The Gibraltar Corridor:Watergate of the Messinian Salinity Crisis

The existence and evolution of a Messinian salt giant in the Mediterranean Sea has caused much debate in the marine science community. Especially the suggestion that the Mediterranean was a deep desiccated basin during the Messinian Salinity Crisis (MSC, 5.97–5.33 Ma), triggered by a temporal disconnection from the global ocean, made it a well-known crisis beyond the scientific boundaries. Approximately ~50 years after this provocative statement, it remained unknown which Mediterranean–Atlantic seaway delivered the 5–6% of the global ocean's salt into the Mediterranean basin. Here, we review the changes in Mediterranean-Atlantic connectivity throughout the late Miocene in order to locate, date and quantify the missing Messinian gateway that provided the salt water inflow during the MSC. We conclude that all the known pre-MSC gateways through southern Spain and northern Morocco were closed, leaving the “Gibraltar Corridor” at its Messinian configuration as the sole candidate. We consider the possibility of longer and narrower straits existing at depth below the present Gibraltar region, and using strait dynamic theory we calculate its dimensions during the Messinian based on the salinity changes in the Mediterranean. A marine Messinian gateway through the Gibraltar Corridor is in agreement with growing evidence that Atlantic waters reached the Mediterranean Sea during all three stages of the MSC

Salinity stratification of the Mediterranean Sea during the Messinian crisis : A first model analysis

In the late Miocene, a thick and complex sequence of evaporites was deposited in the Mediterranean Sea during an interruption of normal marine sedimentation known as the Messinian Salinity Crisis. Because the related deposits are mostly hidden from scrutiny in the deep basin, correlation between onshore and offshore sediments is difficult, hampering the development of a comprehensive stratigraphic model. Since the various facies correspond to different salinities of the basin waters, it would help to have physics-based understanding of the spatial distribution of salt concentration. Here, we focus on modelling salinity as a function of depth, i.e., on the stratification of the water column. A box model is set up that includes a simple representation of a haline overturning circulation and of mixing. It is forced by Atlantic exchange and evaporative loss and is used to systematically explore the degree of stratification that results under a wide range of combinations of parameter values. The model demonstrates counterintuitive behaviour close to the saturation of halite. For parameter values that may well be realistic for the Messinian, we show that a significantly stratified Mediterranean water column can be established. In this case, Atlantic connectivity is limited but may be closer to modern magnitudes than previously thought. In addition, a slowing of Mediterranean overturning and a larger deep-water formation region (both in comparison to the present day) are required. Under these conditions, we would expect a longer duration of halite deposition than currently considered in the MSC stratigraphic consensus model

Salinity stratification of the Mediterranean Sea during the Messinian crisis: A first model analysis

In the late Miocene, a thick and complex sequence of evaporites was deposited in the Mediterranean Sea during an interruption of normal marine sedimentation known as the Messinian Salinity Crisis. Because the related deposits are mostly hidden from scrutiny in the deep basin, correlation between onshore and offshore sediments is difficult, hampering the development of a comprehensive stratigraphic model. Since the various facies correspond to different salinities of the basin waters, it would help to have physics-based understanding of the spatial distribution of salt concentration. Here, we focus on modelling salinity as a function of depth, i.e., on the stratification of the water column. A box model is set up that includes a simple representation of a haline overturning circulation and of mixing. It is forced by Atlantic exchange and evaporative loss and is used to systematically explore the degree of stratification that results under a wide range of combinations of parameter values. The model demonstrates counterintuitive behaviour close to the saturation of halite. For parameter values that may well be realistic for the Messinian, we show that a significantly stratified Mediterranean water column can be established. In this case, Atlantic connectivity is limited but may be closer to modern magnitudes than previously thought. In addition, a slowing of Mediterranean overturning and a larger deep-water formation region (both in comparison to the present day) are required. Under these conditions, we would expect a longer duration of halite deposition than currently considered in the MSC stratigraphic consensus model

The absolute δ18O value for SLAP with respect to VSMOW reveals a much lower value than previously established

RATIONALE: SLAP is one of the two calibration materials for the isotopic water scale. By consensus the established δ18O value is -55.5‰, although there are firm indications that δ18OSLAP is significantly more negative. The real δ18OSLAP value as such does not influence the isotopic water scale, however knowledge of the size of isotopic scale contraction in stable isotope measurements is vital for second order isotopes. In this study quantification of δ18OSLAP with respect to δ18OVSMOW is described. METHODS: SLAP-like water was quantitatively mixed with highly 18O enriched water to mimic VSMOW. The 18O concentration was determined using an electron ionization quadrupole mass spectrometer. The isotopic composition of the SLAP-like and VSMOW-like waters were measured with an optical spectrometer, alongside real VSMOW and SLAP.RESULTS: This study resulted in a much more depleted δ18O value for SLAP than expected. The averaged outcome of 7 independent experiments is δ18OSLAP -56.33 ± 0.03‰. There is a large discrepancy between the actual isotopic measurements of even the most carefully operating groups and the true δ18O value.CONCLUSIONS: Although this finding as such does not influence the use of the VSMOW-SLAP scale, it raises the intriguing question what we actually measure with our instruments, and why even a fully corrected measurement can be so far off. Our result has consequences for issues like the transfer of δ18O from and to the VPDB scale, various fractionation factors, and the Δ17O. The absolute 18O abundance for SLAP was determined at 1.88798 (43) x 10-3 based on the absolute 18O abundance of VSMOW and the presented δ18OSLAP in this paper.<br/

A tale of a changing basin - a transient model of the 7.17 event leading to the Messinian Salinity Crisis

Before the Messinian Salinity Crisis (MSC) left its imprint on the sediment record of the Mediterranean Sea in the form of evaporites, the basin had already undergone significant changes. At 7.17 Ma, a drop in δ13C values, as well as a basin-wide shift in the abundance of benthic foraminifers, already attest to a sudden change in the Mediterranean conditions. This event coincides with an increase in the amplitude of the insolation curve. It thus stands to question whether a change in the freshwater budget or a change in the connection between the Mediterranean Sea and the Atlantic was the driver for this event. Answering this question would not only help to understand the event itself, but might also help to decipher the early dynamics of the MSC. With a computational box model, we investigate the response of the Mediterranean Sea to a varying freshwater budget for a wide range of restriction. The results then let us define scenarios in which we analyse how a gradually changing restriction would express itself in the basin dynamics. We find that the change in the freshwater budget alone cannot explain the changes that are attributed with the 7.2 event, but coupled with an increase in restriction most differences can be accounted for. Our results also show that a gradual change in restriction can provoke a non-linear response in the behaviour of the basin, which can appear abrupt when happening on a short enough timescale. Such a change would also enhance the influence of said changes in the freshwater budget. This tells us that the processes that most likely triggered the Messinian Salinity Crisis started much earlier and incrementally increased the restriction of the Mediterranean Sea.</p

Contamination on AMS Sample Targets by Modern Carbon is Inevitable

Accelerator mass spectrometry (AMS) measurements of the radiocarbon content in very old samples are often challenging and carry large relative uncertainties due to possible contaminations acquired during the preparation and storage steps. In case of such old samples, the natural surrounding levels of C-14 from gases in the atmosphere, which may well be the source of contamination among others, are 2-3 orders of magnitude higher than the samples themselves. Hence, serious efforts are taken during the preparation steps to have the samples pristine until measurements are performed. As samples often have to be temporarily stored until AMS measurements can be performed, storage conditions also become extremely crucial. Here we describe an assessment of this process of contamination in background AMS samples. Samples, both as pressed graphite (on AMS targets) and graphite powder, were stored in various storage conditions (CO2-spiked air) to investigate the extent of contamination. The experiments clearly show that the pressed targets are more vulnerable to contamination than the unpressed graphite. Experiments conducted with enriched CO2-spiked laboratory air also reveal that the contaminating carbon is not only limited to the target surface but also penetrates into the matrix. A combination of measurements on understanding the chemical nature of the graphitization product, combined with long-available knowledge on "adventitious carbon" from the surface science community, brought us to the conclusion that contamination is to a certain extent inevitable. However, it can be minimized, and should be dealt with by sputter-cleaning the samples individually before the actual measurement

Quantifying the Mediterranean freshwater budget throughout the late Miocene : New implications for sapropel formation and the Messinian Salinity Crisis

The cyclic sedimentary record of the late Miocene Mediterranean shows a clear transition from open marine to restricted conditions and finally to evaporitic environments associated with the Messinian Salinity Crisis. This evolution has been attributed to changes in Mediterranean–Atlantic connectivity and regional climate, which has a strong precessional pulse. 31 Coupled climate simulations with different orbital configurations have been combined in a regression model that estimates the evolution of the freshwater budget of the Mediterranean throughout the late Miocene. The study suggests that wetter conditions occur at precession minima and are enhanced at eccentricity maxima. We use the wetter peaks to predict synthetic sapropel records. Using these to retune two Mediterranean sediment successions indicates that the overall net freshwater budget is the most likely mechanism driving sapropel formation in the late Miocene. Our sapropel timing is offset from precession minima and boreal summer insolation maxima during low eccentricity if the present-day drainage configuration across North Africa is used. This phase offset is removed if at least 50% more water drained into the Mediterranean during the late Miocene, capturing additional North African monsoon precipitation, for example via the Chad-Eosahabi catchment in Libya. In contrast with the clear expression of precession and eccentricity in the model results, obliquity, which is visible in the sapropel record during minimum eccentricity, does not have a strong signal in our model. By exploring the freshwater evolution curve in a box model that also includes Mediterranean–Atlantic exchange, we are able, for the first time, to estimate the Mediterranean's salinity evolution, which is quantitatively consistent with precessional control. Additionally, we separate and quantify the distinct contributions regional climate and tectonic restriction make to the lithological changes associated with the Messinian Salinity Crisis. The novel methodology and results of this study have numerous potential applications to other regions and geological scenarios, as well as to astronomical tuning

Quantifying the Mediterranean freshwater budget throughout the late Miocene: New implications for sapropel formation and the Messinian Salinity Crisis

The cyclic sedimentary record of the late Miocene Mediterranean shows a clear transition from open marine to restricted conditions and finally to evaporitic environments associated with the Messinian Salinity Crisis. This evolution has been attributed to changes in Mediterranean–Atlantic connectivity and regional climate, which has a strong precessional pulse. 31 Coupled climate simulations with different orbital configurations have been combined in a regression model that estimates the evolution of the freshwater budget of the Mediterranean throughout the late Miocene. The study suggests that wetter conditions occur at precession minima and are enhanced at eccentricity maxima. We use the wetter peaks to predict synthetic sapropel records. Using these to retune two Mediterranean sediment successions indicates that the overall net freshwater budget is the most likely mechanism driving sapropel formation in the late Miocene. Our sapropel timing is offset from precession minima and boreal summer insolation maxima during low eccentricity if the present-day drainage configuration across North Africa is used. This phase offset is removed if at least 50% more water drained into the Mediterranean during the late Miocene, capturing additional North African monsoon precipitation, for example via the Chad-Eosahabi catchment in Libya. In contrast with the clear expression of precession and eccentricity in the model results, obliquity, which is visible in the sapropel record during minimum eccentricity, does not have a strong signal in our model. By exploring the freshwater evolution curve in a box model that also includes Mediterranean–Atlantic exchange, we are able, for the first time, to estimate the Mediterranean's salinity evolution, which is quantitatively consistent with precessional control. Additionally, we separate and quantify the distinct contributions regional climate and tectonic restriction make to the lithological changes associated with the Messinian Salinity Crisis. The novel methodology and results of this study have numerous potential applications to other regions and geological scenarios, as well as to astronomical tuning

Quantitative analysis of Paratethys sea level change during the Messinian Salinity Crisis

At the time of the Messinian Salinity Crisis in the Mediterranean Sea (i.e., the Pontian stage of the Paratethys), the Paratethys sea level dropped also. Evidence found in the sedimentary record of the Black Sea and the Caspian Sea has been interpreted to indicate that a sea level fall occurred between 5.6 and 5.5 Ma. Estimates for the magnitude of this fall range between tens of meters to more than 1500 m. The purpose of this study is to provide quantitative insight into the sensitivity of the water level of the Black Sea and the Caspian Sea to the hydrologic budget, for a scenario in which the Paratethys is disconnected from the Mediterranean. Using a Late Miocene bathymetry based on a palaeographic map we quantify the fall in sea level, the mean salinity, and the time to reach equilibrium for a wide range of negative hydrologic budgets. By combining our results with (i) estimates calculated from a set of recent global Late Miocene climate simulations and (ii) reconstructed basin salinities, we are able to rule out a drop in sea level of the order of 1000 m in the Caspian Sea during this time period. In the Black Sea, however, such a large sea level fall cannot be fully discarded