Infrared recombination lasers pumped by low energy Nd: YAG and excimer lasers

24 infrared laser lines on atomic and ionic transitions have been observed in recombining plasmas by vaporizing and ionizing Cd, Pb, Sn, Zn, and Mg with low energy Nd:YAG or excimer pump-lasers. For operation and optimization of the recombination lasers separated plasma spots and a plasma confinement have been used. The operation of shorter wavelength systems by isoelectronic scaling is discussed

Generation of short-pulse VUV and XUV radiation

Starting from intense short-pulse KrF (248 nm, 25 mJ, 400 fs), ArF (193 nm, 10 mJ, sim1 ps), and Ti:sapphire (810 nm, 100 mJ, 150 fs) laser systems, schemes for the generation of fixed-frequency and tunable VUV and XUV radiation by nonlinear optical techniques are investigated. With the KrF system, a four-wave mixing process in xenon yields tunable radiation in the range of 130–200 nm with output energies of, so far, 100 mgrJ in less than 1 ps. For the XUV spectral range below 100 nm, nonperturbative high-order harmonic generation and frequency mixing processes in noble gas jets are considered. To achieve tunability, the intense fixed-frequency pump laser radiation is mixed with less intense but broadly tunable radiation from short-pulse dye lasers or optical parametric generator-amplifier systems. In this way, tunability down to wavelengths of less than 40 nm has been demonstrated

Full-time education, full-time school: a dialogue on the times

O presente texto propõe-se a trazer indagações sobre a escola de tempo integral e a educação integral no contexto atual. Essa reflexão implica a leitura do contexto e do cenário social e político, nos quais as concepções de educação e sociedade são forjadas atreladas aos ditames da economia global. Em termos sociológicos, a educação integral faz um chamamento contrário à visão fragmentada do ser, da vida, do tempo, mas, por outro lado, em termos políticos, não altera drasticamente a realidade, mantendo o conjunto de contradições socioeconômicas, de classe, acirrando a exclusão em escala global.39108223236The present text proposes to bring inquiries about the “full-time school” and “full-time education” in the current context. This reflection implies the reading of the context and social and political scenario in which the conceptions of education and society are forged tied to the dictates of global economy. In sociological terms, full-time education makes a contrary call to the fragmented vision of being, of life, of time… But on the other hand, in political terms, it does not drastically alter reality, maintaining the set of socioeconomic and class contradictions, exacerbating exclusion on a global scale

A Educação Infantil brasileira no contexto do Mercosul

O presente artigo tem como objetivo refletir acerca das políticas para a educação infantil no Brasil, como parte de um contexto regional (Mercosul), no qual é possível observar imbricações fortemente marcadas pelos ditames do mercado global. A metodologia utilizada corresponde à pesquisa bibliográfica e documental, emanadas dos contextos locais (de cada país que integra o Mercosul), bem como daqueles documentos elaborados no âmbito do respectivo acordo de integração regional. Optou-se em dar destaque à forma como a educação infantil vem sendo inserida no âmbito das políticas locais dos países que integram o Mercosul. Nesse cenário, analisa-se o Brasil e o conjunto de políticas que nele vem sendo implementadas para a educação das crianças pequenas, as quais seguem, majoritariamente, orientações oriundas da ideologia neoliberal, colocando em risco a educação infantil, na perspectiva do direito social e da formação humana

Microscopic Coexistence of Ferromagnetism and Superconductivity in Single-Crystal UCoGe

Unambiguous evidence for the microscopic coexistence of ferromagnetism and superconductivity in UCoGe ($T_{\rm Curie} \sim 2.5$ K and $T_{\rm SC}$ $\sim$ 0.6 K) is reported from $^{59}$Co nuclear quadrupole resonance (NQR). The $^{59}$Co-NQR signal below 1 K indicates ferromagnetism throughout the sample volume, while nuclear spin-lattice relaxation rate $1/T_1$ in the ferromagnetic (FM) phase decreases below $T_{\rm SC}$ due to the opening of the superconducting(SC) gap. The SC state was found to be inhomogeneous, suggestive of a self-induced vortex state, potentially realizable in a FM superconductor. In addition, the $^{59}$Co-NQR spectrum around $T_{\rm Curie}$ show that the FM transition in UCoGe possesses a first-order character, which is consistent with the theoretical prediction that the low-temperature FM transition in itinerant magnets is generically of first-order.Comment: 5 pages, 5 figure

Superconductivity in novel BiS2-based layered superconductor LaO1-xFxBiS2

Layered superconductors have provided some interesting fields in condensed matter physics owing to the low dimensionality of their electronic states. For example, the high-Tc (high transition temperature) cuprates and the Fe-based superconductors possess a layered crystal structure composed of a stacking of spacer (blocking) layers and conduction (superconducting) layers, CuO2 planes or Fe-Anion layers. The spacer layers provide carriers to the conduction layers and induce exotic superconductivity. Recently, we have reported superconductivity in the novel BiS2-based layered compound Bi4O4S3. It was found that superconductivity of Bi4O4S3 originates from the BiS2 layers. The crystal structure is composed of a stacking of BiS2 superconducting layers and the spacer layers, which resembles those of high-Tc cuprate and the Fe-based superconductors. Here we report a discovery of a new type of BiS2-based layered superconductor LaO1-xFxBiS2, with a Tc as high as 10.6 K.Comment: 23 pages, 5 figures, 1 table (table caption has been revised), to appear in J. Phys. Soc. Jp

Spin-Wave Spectrum in `Single-Domain' Magnetic Ground State of Triangular Lattice Antiferromagnet CuFeO2

By means of neutron scattering measurements, we have investigated spin-wave excitation in a collinear four-sublattice (4SL) magnetic ground state of a triangular lattice antiferromagnet CuFeO2, which has been of recent interest as a strongly frustrated magnet, a spin-lattice coupled system and a multiferroic. To avoid mixing of spin-wave spectrum from magnetic domains having three different orientations reflecting trigonal symmetry of the crystal structure, we have applied uniaxial pressure on [1-10] direction of a single crystal CuFeO2. By elastic neutron scattering measurements, we have found that only 10 MPa of the uniaxial pressure results in almost 'single domain' state in the 4SL phase. We have thus performed inelastic neutron scattering measurements using the single domain sample, and have identified two distinct spin- wave branches. The dispersion relation of the upper spin-wave branch cannot be explained by the previous theoretical model [R. S. Fishman: J. Appl. Phys. 103 (2008) 07B109]. This implies the importance of the lattice degree of freedom in the spin-wave excitation in this system, because the previous calculation neglected the effect of the spin-driven lattice distortion in the 4SL phase. We have also discussed relationship between the present results and the recently discovered "electromagnon" excitation.Comment: 5 pages, 3 figures, accepted for publication in J. Phys. Soc. Jp

Crystal structure of Cu-Sn-In alloys around the {\eta} phase field studied by neutron diffraction

The study of the Cu-Sn-In ternary system has become of great importance in recent years, due to new environmental regulations forcing to eliminate the use of Pb in bonding technologies for electronic devices. A key relevant issue concerns the intermetallic phases which grow in the bonding zone and are determining in their quality and performance. In this work, we focus in the {\eta}-phase (Cu2In or Cu6Sn5) that exists in both end binaries and as a ternary phase. We present a neutron diffraction study of the constitution and crystallography of a series of alloys around the 60 at.% Cu composition, and with In contents ranging from 0 to 25 at.%, quenched from 300\degreeC. The alloys were characterized by scanning electron microscopy, probe microanalysis and high-resolution neutron diffraction. The Rietveld refinement of neutron diffraction data allowed to improve the currently available model for site occupancies in the hexagonal {\eta}-phase in the binary Cu-Sn as well as in ternary alloys. For the first time, structural data is reported in the ternary Cu-Sn-In {\eta}-phase as a function of composition, information that is of fundamental technological importance as well as valuable input data for ongoing modelisations of the ternary phase diagram.Comment: 8 pages, 10 figure

Environment-mediated structure, surface redox activity and reactivity of ceria nanoparticles

Nanomaterials, with potential application as bio-medicinal agents, exploit the chemical properties of a solid, with the ability to be transported (like a molecule) to a variety of bodily compartments. However, the chemical environment can change significantly the structure and hence properties of a nanomaterial. Accordingly, its surface reactivity is critically dependent upon the nature of the (biological) environment in which it resides. Here, we use Molecular Dynamics (MD) simulation, Density Functional Theory (DFT) and aberration corrected TEM to predict and rationalise differences in structure and hence surface reactivity of ceria nanoparticles in different environments. In particular we calculate reactivity 'fingerprints' for unreduced and reduced ceria nanoparticles immersed in water and in vacuum. Our simulations predict higher activities of ceria nanoparticles, towards oxygen release, when immersed in water because the water quenches the coordinative unsaturation of surface ions. Conversely, in vacuum, surface ions relax into the body of the nanoparticle to relieve coordinative unsaturation, which increases the energy barriers associated with oxygen release. Our simulations also reveal that reduced ceria nanoparticles are more active towards surface oxygen release compared to unreduced nanoceria. In parallel, experiment is used to explore the activities of ceria nanoparticles that have suffered a change in environment. In particular, we compare the ability of ceria nanoparticles, in an aqueous environment, to scavenge superoxide radicals compared to the same batch of nanoparticles, which have first been dried and then rehydrated. The latter show a distinct reduction in activity, which we correlate to a change in the redox chemistry associated with moving between different environments. The reactivity of ceria nanoparticles is therefore not only environment dependent, but is also influenced by the transport pathway or history required to reach the particular environment in which its reactivity is to be exploited. © 2013 The Royal Society of Chemistry

On Quantum Markov Chains on Cayley tree II: Phase transitions for the associated chain with XY-model on the Cayley tree of order three

In the present paper we study forward Quantum Markov Chains (QMC) defined on a Cayley tree. Using the tree structure of graphs, we give a construction of quantum Markov chains on a Cayley tree. By means of such constructions we prove the existence of a phase transition for the XY-model on a Cayley tree of order three in QMC scheme. By the phase transition we mean the existence of two now quasi equivalent QMC for the given family of interaction operators $\{K_{}\}$.Comment: 34 pages, 1 figur