Recent advances and perspectives on starch nanocomposites for packaging applications

Starch nanocomposites are popular and abundant materials in packaging sectors. The aim of this work is to review some of the most popular starch nanocomposite systems that have been used nowadays. Due to a wide range of applicable reinforcements, nanocomposite systems are investigated based on nanofiller type such as nanoclays, polysaccharides and carbonaceous nanofillers. Furthermore, the structures of starch and material preparation methods for their nanocomposites are also mentioned in this review. It is clearly presented that mechanical, thermal and barrier properties of plasticised starch can be improved with well-dispersed nanofillers in starch nanocomposites

Thermal and mechanical properties of chitosan nanocomposites with cellulose modified in ionic liquids

In this paper, ionic liquid treatment was applied to produce nanometric cellulose particles of two polymorphic forms. A complex characterization of nanofillers including wide-angle X-ray scattering, Fourier transform infrared spectroscopy, and particle size determination was performed. The evaluated ionic liquid treatment was effective in terms of nanocrystalline cellulose production, leaving chemical and supermolecular structure of the materials intact. However, nanocrystalline cellulose II was found to be more prone to ionic liquid hydrolysis leading to formation larger amount of small particles. Each nanocrystalline cellulose was subsequently mixed with a solution of chitosan, so that composite films containing 1, 3, and 5% mass/mass of nanometric filler were obtained. Reference samples of chitosan and chitosan with micrometric celluloses were also solvent casted. Thermal, mechanical, and morphological properties of films were tested and correlated with properties of filler used. The results of both, tensile tests and thermogravimetric analysis showed a significant discrepancy between composites filled with nanocrystalline cellulose I and nanocrystalline cellulose II

An Accurately Controlled Antagonistic Shape Memory Alloy Actuator with Self-Sensing

With the progress of miniaturization, shape memory alloy (SMA) actuators exhibit high energy density, self-sensing ability and ease of fabrication, which make them well suited for practical applications. This paper presents a self-sensing controlled actuator drive that was designed using antagonistic pairs of SMA wires. Under a certain pre-strain and duty cycle, the stress between two wires becomes constant. Meanwhile, the strain to resistance curve can minimize the hysteresis gap between the heating and the cooling paths. The curves of both wires are then modeled by fitting polynomials such that the measured resistance can be used directly to determine the difference between the testing values and the target strain. The hysteresis model of strains to duty cycle difference has been used as compensation. Accurate control is demonstrated through step response and sinusoidal tracking. The experimental results show that, under a combination control program, the root-mean-square error can be reduced to 1.093%. The limited bandwidth of the frequency is estimated to be 0.15 Hz. Two sets of instruments with three degrees of freedom are illustrated to show how this type actuator could be potentially implemented

A Comparative Study of Ni49.9Ti50.1 and Ni50.3Ti29.7Hf20 Tube Actuators

© 2015, ASM International. A shape memory alloy (SMA) actuator typically has to operate for a large number of thermomechanical cycles due to its application requirements. Therefore, it is necessary to understand the cyclic behavioral response of the SMA actuation material and the devices into which they are incorporated under extended cycling conditions. The present work is focused on the nature of the cyclic, evolutionary behavior of two widely used SMA actuator material systems: (1) a commercially available Ni49.9Ti50.1, and (2) a developmental high-temperature Ni50.3Ti29.7Hf20 alloy. Using a recently developed general SMA modeling framework that utilizes multiple inelastic mechanisms, differences and similarities between the two classes of materials are studied, accounting for extended number of thermal cycles under a constant applied tensile/compressive force and under constant applied torque loading. From the detailed results of the simulations, there were significant qualitative differences in the evolution of deformation responses for the two different materials. In particular, the Ni49.9Ti50.1 tube showed significant evolution of the deformation response, whereas the Ni50.3Ti29.7Hf20 tube stabilized quickly. Moreover, there were significant differences in the tension-compression-shear asymmetry properties in the two materials. More specifically, the Ni50.3Ti29.7Hf20 tube exhibited much higher asymmetry effects, especially at low stress levels, compared to the Ni49.9Ti50.1. For both SMA tubes, the evolution of the deformation response under thermal cycling typically exhibited regions of initial transients, and subsequent evolution