Enhanced photoinduced birefringence in polymer-dye complexes: Hydrogen bonding makes a difference

The authors demonstrate that photoinduced birefringence in azo-dye-doped polymers is strongly enhanced by hydrogen bonding between the guest molecules and the polymer host. The primary mechanism behind the enhancement is the possibility to use high dye doping levels compared to conventional guest-host systems because dye aggregation is restrained by hydrogen bonding. Moreover, hydrogen bonding reduces the mobility of the guest molecules in the polymer host leading to a larger fraction of the induced birefringence to be preserved after the excitation light has been turned off.Peer reviewe

Phase Calibration of Liquid-Crystal-Based Spatial Light Modulators Using the Spatial Structure of Focused Optical Fields

We present an in situ microscopic technique to calibrate phase-only liquid-crystal-based spatial light modulators LC SLM). The technique relies on the spatial structure of focused fields that are commonly encountered in optical microscopy. To retrieve the phase response curve of the LC SLM, we modulate the phase of one half of the incident beam, record the resulting variations of the focused fields at the focal plane of the microscope objective, and perform a correlation of those variations in the corresponding experimental and theoretical intensity distributions of the focused fields. We establish the validity of the technique by comparing its performance to the well-known two-beam interference technique for calibrating a phase-only LC SLM. Our technique is general, robust, and directly applicable to any microscopy set up that utilizes a LC SLM in the excitation path.publishedVersionPeer reviewe

Leadership Strategies to Influence Employee Engagement in Health Care

Hospitals are in a precarious financial position with declining reimbursement, eroding profit margins, and low patient satisfaction. The Patient Protection and Affordable Care Act of 2010 reform may decrease hospital reimbursement by $500 billion from 2010 to 2020, while low patient satisfaction may decrease profitability for hospitals by 27%. Employee disengagement may decrease patient satisfaction and consumer loyalty. The purpose of this phenomenological study was to explore the lived experiences of health care leaders as they worked to engage employees and provide better patient care. Improving patient care provides opportunities to capture new market shares, which increases sustainability of health care organizations. Expectancy theory shaped the conceptual framework of this study. Inquiry consisted of personal interviews with 23 mid-level hospital managers. Data analysis occurred with a modified Van Kamm data analysis process, which entailed descriptive coding and sequential review of the interview transcripts. Member checks and data saturation ensured trustworthiness of the findings. The findings from these personal interviews led to discovery of 4 themes of leader-employee engagement to include psychological commitment, expectation realization, trust actualization, and reduction in the leadership power distance. By applying employee engagement strategies aligned with these themes, leaders may influence patient care. This study contributes to social change by increasing health care quality for patients leading to a positive influence on medical care and societal health

Soliton-assisted random lasing in optically-pumped liquid crystals

We demonstrate a guided-wave random laser configuration by exploiting the coexistence of optical gain and light self-localization in a reorientational nonlinear medium. A spatial soliton launched by a near-infrared beam in dye-doped nematic liquid crystals enhances and confines stimulated emission of visible light in the optically-pumped gain-medium, yielding random lasing with enhanced features.See also erratum at:Appl. Phys. Lett. 110, 019902 (2017); https://doi.org/10.1063/1.4973864<br/

Polarized THG Microscopy Identifies Compositionally Different Lipid Droplets in Mammalian Cells

Peer reviewe

Atomic layer deposited second order nonlinear optical metamaterial for back-end integration with CMOS-compatible nanophotonic circuitry

We report the fabrication of artificial unidimensional crystals exhibiting an effective bulk second-order nonlinearity. The crystals are created by cycling atomic layer deposition of three dielectric materials such that the resulting metamaterial is non-centrosymmetric in the direction of the deposition. Characterization of the structures by second-harmonic generation Maker-fringe measurements shows that the main component of their nonlinear susceptibility tensor is about 5 pm/V which is comparable to well-established materials and more than an order of magnitude greater than reported for a similar crystal [1-Alloatti et al, arXiv:1504.00101[cond-mat.mtrl- sci]]. Our demonstration opens new possibilities for second-order nonlinear effects on CMOS-compatible nanophotonic platforms.Comment: 4 pages, 2 tables, 4 figures, submitted to Optics Letter

Backward phase-matched second-harmonic generation from stacked metasurfaces

We demonstrate phase-matched second-harmonic generation (SHG) from three-dimensional metamaterials consisting of stacked metasurfaces. To achieve phase matching, we utilize a novel mechanism based on phase engineering of the metasurfaces at the interacting wavelengths, facilitating phase-matched SHG in the unconventional backward direction. By stacking up to five metasurfaces, we obtain the expected factor of 25 enhancement in SHG efficiency. Our results motivate further investigations to achieve higher conversion efficiencies also with more complex wavefronts.Comment: 5 pages, 3 figures, supplementary materia

Efficient hybrid-mode excitation in plasmonic nanoantennas by tightly focused higher-order vector beams

Efficient optical excitation of hybridized plasmon modes in nanoantennas is vital to achieve many promising functionalities, but it can be challenging due to a field-profile mismatch between the incident light and the hybrid mode. We present a general approach for efficient hybrid-mode excitation by focusing the incident light field in the basis of cylindrically polarized vector beams of various higher-order spiral phases. Such basis vector beams are described in the higher-order polarization states and Stokes parameters (both defined locally in polar coordinates), and visualized correspondingly on the higher-order Poincaré spheres. The focal field is formulated exclusively in cylindrical coordinates as a series sum of all focused beams of the associated high-order paraxial beams. Our focal field decomposition enables an analysis of hybrid-mode excitation via higher-order vector beams, and thus yields a straightforward design of an effective mode-matching field profile in the tightly focused region.acceptedVersionPeer reviewe

On the determination of χ(2) in thin films : a comparison of one-beam second-harmonic generation measurement methodologies

The determination of the second-order susceptibility (chi((2))) of thin film samples can be a delicate matter since well-established chi((2)) measurement methodologies such as the Maker fringe technique are best suited for nonlinear materials with large thicknesses typically ranging from tens of microns to several millimeters. Here we compare two different second-harmonic generation setups and the corresponding measurement methodologies that are especially advantageous for thin film chi((2)) characteriza tion. This exercise allows for cross-checking the chi((2)) obtained for identical samples and identifying the main sources of error for the respective techniques. The development of photonic integrated circuits makes nonlinear thin films of particular interest, since they can be processed into long waveguides to create efficient nonlinear devices. The investigated samples are ABC-type nanolaminates, which were reported recently by two different research groups. However, the subsequent analysis can be useful for all researchers active in the field of thin film chi((2)) characterization