1,600 research outputs found
CO oxidation over nonstoichiometric nickel manganite spinels
Nonstoichiometric nickel–manganese spinel oxides, NixMn3−x ▭3δ/4O4+δ (1≥x≥0), have been synthesized by calcination in air of mixed oxalates at 623 K. These materials are shown to be highly reactive for CO oxidation, some conversion being observed at room temperature for the most active solid (x=1.0). The interaction of CO and O2 with these oxides has been studied by in situ IR spectroscopy under steady-state and transient reaction conditions. A detailed mechanism is proposed wherein CO reacts with coordinatively unsaturated cations to give carbonyl complexes which in turn react with surface oxygen activated on anionic vacancies. Adsorbed and gaseous CO2 also undergo much slower side reactions with lattice oxygen or surface hydroxide groups to give more stable hydrogen carbonate and carbonates species, which lead to catalyst deactivation. Marked effects of pretreatment are explained on the basis of the observed kinetics and the proposed mechanis
Location of laccase in ordered mesoporous materials
The functionalization with amine groups was developed on the SBA-15, and its effect in the laccase immobilization was compared with that of a Periodic Mesoporous Aminosilica. A method to encapsulate the laccase in situ has now been developed. In this work, spherical aberration (Cs) corrected scanning transmission electron microscopy combined with high angle annular dark field detector and electron energy loss spectroscopy were applied to identify the exact location of the enzyme in the matrix formed by the ordered mesoporous solids
The discovery of the most UV-Lya luminous star-forming galaxy: a young, dust- and metal-poor starburst with QSO-like luminosities
We report the discovery of BOSS-EUVLG1 at z=2.469, by far the most luminous,
almost un-obscured star-forming galaxy known at any redshift. First classified
as a QSO within the Baryon Oscillation Spectroscopic Survey, follow-up
observations with the Gran Telescopio Canarias reveal that its large
luminosity, MUV = -24.40 and log(L_Lya/erg s-1) = 44.0, is due to an intense
burst of star-formation, and not to an AGN or gravitational lensing.
BOSS-EUVLG1 is a compact (reff = 1.2 kpc), young (4-5 Myr) starburst with a
stellar mass log(M*/Msun) = 10.0 +/- 0.1 and a prodigious star formation rate
of ~1000 Msun yr-1. However, it is metal- and dust-poor (12+log(O/H) = 8.13 +/-
0.19, E(B-V) = 0.07, log(LIR/LUV) < -1.2), indicating that we are witnessing
the very early phase of an intense starburst that has had no time to enrich the
ISM. BOSS-EUVLG1 might represent a short-lived (<100 Myrs), yet important phase
of star-forming galaxies at high redshift that has been missed in previous
surveys. Within a galaxy evolutionary scheme, BOSS-EUVLG1 could likely
represent the very initial phases in the evolution of massive quiescent
galaxies, even before the dusty star-forming phase.Comment: 6 pages, 3 figures, 1 table. Accepted for publication in MNRAS
Letter
Mechanical Activation of Al-Oxyhydroxide Minerals – Physicochemical Changes, Reactivity and Relevance to Bayer Process
Overview of our research on ‘structure and reactivity’ of gibbsite and boehmite under varied conditions of mechanical activation, e.g. milling energy and presence of a second phase is presented. Bulk and surface changes induced in the solids by milling are characterized in terms of morphology, particle size distribution, specific surface area and nature of porosity, crystallite size and zeta potential. Results on enhanced amorphisation of gibbsite in presence of a second phase (quartz, hematite etc), changes in zeta potential of gibbsite due to loss of texture during milling and anomalous decrease in surface area of boehmite during milling are reported. Reactivity of the activated solids in sodium hydroxide and variation in thermal transformation temperatures is correlated with physicochemical characteristics of the samples and plausible explanation for the observed correlations presented. Significance of the results with specific reference to bauxite and alumina processing in Bayer process is highlighted
The Pierre Auger Observatory III: Other Astrophysical Observations
Astrophysical observations of ultra-high-energy cosmic rays with the Pierre
Auger ObservatoryComment: Contributions to the 32nd International Cosmic Ray Conference,
Beijing, China, August 201
Highlights from the Pierre Auger Observatory
The Pierre Auger Observatory is the world's largest cosmic ray observatory.
Our current exposure reaches nearly 40,000 km str and provides us with an
unprecedented quality data set. The performance and stability of the detectors
and their enhancements are described. Data analyses have led to a number of
major breakthroughs. Among these we discuss the energy spectrum and the
searches for large-scale anisotropies. We present analyses of our X
data and show how it can be interpreted in terms of mass composition. We also
describe some new analyses that extract mass sensitive parameters from the 100%
duty cycle SD data. A coherent interpretation of all these recent results opens
new directions. The consequences regarding the cosmic ray composition and the
properties of UHECR sources are briefly discussed.Comment: 9 pages, 12 figures, talk given at the 33rd International Cosmic Ray
Conference, Rio de Janeiro 201
Operations of and Future Plans for the Pierre Auger Observatory
Technical reports on operations and features of the Pierre Auger Observatory,
including ongoing and planned enhancements and the status of the future
northern hemisphere portion of the Observatory. Contributions to the 31st
International Cosmic Ray Conference, Lodz, Poland, July 2009.Comment: Contributions to the 31st ICRC, Lodz, Poland, July 200
Measurement of the Depth of Maximum of Extensive Air Showers above 10^18 eV
We describe the measurement of the depth of maximum, Xmax, of the
longitudinal development of air showers induced by cosmic rays. Almost four
thousand events above 10^18 eV observed by the fluorescence detector of the
Pierre Auger Observatory in coincidence with at least one surface detector
station are selected for the analysis. The average shower maximum was found to
evolve with energy at a rate of (106 +35/-21) g/cm^2/decade below 10^(18.24 +/-
0.05) eV and (24 +/- 3) g/cm^2/decade above this energy. The measured
shower-to-shower fluctuations decrease from about 55 to 26 g/cm^2. The
interpretation of these results in terms of the cosmic ray mass composition is
briefly discussed.Comment: Accepted for publication by PR
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