Women, gender and identity in popular music-making in Gauteng, 1994-2012

Thesis (M.Mus.)--University of the Witwatersrand, Faculty of Humanities, Wits School of Arts, 2013

A bridge between liquids and socio-economic systems: the key role of interaction strengths

One distinctive and pervasive aspect of social systems is the fact that they comprise several kinds of agents. Thus, in order to draw parallels with physical systems one is lead to consider binary (or multi-component) compounds. Recent views about the mixing of liquids in solutions gained from neutron and X-ray scattering show these systems to have a number of similarities with socio-economic systems. It appears that such phenomena as rearrangement of bonds in a solution, gas condensation, selective evaporation of molecules can be transposed in a natural way to socio-economic phenomena. These connections provide a novel perspective for looking at social systems which we illustrate through some examples. For instance, we interpret suicide as an escape phenomenon and in order to test that interpretation we consider social systems characterized by very low levels of social interaction. For those systems suicide rates are found to be 10 to 100 times higher than in the general population. Another interesting parallel concerns the phase transition which occurs when locusts gather together to form swarms which may contain several billion insects. What hinders the thorough investigation of such cases from the standpoint of collective phenomena that we advocate is the lack or inadequacy of statistical data for, up to now, they were collected for completely different purposes. Most essential for further progress are statistics which would permit to estimate the strength of social ties and interactions. Once adequate data become available, rapid advance may be expected.Comment: 23 pages, 6 figures, 4 table

Experimental triplet and quadruplet fluctuation densities and spatial distribution function integrals for pure liquids

Citation: Ploetz, E. A., Karunaweera, S., & Smith, P. E. (2015). Experimental triplet and quadruplet fluctuation densities and spatial distribution function integrals for pure liquids. Journal of Chemical Physics, 142(4), 14. doi:10.1063/1.4905562Fluctuation solution theory has provided an alternative view of many liquid mixture properties in terms of particle number fluctuations. The particle number fluctuations can also be related to integrals of the corresponding two body distribution functions between molecular pairs in order to provide a more physical picture of solution behavior and molecule affinities. Here, we extend this type of approach to provide expressions for higher order triplet and quadruplet fluctuations, and thereby integrals over the corresponding distribution functions, all of which can be obtained from available experimental thermodynamic data. The fluctuations and integrals are then determined using the International Association for the Properties of Water and Steam Formulation 1995 (IAPWS-95) equation of state for the liquid phase of pure water. The results indicate small, but significant, deviations from a Gaussian distribution for the molecules in this system. The pressure and temperature dependence of the fluctuations and integrals, as well as the limiting behavior as one approaches both the triple point and the critical point, are also examined. (C) 2015 AIP Publishing LLC

One possible explanation for the α* relation in non-crystalline materials

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/43032/1/10855_2004_Article_BF00719868.pd

The transition state and cognate concepts

This review aims firstly to clarify the meanings of key terms and concepts associated with the idea of the transition state, as developed by theoreticians and applied by experimentalist, and secondly to provide an update to the meaning and significance of the transition state in an era when computational simulation, in which complexity is being increasingly incorporated, is commonly employed as a means by which to bridge the realms of theory and experiment. The relationship between the transition state and the potential-energy surface for an elementary reaction is explored, with discussion of the following terms: saddle point, minimum-energy reaction path, reaction coordinate, activated complex, transition structure, intrinsic reaction coordinate, transition vector, transition-state structure, and transition state. Structural information determined by the application of computational methods to simple systems or inferred from empirical studies is critically discussed in the light of various complications. Consequently, the relationship between the transition state and the free-energy surface for an elementary reaction within a condensed system is explored, with discussion of collective variables, minimum free-energy paths, variational transition-state theory, transmission coefficients, more about reaction coordinates, and equicommittors. It is noted that any visual picture of a transition state is necessarily an average view, and an updated definition of the transition state is proposed.</p