The impact of free convection on late morning ozone decreases on an Alpine foreland mountain summit

Exceptional patterns in the diurnal course of ozone mixing ratio at a mountain top site (998 m a.s.l.) were observed during a field experiment (September 2005). They manifested themselves as strong and sudden decreases of ozone mixing ratio with a subsequent return to previous levels. The evaluation of corresponding long-term time series (2000–2005) revealed that such events occur mainly during summer, and affect the mountain top site on about 18% of the summer days. Combining (a) surface layer measurements at mountain summit and at the foot of the mountain, (b) in-situ (tethered balloon) and remote sensing (SODAR-RASS) measurements within the atmospheric boundary layer, the origin of these events of sudden ozone decrease could be attributed to free convection. The free convection was triggered by a rather frequently occurring wind speed minimum around the location of the mountain

Seasonal variation of ozone deposition to a tropical rain forest in southwest Amazonia

International audienceWithin the project EUropean Studies on Trace gases and Atmospheric CHemistry as a contribution to Large-scale Biosphere-atmosphere experiment in Amazonia (LBA-EUSTACH), we performed tower-based eddy covariance measurements of O3 flux above an Amazonian primary rain forest at the end of the wet and dry season. Ozone deposition revealed distinct seasonal differences in the magnitude and diel variation. In the wet season, the rain forest was an effective O3 sink with a mean daytime (midday) maximum deposition velocity of 2.3 cm s?1, and a corresponding O3 flux of ?11 nmol m?2 s?1. At the end of the dry season, the ozone mixing ratio was about four times higher (up to maximum values of 80 ppb) than in the wet season, as a consequence of strong regional biomass burning activity. However, the typical maximum daytime deposition flux was very similar to the wet season. This results from a strong limitation of daytime O3 deposition due to reduced plant stomatal aperture as a response to large values of the specific humidity deficit. As a result, the average midday deposition velocity in the dry burning season was only 0.5 cm s?1. The large diel ozone variation caused large canopy storage effects that masked the true diel variation of ozone deposition mechanisms in the measured eddy covariance flux, and for which corrections had to be made. In general, stomatal aperture was sufficient to explain the largest part of daytime ozone deposition. However, during nighttime, chemical reaction with nitrogen monoxide (NO) was found to contribute substantially to the O3 sink in the rain forest canopy. Further contributions were from non-stomatal plant uptake and other processes that could not be clearly identified. Measurements, made simultaneously on a 22 years old cattle pasture enabled the spatially and temporally direct comparison of O3 dry deposition values from this site with typical vegetation cover of deforested land in southwest Amazonia to the results from the primary rain forest. The mean ozone deposition to the pasture was found to be systematically lower than that to the forest by 30% in the wet and 18% in the dry season

The enigmatic B[e]-star Henize 2-90: The non-spherical mass loss history from an analysis of forbidden lines

(abridged) We study the optical spectrum of the exciting B[e] star Hen 2-90 based on new high-resolution observations that cover the innermost 2". Our investigation is splitted in two parts, a qualitative study of the presence of the numerous emission lines and the classification of their line profiles which indicate a circumstellar environment of high complexity, and a quantitative analysis of numerous forbidden lines, e.g. [OI], [OII], [OIII], [SII], [SIII], [ArIII], [ClII], [ClIII] and [NII]. We find a correlation between the different ionization states of the elements and the velocities derived from the line profiles: the highly ionized atoms have the highest outflow velocity while the neutral lines have the lowest outflow velocity. The recent HST image of Hen 2-90 reveals a bipolar, highly ionized region, a neutral disk-like structure and an intermediate region of moderate ionization. It seems that a non-spherical stellar wind model is a good option to explain the ionization and spatial distribution of the circumstellar material. We modelled the forbidden lines under the assumption of a non-spherically symmetric wind based on the HST image. We find that in order to fit the observed line luminosities, the mass flux, surface temperature, and terminal wind velocities need to be latitude dependent, which might be explained in terms of a rapidly rotating central star. A rotation speed of 75-80 % of the critical velocity has been derived. The total mass loss rate of the star was determined to be of order 3 10^{-5} M_sun/yr. Such a wind scenario and the fact that compared to solar abundances C, O, and N seem to be underabundant while S, Ar and Cl have solar abundances, might be explained in terms of a rapidly rotating post-AGB star.Comment: 16 pages, 13 figures, accepted for publication in A&A. Table 4 is included at the end of the paper. This table will only be available in the online version of the paper and will not appear in the printed versio

Surface and Boundary Layer Exchanges of Volatile Organic Compounds, Nitrogen Oxides and Ozone During the GABRIEL Campaign

Abstract. We present an evaluation of sources, sinks and turbulent transport of nitrogen oxides, ozone and volatile organic compounds (VOC) in the boundary layer over French Guyana and Suriname during the October 2005 GABRIEL campaign by simulating observations with a single-column chemistry and climate model (SCM) along a zonal transect. Simulated concentrations of O3 and NO as well as NO2 photolysis rates over the forest agree well with observations when a small soil-biogenic NO emission flux was applied. This suggests that the photochemical conditions observed during GABRIEL reflect a pristine tropical low-NOx regime. The SCM uses a compensation point approach to simulate nocturnal deposition and daytime emissions of acetone and methanol and produces daytime boundary layer mixing ratios in reasonable agreement with observations. The area average isoprene emission flux, inferred from the observed isoprene mixing ratios and boundary layer height, is about half the flux simulated with commonly applied emission algorithms. The SCM nevertheless simulates too high isoprene mixing ratios, whereas hydroxyl concentrations are strongly underestimated compared to observations, which can at least partly explain the discrepancy. Furthermore, the model substantially overestimates the isoprene oxidation products methlyl vinyl ketone (MVK) and methacrolein (MACR) partly due to a simulated nocturnal increase due to isoprene oxidation. This increase is most prominent in the residual layer whereas in the nocturnal inversion layer we simulate a decrease in MVK and MACR mixing ratios, assuming efficient removal of MVK and MACR. Entrainment of residual layer air masses, which are enhanced in MVK and MACR and other isoprene oxidation products, into the growing boundary layer poses an additional sink for OH which is thus not available for isoprene oxidation. Based on these findings, we suggest pursuing measurements of the tropical residual layer chemistry with a focus on the nocturnal depletion of isoprene and its oxidation products.JRC.H.2-Climate chang

Magnetic Properties of YBa_2Cu_3O_{7-\delta} in a self-consistent approach: Comparison with Quantum-Monte-Carlo Simulations and Experiments

We analyze single-particle electronic and two-particle magnetic properties of the Hubbard model in the underdoped and optimally-doped regime of \YBCO by means of a modified version of the fluctuation-exchange approximation, which only includes particle-hole fluctuations. Comparison of our results with Quantum-Monte Carlo (QMC) calculations at relatively high temperatures ($T\sim 1000 K$) suggests to introduce a temperature renormalization in order to improve the agreement between the two methods at intermediate and large values of the interaction $U$. We evaluate the temperature dependence of the spin-lattice relaxation time $T_1$ and of the spin-echo decay time $T_{2G}$ and compare it with the results of NMR measurements on an underdoped and an optimally doped \YBCO sample. For $U/t=4.5$ it is possible to consistently adjust the parameters of the Hubbard model in order to have a good {\it semi-quantitative} description of this temperature dependence for temperatures larger than the spin gap as obtained from NMR measurements. We also discuss the case $U/t\sim 8$, which is more appropriate to describe magnetic and single-particle properties close to half-filling. However, for this larger value of $U/t$ the agreement with QMC as well as with experiments at finite doping is less satisfactory.Comment: Final version, to appear in Phys. Rev. B (sched. Feb. 99

New Magellanic Cloud R Coronae Borealis and DY Per type stars from the EROS-2 database: the connection between RCBs, DYPers and ordinary carbon stars

R Coronae Borealis stars (RCB) are a rare type of evolved carbon-rich supergiant stars that are increasingly thought to result from the merger of two white dwarfs, called the Double degenerate scenario. This scenario is also studied as a source, at higher mass, of type Ia Supernovae (SnIa) explosions. Therefore a better understanding of RCBs composition would help to constrain simulations of such events. We searched for and studied RCB stars in the EROS Magellanic Clouds database. We also extended our research to DY Per type stars (DYPers) that are expected to be cooler RCBs (T~3500 K) and much more numerous than their hotter counterparts. The light curves of ~70 millions stars have been analysed to search for the main signature of RCBs and DYPers: a large drop in luminosity. Follow-up optical spectroscopy was used to confirm each photometric candidate found. We have discovered and confirmed 6 new Magellanic Cloud RCB stars and 7 new DYPers, but also listed new candidates: 3 RCBs and 14 DYPers. We estimated a range of Magellanic RCB shell temperatures between 360 and 600 K. We confirm the wide range of absolute luminosity known for RCB stars, M_V~-5.2 to -2.6. Our study further shows that mid-infrared surveys are ideal to search for RCB stars, since they have thinner and cooler circumstellar shells than classical post-AGB stars. In addition, by increasing the number of known DYPers by ~400%, we have been able to shed light on the similarities in the spectral energy distribution between DYPers and ordinary carbon stars. We also observed that DYPer circumstellar shells are fainter and hotter than those of RCBs. This suggests that DYPers may simply be ordinary carbon stars with ejection events, but more abundance analysis is necessary to give a status on a possible evolutionnary connexion between RCBs and DYPers.Comment: 22 pages, 38 figures, Accepted for publication in A&

Angle resolved photoemission spectroscopy of Sr_2CuO_2Cl_2 - a revisit

We have investigated the lowest binding-energy electronic structure of the model cuprate Sr_2CuO_2Cl_2 using angle resolved photoemission spectroscopy (ARPES). Our data from about 80 cleavages of Sr_2CuO_2Cl_2 single crystals give a comprehensive, self-consistent picture of the nature of the first electron-removal state in this model undoped CuO_2-plane cuprate. Firstly, we show a strong dependence on the polarization of the excitation light which is understandable in the context of the matrix element governing the photoemission process, which gives a state with the symmetry of a Zhang-Rice singlet. Secondly, the strong, oscillatory dependence of the intensity of the Zhang-Rice singlet on the exciting photon-energy is shown to be consistent with interference effects connected with the periodicity of the crystal structure in the crystallographic c-direction. Thirdly, we measured the dispersion of the first electron-removal states along G->(pi,pi) and G->(pi,0), the latter being controversial in the literature, and have shown that the data are best fitted using an extended t-J-model, and extract the relevant model parameters. An analysis of the spectral weight of the first ionization states for different excitation energies within the approach used by Leung et al. (Phys. Rev. B56, 6320 (1997)) results in a strongly photon-energy dependent ratio between the coherent and incoherent spectral weight. The possible reasons for this observation and its physical implications are discussed.Comment: 10 pages, 8 figure

Competing orders in a magnetic field: spin and charge order in the cuprate superconductors

We describe two-dimensional quantum spin fluctuations in a superconducting Abrikosov flux lattice induced by a magnetic field applied to a doped Mott insulator. Complete numerical solutions of a self-consistent large N theory provide detailed information on the phase diagram and on the spatial structure of the dynamic spin spectrum. Our results apply to phases with and without long-range spin density wave order and to the magnetic quantum critical point separating these phases. We discuss the relationship of our results to a number of recent neutron scattering measurements on the cuprate superconductors in the presence of an applied field. We compute the pinning of static charge order by the vortex cores in the `spin gap' phase where the spin order remains dynamically fluctuating, and argue that these results apply to recent scanning tunnelling microscopy (STM) measurements. We show that with a single typical set of values for the coupling constants, our model describes the field dependence of the elastic neutron scattering intensities, the absence of satellite Bragg peaks associated with the vortex lattice in existing neutron scattering observations, and the spatial extent of charge order in STM observations. We mention implications of our theory for NMR experiments. We also present a theoretical discussion of more exotic states that can be built out of the spin and charge order parameters, including spin nematics and phases with `exciton fractionalization'.Comment: 36 pages, 33 figures; for a popular introduction, see http://onsager.physics.yale.edu/superflow.html; (v2) Added reference to new work of Chen and Ting; (v3) reorganized presentation for improved clarity, and added new appendix on microscopic origin; (v4) final published version with minor change

Tropospheric vertical column densities of NO<sub>2</sub> over managed dryland ecosystems (Xinjiang, China): MAX-DOAS measurements vs. 3-D dispersion model simulations based on laboratory-derived NO emission from soil samples

We report on MAX-DOAS observations of NO2 over an oasis–ecotone–desert ecosystem in NW China. There, local ambient NO2 concentrations originate from enhanced biogenic NO emission of intensively managed soils. Our target oasis "Milan" is located at the southern edge of the Taklimakan desert, very remote and well isolated from other potential anthropogenic and biogenic NOx sources. Four observation sites for MAX-DOAS measurements were selected, at the oasis centre, downwind and upwind of the oasis, and in the desert. Biogenic NO emissions in terms of (i) soil moisture and (ii) soil temperature of Milan oasis (iii) different land-cover type sub-units (cotton, Jujube trees, cotton/Jujube mixture, desert) were quantified by laboratory incubation of corresponding soil samples. Net potential NO fluxes were up-scaled to oasis scale by areal distribution and classification of land-cover types derived from satellite images using GIS techniques. A Lagrangian dispersion model (LASAT, Lagrangian Simulation of Aerosol Transport) was used to calculate the dispersion of soil emitted NO into the atmospheric boundary layer over Milan oasis. Three-dimensional (3-D) NO concentrations (30 m horizontal resolution) have been converted to 3-D NO2 concentrations, assuming photostationary state conditions. NO2 column densities were simulated by suitable vertical integration of modelled 3-D NO2 concentrations at those downwind and upwind locations, where the MAX-DOAS measurements were performed. Downwind–upwind differences (a direct measure of Milan oasis' contribution to the areal increase of ambient NO2 concentration) of measured and simulated slant (as well as vertical) NO2 column densities show excellent agreement. This agreement is considered as the first successful attempt to prove the validity of the chosen approach to up-scale laboratory-derived biogenic NO fluxes to ecosystem field conditions, i.e. from the spatial scale of a soil sample (cm2) to the size of an entire agricultural ecosystem (km2)