936 research outputs found
Proton-induced magnetic order in carbon: SQUID measurements
In this work we have studied systematically the changes in the magnetic
behavior of highly oriented pyrolytic graphite (HOPG) samples after proton
irradiation in the MeV energy range. Superconducting quantum interferometer
device (SQUID) results obtained from samples with thousands of localized spots
of micrometer size as well on samples irradiated with a broad beam confirm
previously reported results. Both, the para- and ferromagnetic contributions
depend strongly on the irradiation details. The results indicate that the
magnetic moment at saturation of spots of micrometer size is of the order of
emu.Comment: Invited contribution at ICACS2006 to be published in Nucl. Instr. and
Meth. B. 8 pages and 6 figure
Fingerprints of Spin-Orbital Physics in Crystalline O
The alkali hyperoxide KO is a molecular analog of strongly-correlated
systems, comprising of orbitally degenerate magnetic O ions. Using
first-principles electronic structure calculations, we set up an effective
spin-orbital model for the low-energy \textit{molecular} orbitals and argue
that many anomalous properties of KO replicate the status of its orbital
system in various temperature regimes.Comment: 4 pages, 2 figures, 1 tabl
Induced Magnetic Ordering by Proton Irradiation in Graphite
We provide evidence that proton irradiation of energy 2.25 MeV on
highly-oriented pyrolytic graphite samples triggers ferro- or ferrimagnetism.
Measurements performed with a superconducting quantum interferometer device
(SQUID) and magnetic force microscopy (MFM) reveal that the magnetic ordering
is stable at room temperature.Comment: 3 Figure
First-Principles Study of Substitutional Metal Impurities in Graphene: Structural, Electronic and Magnetic Properties
We present a theoretical study using density functional calculations of the
structural, electronic and magnetic properties of 3d transition metal, noble
metal and Zn atoms interacting with carbon monovacancies in graphene. We pay
special attention to the electronic and magnetic properties of these
substitutional impurities and found that they can be fully understood using a
simple model based on the hybridization between the states of the metal atom,
particularly the d shell, and the defect levels associated with an
unreconstructed D3h carbon vacancy. We identify three different regimes
associated with the occupation of different carbon-metal hybridized electronic
levels:
(i) bonding states are completely filled for Sc and Ti, and these impurities
are non-magnetic;
(ii) the non-bonding d shell is partially occupied for V, Cr and Mn and,
correspondingly, these impurties present large and localized spin moments;
(iii) antibonding states with increasing carbon character are progressively
filled for Co, Ni, the noble metals and Zn. The spin moments of these
impurities oscillate between 0 and 1 Bohr magnetons and are increasingly
delocalized.
The substitutional Zn suffers a Jahn-Teller-like distortion from the C3v
symmetry and, as a consequence, has a zero spin moment. Fe occupies a distinct
position at the border between regimes (ii) and (iii) and shows a more complex
behavior: while is non-magnetic at the level of GGA calculations, its spin
moment can be switched on using GGA+U calculations with moderate values of the
U parameter.Comment: 13 figures, 4 tables. Submitted to Phys. Rev. B on September 26th,
200
Magnetic properties of carbon phases synthesized using high pressure-high temperature treatment
Two sets of samples were synthesized at 3.5 GPa near the point of C60 cage
collapse at different annealing times. A clear structural transformation from
mixture of C60 polymeric phases to graphite-like hard carbon phase was
confirmed by X-ray diffraction and Raman spectroscopy. Magnetic force
microscopy and superconducting quantum interference device were used to
characterize the magnetic properties of the synthesized samples. We found that
the sample preparation conditions used in this study are not suitable to
produce bulk magnetic carbon.Comment: 26 pages, 7 figure
High-temperature ferromagnetism of electrons in narrow impurity bands: Application to CaB
Ferromagnetism with high Curie temperature , well above room
temperature, and very small saturation moment has been reported in various
carbon and boron systems. It is argued that the magnetization must be very
inhomogeneous with only a small fraction of the sample ferromagnetically
ordered. It is shown that a possible source of high within the
ferromagnetic regions is itinerant electrons occupying a narrow impurity band.
Correlation effects do not reduce the effective interaction which enters the
Stoner criterion in the same way as in a bulk band. It is also shown how, in
the impurity band case, spin wave excitations may not be effective in lowering
below its value given by Stoner theory. These ideas are applied to
CaB and a thorough review of the experimental situation in this material is
given. It is suggested that the intrinsic magnetism of the B and O
dimers might be exploited in suitable structures containing these elements.Comment: 26 pages, 2 figure
Magnetic fluctuations in frustrated Laves hydrides R(Mn_{1-x}Al_{x})_{2}H_{y}
By neutron scattering, we have studied the spin correlations and spin
fluctuations in frustrated Laves hydrides, where magnetic disorder sets in the
topologically frustrated Mn lattice. Below the transition towards short range
magnetic order, static spin clusters coexist with fluctuating and alsmost
uncorrelated spins. The magnetic response shows a complexe lineshape, connected
with the presence of the magnetic inhomogeneities. Its analysis shows the
existence of two different processes, relaxation and local excitations, for the
spin fluctuations below the transition. The paramagnetic fluctuations are
discussed in comparison with classical spin glasses, cluster glasses, and non
Fermi liquid itinerant magnets
The Contribution of Magnetic Nanoparticles to Ferrogel Biophysical Properties
Iron oxide gamma-Fe(2)O(3 )magnetic nanoparticles (MNPs) were fabricated by laser target evaporation technique (LTE) and their structure and magnetic properties were studied. Polyacrylamide (PAAm) gels with different cross-linking density of the polymer network and polyacrylamide-based ferrogel with embedded LTE MNPs (0.34 wt.%) were synthesized. Their adhesive and proliferative potential with respect to human dermal fibroblasts were studied. At the same value of Young modulus, the adhesive and proliferative activities of the human dermal fibroblasts on the surface of ferrogel were unexpectedly much higher in comparison with the surface of PAAm gel. Properties of PAAm-100 + gamma-Fe2O3 MNPs composites were discussed with focus on creation of a new generation of drug delivery systems combined in multifunctional devices, including magnetic field assisted delivery, positioning, and biosensing. Although exact applications are still under development, the obtained results show a high potential of LTE MNPs to be applied for cellular technologies and tissue engineering. PAAm-100 ferrogel with very low concentration of gamma-Fe2O3 MNPs results in significant improvement of the cells' compatibility to the gel-based scaffold
Far-infrared vibrational properties of linear C60 polymers: A comparison between neutral and charged materials
We report the far-infrared transmittance spectrum of a pure phase of the orthorhombic high-temperature and high-pressure C-60 polymer and compare the results with a previously published spectrum of the charged RbC60 orthorhombic polymer. Assignments for both spectra are made with the aid of first-principles quantum molecular dynamics simulations of the two materials. We find that the striking spectral differences between the neutral and charged linear fullerene polymers can be fully accounted for by charge effects on the C-60 ball
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