concentration of cosmogenic isotopes, the change of solar activity and hence secondary neutron flux has already been proven. The temporal atmospheric variation of the most studied cosmogenic isotopes shows a significant anti-correlation with solar cycles. However, since artificial tritium input to the atmosphere due to nuclear-weapon tests masked the expected variations of tritium production rate by three orders of magnitude, the natural variation of tritium in meteoric precipitation has not previously been detected. For the first time, we provide clear evidence of the positive correlation between the tritium concentration of meteoric precipitation and neutron flux modulated by solar magnetic activity. We found trends in tritium time series for numerous locations worldwide which are similar to the variation of secondary neutron flux and sun spot numbers. This variability appears to have similar periodicities to that of solar cycle. Frequency analysis, cross correlation analysis, continuous and cross wavelet analysis provide mathematical evidence that the correlation between solar cycle and meteoric tritium does exist. Our results demonstrate that the response of tritium variation in precipitation to the solar cycle can be used to help us understand its role in the water cycle