1,108 research outputs found
Pure xenon hexafluoride prepared for thermal properties studies
Preparation of a xenon hexafluoride and sodium fluoride salt yields a sample of the highest possible purity for use in thermal measurements. The desired hexafluoride can easily be freed from the common contaminants, xenon tetra-fluoride, xenon difluoride, and xenon oxide tetrafluoride, because none of these compounds reacts with sodium fluoride
Xenon forms stable compound with fluorine
Experiments show that xenon and fluorine combine readily at 400 deg C to form xenon tetrafluoride, which is colorless, crystalline, chemically stable and solid at room temperature. This process can be used for the separation of xenon from mixtures with other noble gases
Direct observation and imaging of a spin-wave soliton with like symmetry
The prediction and realization of magnetic excitations driven by electrical
currents via the spin transfer torque effect, enables novel magnetic
nano-devices where spin-waves can be used to process and store information. The
functional control of such devices relies on understanding the properties of
non-linear spin-wave excitations. It has been demonstrated that spin waves can
show both an itinerant character, but also appear as localized solitons. So
far, it was assumed that localized solitons have essentially cylindrical,
like symmetry. Using a newly developed high-sensitivity time-resolved
magnetic x-ray microscopy, we instead observe the emergence of a novel
localized soliton excitation with a nodal line, i.e. with like symmetry.
Micromagnetic simulations identify the physical mechanism that controls the
transition from to like solitons. Our results suggest a potential new
pathway to design artificial atoms with tunable dynamical states using
nanoscale magnetic devices
Detection of X-ray Emission from Gravitationally Lensed Submillimeter Sources in the Field of Abell 370
We report the detection by Chandra of SMM J02399-0134 and SMM J02399-0136,
two distant (z=1.06 and z=2.81, respectively) submillimeter sources
gravitationally magnified by the galaxy cluster Abell 370. These are
high-significance (> 7-sigma) X-ray detections of the high-redshift
submillimeter source population. The X-ray positions are coincident with the
optical positions to within one arcsecond. The X-ray spectra, while of low
signal-to-noise ratio, are quite hard. Absorbed power law models with fixed
photon indices of imply local absorbing columns cm and unabsorbed luminosities erg s in both
sources. These results imply that nuclear activity is responsible for the bulk
of the luminosity in SMM J02399-0134, and for at least 20% of the luminosity of
SMM J02399-0136, consistent with previous optical observations. We also place
an upper limit on the X-ray flux of a third submillimeter source, SMM
J02400-0134. Considered together with previously published Chandra upper limits
on X-ray flux from submillimeter sources, our results imply that
% of submillimeter sources exhibit X-ray emission from AGN
(90% confidence), consistent with expectations of their contribution to the
diffuse X-ray background.Comment: Corrected typos in Figure 1 labels; Accepted for publication in ApJ
Letters, 6 pages, 2 figures, latex requires emulateapj5.st
Chandra X-ray Observations of the Quadruply Lensed Quasar RX J0911.4+0551
We present results from X-ray observations of the quadruply lensed quasar RX
J0911.4+0551 using data obtained with the Advanced CCD Imaging Spectrometer
(ACIS) on board the Chandra X-ray Observatory. The 29 ks observation detects a
total of ~404 X-ray photons (0.3 to 7.0 keV) from the four images of the lensed
quasar. Deconvolution of the aspect corrected data resolves all four lensed
images, with relative positions in good agreement with optical measurements.
When compared to contemporaneous optical data, one of the lensed images
(component A3) is dimmer by a factor of ~6 in X-rays with respect to the 2
brighter images (components A1 and A2). Spectral fitting for the combined
images shows significant intrinsic absorption in the soft (0.2 to 2.4 keV)
energy band, consistent with the mini-BAL nature of this quasar, while a
comparison with ROSAT PSPC observations from 1990 shows a drop of ~6.5 in the
total soft bandpass flux. The observations also detect ~157 X-ray photons
arising from extended emission of the nearby cluster (peaked ~42" SW of
RXJ0911.4+0551) responsible for the large external shear present in the system.
The Chandra observation reveals the cluster emission to be complex and
non-spherical, and yields a cluster temperature of kT = 2.3^{+1.8}_{-0.8} keV
and a 2.0 to 10 keV cluster luminosity within a 1 Mpc radius of L_X =
7.6_{-0.2}^{+0.6} x 10^{43} ergs/s (error bars denote 90% confidence limits).
Our mass estimate of the cluster within its virial radius is 2.3^{+1.8}_{-0.7}
x 10^{14} solar, and is a factor of 2 smaller than, although consistent with,
previous mass estimates based on the observed cluster velocity dispersion.Comment: 16 pages, 3 figures (figure 1 is color ps). Accepted by Ap
Measured and modeled humidification factors of fresh smoke particles from biomass burning: role of inorganic constituents
During the 2006 FLAME study (<b>F</b>ire <b>L</b>aboratory <b>a</b>t <b>M</b>issoula <b>E</b>xperiment), laboratory burns of biomass fuels were performed to investigate the physico-chemical, optical, and hygroscopic properties of fresh biomass smoke. As part of the experiment, two nephelometers simultaneously measured dry and humidified light scattering coefficients (<i>b</i><sub>sp(dry) </sub> and <i>b</i><sub>sp(RH)</sub>, respectively) in order to explore the role of relative humidity (RH) on the optical properties of biomass smoke aerosols. Results from burns of several biomass fuels from the west and southeast United States showed large variability in the humidification factor (<i>f</i>(RH)=<i>b</i><sub>sp(RH)</sub>/<i>b</i><sub>sp(dry)</sub>). Values of <i>f</i>(RH) at RH=80–85% ranged from 0.99 to 1.81 depending on fuel type. We incorporated measured chemical composition and size distribution data to model the smoke hygroscopic growth to investigate the role of inorganic compounds on water uptake for these aerosols. By assuming only inorganic constituents were hygroscopic, we were able to model the water uptake within experimental uncertainty, suggesting that inorganic species were responsible for most of the hygroscopic growth. In addition, humidification factors at 80–85% RH increased for smoke with increasing inorganic salt to carbon ratios. Particle morphology as observed from scanning electron microscopy revealed that samples of hygroscopic particles contained soot chains either internally or externally mixed with inorganic potassium salts, while samples of weak to non-hygroscopic particles were dominated by soot and organic constituents. This study provides further understanding of the compounds responsible for water uptake by young biomass smoke, and is important for accurately assessing the role of smoke in climate change studies and visibility regulatory efforts
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Fossil and Contemporary Fine Carbon Fractions at 12 Rural and Urban Sites in the United States
Fine particulate matter collected at two urban, four near-urban, and six remote sites throughout the United States were analyzed for total carbon (TC) and radiocarbon ({sup 14}C). Samples were collected at most sites for both a summer and winter season. The radiocarbon was used to partition the TC into fossil and contemporary fractions. On average, contemporary carbon composed about half of the carbon at the urban, {approx}70-97% at near-urban, and 82-100% at remote sites. At Phoenix, Arizona, and Seattle, Washington, one monitor was located within the urban center and one outside to assess the urban excess over background concentrations. During the summer the urban and rural sites had similar contemporary carbon concentrations. However, during the winter the urban sites had more than twice the contemporary carbon measured at the neighboring sites, indicating anthropogenic contributions to the contemporary carbon. The urban fossil carbon was 4-20 times larger than the neighboring rural sites for both seasons. Organic (OC) and elemental carbon (EC) from TOR analysis were available. These and the radiocarbon data were used to estimate characteristic fossil and contemporary EC/TC ratios for the winter and summer seasons. These ratios were applied to carbon data from the Interagency Monitoring of Protected Visual Environments network to estimate the fraction of contemporary carbon at mostly rural sites throughout the United States. In addition, the ratios were used to develop a semiquantitative, lower bound estimate of secondary organic carbon (SOC) contribution to fossil and contemporary carbon. SOC accounted for more than one-third of the fossil and contemporary carbon
Evolution from adherent to suspension: systems biology of HEK293 cell line development
The need for new safe and efficacious therapies has led to an increased focus on biologics produced in mammalian cells. The human cell line HEK293 has bio-synthetic potential for human-like production attributes and is currently used for manufacturing of several therapeutic proteins and viral vectors. Despite the increased popularity of this strain we still have limited knowledge on the genetic composition of its derivatives. Here we present a genomic, transcriptomic and metabolic gene analysis of six of the most widely used HEK293 cell lines. Changes in gene copy and expression between industrial progeny cell lines and the original HEK293 were associated with cellular component organization, cell motility and cell adhesion. Changes in gene expression between adherent and suspension derivatives highlighted switching in cholesterol biosynthesis and expression of five key genes (RARG, ID1, ZIC1, LOX and DHRS3), a pattern validated in 63 human adherent or suspension cell lines of other origin
Globally Distributed Drug Discovery of New Antibiotics: Design and Combinatorial Synthesis of Amino Acid Derivatives in the Organic Chemistry Laboratory
An experiment for the synthesis of N-acyl derivatives of natural amino acids has been developed as part of the Distributed Drug Discovery (D3) program. Students use solid-phase synthesis techniques to complete a three-step, combinatorial synthesis of six products, which are analyzed using LC–MS and NMR spectroscopy. This protocol is suitable for introductory organic laboratory students and has been successfully implemented at multiple academic sites internationally. Accompanying prelab activities introduce students to SciFinder and to medicinal chemistry design principles. Pairing of these activities with the laboratory work provides students an authentic and cohesive research project experience
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