Comparative Analysis of Mineralogical Characteristics of Clay-Rich Soil Samples obtained from Gbajimba, Angbaaye and Makurdi Areas of Benue State

The elemental concentrations and mineralogical composition of soil samples from Gbajimba, Angbaaye and Makurdi areas of Benue state were evaluated. Their clay fractions (particles smaller than 2 microns) studied through a series of mineralogical, chemical and physico-chemical analyses showed that the colour test of the sample showed brown to red. The study suggested that morphology of kaolinitic and quartz minerals is influenced by the parent material (i.e. feldspars or micas) and degree of chemical weathering. The pH values of pore water from clay samples showed acidity, ranging from 4.93 - 6.96. The electrical conductivities (EC) of the samples ranged from 2.68-3.48 mS/cm – 3.48mS/cm. The CEC results of the sample showed a 6.98-7.32 range. The results of X-ray diffraction (XRD), infrared spectroscopy (IR), Scanning Electron Microscopy (SEM) characterization showed that the soil samples from these three areas with clay-rich soil were a mixtures of kaolinite, quartz, muscovite, microline, pyrite, chlorite and sylvite, showing quartz present in all samples. The results obtained from XRF showed that the clay samples mostly composed of silicon (IV) oxide in Gbajimba(51.538%), Angbaaye (49.107%) and Makurdi (64.826%); Aluminum in Gbajimba (18.883%), Angbaaye (22.419%) and Makurdi(16.319%);Iron in Gbajimba (8.3230%), Angbaaye (8.8611%) and Makurdi (4.2672%); Manganese, phosphorous, titanium etc. These are the proportion of the major expected elements. Hence, the results from the analysis fell within the same range of results from other works studied

Robust adaptive algorithms for underwater acoustic channel estimation and their performance analysis

We introduce a novel family of adaptive robust channel estimators for highly challenging underwater acoustic (UWA) channels. Since the underwater environment is highly non-stationary and subjected to impulsive noise, we use adaptive filtering techniques based on minimization of a logarithmic cost function, which results in a better trade-off between the convergence rate and the steady state performance of the algorithm. To improve the convergence performance of the conventional first and second order linear estimation methods while mitigating the stability issues related to impulsive noise, we intrinsically combine different norms of the error in the cost function using a logarithmic term. Hence, we achieve a comparable convergence rate to the faster algorithms, while significantly enhancing the stability against impulsive noise in such an adverse communication medium. Furthermore, we provide a thorough analysis for the tracking and steady-state performances of our proposed methods in the presence of impulsive noise. In our analysis, we not only consider the impulsive noise, but also take into account the frequency and phase offsets commonly experienced in real life experiments. We demonstrate the performance of our algorithms through highly realistic experiments performed on accurately simulated underwater acoustic channels. © 2017 Elsevier Inc

From Conventional to State-of-the-Art IoT Access Control Models

open access articleThe advent in Online Social Networks (OSN) and Internet of Things (IoT) has created a new world of collaboration and communication between people and devices. The domain of internet of things uses billions of devices (ranging from tiny sensors to macro scale devices) that continuously produce and exchange huge amounts of data with people and applications. Similarly, more than a billion people are connected through social networking sites to collaborate and share their knowledge. The applications of IoT such as smart health, smart city, social networking, video surveillance and vehicular communication are quickly evolving people’s daily lives. These applications provide accurate, information-rich and personalized services to the users. However, providing personalized information comes at the cost of accessing private information of users such as their location, social relationship details, health information and daily activities. When the information is accessible online, there is always a chance that it can be used maliciously by unauthorized entities. Therefore, an effective access control mechanism must be employed to ensure the security and privacy of entities using OSN and IoT services. Access control refers to a process which can restrict user’s access to data and resources. It enforces access rules to grant authorized users an access to resources and prevent others. This survey examines the increasing literature on access control for traditional models in general, and for OSN and IoT in specific. Challenges and problems related to access control mechanisms are explored to facilitate the adoption of access control solutions in OSN and IoT scenarios. The survey provides a review of the requirements for access control enforcement, discusses several security issues in access control, and elaborates underlying principles and limitations of famous access control models. We evaluate the feasibility of current access control models for OSN and IoT and provide the future development direction of access control for the sam

Mid-channel braid bar induced turbulent bursts: analysis using octant events approach

YesIn a laboratory, a model of a mid-channel bar is built to study the turbulent flow structures in its vicinity. The present study on the turbulent flow structure around a mid-channel bar is based on unravelling the fluvial fluxes triggered by the bar’s 3D turbulent burst phenomenon. To this end, the three-dimensional velocity components are measured with the help of acoustic doppler velocimetry (ADV). The results indicate that the transverse component of turbulent kinetic energy cannot be neglected when analyzing turbulent burst processes, since the dominant flow is three-dimensional around the mid-channel bar. Due to the three-dimensionality of flow, the octant events approach is used for analyzing the flow in the vicinity of the mid-channel bar. The aim is to develop functional relationships between the stable movements that are modelled in the present study. To find the best Markov chain order to present experimental datasets, the zero-, first-, and second-order Markov chains are analyzed using the Akaike information criterion (AIC) and the Bayesian information criterion (BIC). The parameter transition ratio has evolved in this research to reflect the linkage of streambed elevation changes with stable transitional movements. For a better understanding of the temporal behaviors of stable transitional movements, the residence time vs. frequency graphs are also plotted for scouring as well as for depositional regions. The study outcome herein underlines the usefulness of the octant events approach for characterizing turbulent bursts around mid-channel bar formation, which is a precursor to the initiation of braiding configuration.This research and APC was funded by King Saud University, Riyadh, Saudi Arabia through Researchers Supporting Project number (RSP-2021/297)

Photocatalytic treatment technology for palm oil mill effluent (POME) – A review

This review provides insight into various techniques utilized for the treatments of palm oil mill effluents (POME). Generally, POME treatment is achieved in two ways, these are (1) pre-treatment stages, involving majorly the reduction of oil and grease and suspended matter and (2) an advanced treatment stage, in which wastewater contaminants (e.g. BOD5, COD) are reduced to standard discharge limits. Different methods utilized in the treatment of POME such as coagulation-flocculation, anaerobic, aerobic and membrane technology are explained fully and recent trends in their advancement and improvement are outlined. Though, various pilot or industrial scale treatment plants have been reported in scientific literature for POME treatments methods such as anaerobic, aerobic and membrane technology, the literature is still scarce for application of photocatalytic degradation technology to POME treatment as the technology is still in development stage and has not been fully utilized on an industrial scale in palm oil mill industries. This is mainly as a result of inadequate investigation involving POME degradation. The review presented here is focused on photocatalytic degradation technology and reflects published outcomes with the aim of offering the technique as an attractive and sustainable process units. Also the potential of the process to replace some of the well-known separation and degradation technologies has been highlighted at advanced treatment stage for POME

The Persistence Length of a Strongly Charged, Rod-like, Polyelectrolyte in the Presence of Salt

The persistence length of a single, intrinsically rigid polyelectrolyte chain, above the Manning condensation threshold is investigated theoretically in presence of added salt. Using a loop expansion method, the partition function is consistently calculated, taking into account corrections to mean-field theory. Within a mean-field approximation, the well-known results of Odijk, Skolnick and Fixman are reproduced. Beyond mean-field, it is found that density correlations between counterions and thermal fluctuations reduce the stiffness of the chain, indicating an effective attraction between monomers for highly charged chains and multivalent counterions. This attraction results in a possible mechanical instability (collapse), alluding to the phenomenon of DNA condensation. In addition, we find that more counterions condense on slightly bent conformations of the chain than predicted by the Manning model for the case of an infinite cylinder. Finally, our results are compared with previous models and experiments.Comment: 13 pages, 2 ps figure

Effective interaction between helical bio-molecules

The effective interaction between two parallel strands of helical bio-molecules, such as deoxyribose nucleic acids (DNA), is calculated using computer simulations of the "primitive" model of electrolytes. In particular we study a simple model for B-DNA incorporating explicitly its charge pattern as a double-helix structure. The effective force and the effective torque exerted onto the molecules depend on the central distance and on the relative orientation. The contributions of nonlinear screening by monovalent counterions to these forces and torques are analyzed and calculated for different salt concentrations. As a result, we find that the sign of the force depends sensitively on the relative orientation. For intermolecular distances smaller than $6\AA$ it can be both attractive and repulsive. Furthermore we report a nonmonotonic behaviour of the effective force for increasing salt concentration. Both features cannot be described within linear screening theories. For large distances, on the other hand, the results agree with linear screening theories provided the charge of the bio-molecules is suitably renormalized.Comment: 18 pages, 18 figures included in text, 100 bibliog

Adsorption of mono- and multivalent cat- and anions on DNA molecules

Adsorption of monovalent and multivalent cat- and anions on a deoxyribose nucleic acid (DNA) molecule from a salt solution is investigated by computer simulation. The ions are modelled as charged hard spheres, the DNA molecule as a point charge pattern following the double-helical phosphate strands. The geometrical shape of the DNA molecules is modelled on different levels ranging from a simple cylindrical shape to structured models which include the major and minor grooves between the phosphate strands. The densities of the ions adsorbed on the phosphate strands, in the major and in the minor grooves are calculated. First, we find that the adsorption pattern on the DNA surface depends strongly on its geometrical shape: counterions adsorb preferentially along the phosphate strands for a cylindrical model shape, but in the minor groove for a geometrically structured model. Second, we find that an addition of monovalent salt ions results in an increase of the charge density in the minor groove while the total charge density of ions adsorbed in the major groove stays unchanged. The adsorbed ion densities are highly structured along the minor groove while they are almost smeared along the major groove. Furthermore, for a fixed amount of added salt, the major groove cationic charge is independent on the counterion valency. For increasing salt concentration the major groove is neutralized while the total charge adsorbed in the minor groove is constant. DNA overcharging is detected for multivalent salt. Simulations for a larger ion radii, which mimic the effect of the ion hydration, indicate an increased adsorbtion of cations in the major groove.Comment: 34 pages with 14 figure

Measurement of the B0-anti-B0-Oscillation Frequency with Inclusive Dilepton Events

The $B^0$-$\bar B^0$ oscillation frequency has been measured with a sample of 23 million \B\bar B pairs collected with the BABAR detector at the PEP-II asymmetric B Factory at SLAC. In this sample, we select events in which both B mesons decay semileptonically and use the charge of the leptons to identify the flavor of each B meson. A simultaneous fit to the decay time difference distributions for opposite- and same-sign dilepton events gives $\Delta m_d = 0.493 \pm 0.012{(stat)}\pm 0.009{(syst)}$ ps$^{-1}$.Comment: 7 pages, 1 figure, submitted to Physical Review Letter