Méthodologie d'analyse détaillée de la contamination par tronçon du fleuve Saint-Laurent par modélisation numérique : le cas du lac Saint-Pierre

Dans le cadre du Plan d'Action Saint-Laurent, une méthodologie détaillée d'analyse de la contamination par tronçon faisant appel à la modélisation numérique a été développée. Une méthode de simulation utilisant le mouvement aléatoire de particules a servi à élaborer le logiciel PANACHE. Les concentrations sont obtenues en post-traitement en attribuant une masse de contaminant aux particules du modèle. Les champs de vitesses servant à calculer leurs mouvements sont produits à l'aide d'un modèle bidimensionnel aux éléments finis. Une nouvelle approche pour l'analyse de la contamination est proposée. Celle-ci s'inspire de la méthodologie de modélisation des micro-habitats populaire dans le domaine de l'hydrobiologie. Le résultat apparaît sous la forme d'Aires Pondérées Inutilisables (API), c'est-à-dire, des surfaces où certains critères de qualité de l'eau ne sont pas respectés dans les zones de mélange. Ce système Informatisé a été élaboré sur une plate-forme INTEL/386-486 - OS2/PM.ContextThe St-Lawrence Center, part of Environment Canada, undertook a few years ago the very ambitious project of studying the toxic contamination of the St-Lawrence River. In collaboration with the Institut National de la Recherche Scientifique - Eau, a sub-project based on numerical modeling was defined in order to analyze contaminant propagation from industrial and municipal effluents into the river system.GoalsThe specific goals of the project were the following :1) to provide a precise quantification of contaminant concentrations in the effluent plume al a convenient scale;2) to analyze areas influenced by main tributaries and different water masses entering the river reach;3) to map and quantify areas as compared to water quality criteria ;4) to provide a method to select relevant hydrological events as a significant part of the analysis frameworkMethodologySome basic choices were made at the beginning of the project :1) the analysis framework emphasis the instream water quality instead of the effluent water quality;2) numerical modelling was the main tool used to evaluate the water quality;3) as far as possible references to public regulations were incorporated;4) a strong complementarity of different computer tools was favoured : Geographical Information Systems, Database management systems, simulation models;5) the numerical solution method for the transport diffusion model is typically Lagrangian : the Random Walk Method;6) the contamination analysis uses the so-called « Weighted Unusable Area » method to quantify areas that do not respect some water quality criteria.A typical contamination analysis project based on numerical modelling includes the following steps (fig 2) :1) a preliminary study to determine the main characteristics of the problem and to choose the best strategy to analyze it;2) field measurements essential to the calibration and validation of the computer model;3) hydrodynamic modelling provides the basic data on the flow field; this step includes the calibration and the validation of the model, as well as the prediction of the flow fields corresponding to well-defined and contamination relevant hydrological events;4) hydrological analysis identifies the relevant flow events chat will further be used in the mode) prediction ; this approach allows standardization of this very important input data set and avoids arbitrary choices of flow field;5) transport-diffusion modelling constitutes the main step; it provides the chemical species concentrations downstream from the effluent discharge and affords an estimate of the overall water quality of the reach, as influenced by the main tributaries. This step includes the calibration and the validation of the model which precedes the prediction exercise;6) contamination analysis necessitates the choice of appropriate and relevant water quality criteria ; we propose a new approach, inspired by the Instream Flow Incremental Methodology often used to define the quality and availability of fish habitat in river reaches, to implement this step.Numerical methodsAs previously mentioned, the project included the development of a Lagrangian model to simulate the transport of solutes in a two-dimensional steady-state river flow. We will emphasize this point. The main objective of the software development was to provide an efficient and user-friendly management tool for the public agencies. Many analytical test cases helped in the choice of the best numerical algorithms, non-physical related parameters, and in the validation of the computer code. Furthermore, the results of two dye tracing experiments performed in conjunction with airborne remote sensing techniques provided data to validate the model on the St-Lawrence River (fig. 5, 6, land 8 illustrate different simulation results corresponding to the different tasks mentioned previously). In the next paragraphs, we will summerize the basic mathematical and numerical concepts implemented in the simulations.To simulate solute transport in water media (porous or free surface), one usually uses eulerian methods which lead directly to concentration values. The solution algorithm presented here is rather based on a Lagrangian method which offers an explicit control over the additional numerical diffusion associated with every discretization method. This approach, also called the Random Walk Method (illustrated in fig. 3), or Particle Tracking Method, is more and more often used to solve hyperbolic equations. So far, the literature does not provide many applications of this method to solute transport in free surface flow. Oil spin modeling is a domain where many applications have been reported.The propagation of solute matter in free surface flow is mathematically described with momentum, mass and solute conservation equations. Since the Random Walk solution method of the transport-diffusion equation (equ. 1) requires hydrodynamic data to calculate the mean transport on streamlines along with dispersion, independent simulations providing the necessary flow field data (velocities, diffusivities, depths) have to be performed before undertaking the transport-diffusion tasks. For this purpose, the Navier-Stokes shallow water equations have become a well known tool to represent flow field in shallow waters. However, one should be aware of some often neglected but important aspects of such models, such as moving boundaries and turbulence closure. Solution techniquesTwo main goals were kept in mind during the implementation of the various algorithms : precision of results and fast computation. The following choices were made to achieve these objectives :1) A finite element discretization and solution method provides and carries hydrodynamic Information, but particles are tracked on a finite-difference grid (mixed discretization principle).2) The convective component of the movement is realized by moving the grid instead of the particles (shifted grid principle).3) Computation of concentrations optimizes smoothing while minimizing artificial diffusion (controlled effusive smoothing principle).4) When a section of the plume is described in a steady state « regime », it is mot necessary to continue the simulation on that section to proceed downstream ; the simulation is divided in almost independent sections (convolution principle).5) The particles have an a priori nondimensional weight and a unit concentration is calculated from these (unit plume principle).6) The real concentration is linearly dependent on the pollutant loads introduced into the milieu (linearity principle).The Weighted Unusable Area MethodThe Weighted Unusable Area method provides a convenient means to compare effluent plume water quality to water quality criteria as well as to quantify areas that do not comply to them. A comparable method is widely used to define the quality and availability of fish habitat downstream from regulation reservoirs, with the purpose of establishing minimum guaranteed flow discharge to protect target species (the Instream Flow Incremental Methodology : IFIM). The method consists essentially of computing areas within the analysis domain weighted by a certain factor that represents the exceedence of certain water quality, criteria. Among different options to define the weighting factor, all incorporating the effective contaminant concentration, we defined the following :1) the ratio of the concentration to the water quality criterion without consideration of exceedence or compliance;2) weighting factor equal to 1 only if the concentration exceeds the criterion (non-compliance);3) option #1, but using the concentration results corresponding only to the effluent plumes excluding the ambient water quality of the reach ; this emphasizes individual corporate responsibility (proposed for implementation);4) option 11, but with the ratio increased by a power « n », a procedure that emphasizes the non-linear increase of toxicity related to the exceedence of the criterion (could be useful for academic purposes).We also propose a Global Weighted Unusable Area concept to combine all the different chemical species present in an effluent plume. The combination is made possible using the specific criterion corresponding to each species. This procedure leads to a new state variable that represents Contamination Standard Units

The spectral type of CHS7797 - an intriguing very low mass periodic variable in the Orion Nebula Cluster

We present the spectroscopic characterization of the unusual high-amplitude very low mass pre-main-sequence periodic variable CHS7797. This study is based on optical medium-resolution (R=2200) spectroscopy in the 6450-8600 A range, carried out with GMOS-GEMINI-S in March 2011. Observations of CHS7797 have been carried out at two distinct phases of the 17.8d period, namely at maximum and four days before maximum. Four different spectral indices were used for the spectral classification at these two phases, all of them well-suited for spectral classification of young and obscured late M dwarfs. In addition, the gravity-sensitive NaI (8183/8195 A) and KI (7665/7699 A) doublet lines were used to confirm the young age of CHS7797. From the spectrum obtained at maximum light we derived a spectral type (SpT) of M6.05, while for the spectrum taken four days before maximum the derived SpT is M5.75. The derived SpTs confirm that CHS7797 has a mass in the stellar-substellar boundary mass range. In addition, the small differences in the derived SpTs at the two observed phases may provide indirect hints that CHS7797 is a binary system of similar mass components surrounded by a tilted circumbinary disk, a system similar to KH15D.Comment: 6 pages, accepted for publication A&

Impact of reanalysis boundary conditions on downscaled Atlantic hurricane activity

Climate models are capable of producing features similar to tropical cyclones, but typically display strong biases for many of the storm physical characteristics due to their relatively coarse resolution compared to the size of the storms themselves. One strategy that has been adopted to circumvent this limitation is through the use of a hybrid downscaling technique, wherein a large set of synthetic tracks are created by seeding disturbances in the large-scale environment. Here, we evaluate the ability of this technique at reproducing many of the characteristics of the recent North Atlantic hurricane activity as well as its sensitivity to the choice of the reanalysis dataset used as boundary conditions. In particular, we show that the geographical and intensity distributions are well reproduced, but that the technique has difficulty capturing the large difference in activity observed between the most recent active and quiescent phase. Although the signal is somewhat reduced compared to observation, the technique also detects a significant decrease in the intensification rate of hurricanes near the coastal U.S. during the active phase compared to the quiescent phase. Finally, the influence of the El Ni\~no Southern Oscillation on hurricane activity is generally well captured as well, but the technique fails to reproduce the increase in activity over the western part of the basin during Modoki El Niños.Ministerio de Economa y Competitividad (MINECO; Project GL2014-55764-R

The Effect of Mothers’ ASL Skill Level on the English Literacy of Their Deaf Children

Previous studies demonstrated a positive relationship between deaf children\u27s ASL acquisition and their English literacy skills and the importance of parental language input. This study examined the role of mothers\u27 ASL skill in the English literacy skills of their deaf children. Mothers and their deaf children in grades six through nine took the TGJASL-R. Correlations were performed to determine if a relationship exists between the mothers\u27 ASL skill level, and the children\u27s English literacy measured by the STAR test. No significant relationship was found; marginal significance was found between the students\u27 ASL skill and their English literacy score

Search for free-floating planetary-mass objects in the Pleiades

(Abridged) We aim at identifying the least massive population of the solar metallicity, young (120 Myr), nearby (133.5 pc) Pleiades star cluster with the ultimate goal of understanding the physical properties of intermediate-age, free-floating, low-mass brown dwarfs and giant planetary-mass objects, and deriving the cluster substellar mass function across the deuterium-burning mass limit at ~0.012 Msol. We performed a deep photometric and astrometric J- and H-band survey covering an area of ~0.8 deg^2. The images with completeness and limiting magnitudes of J,H ~ 20.2 and ~ 21.5 mag were acquired ~9 yr apart (proper motion precision of +/-6 mas/yr). J- and H-band data were complemented with Z, K, and mid-infrared magnitudes up to 4.6 micron coming from UKIDSS, WISE, and follow-up observations of our own. Pleiades member candidates were selected to have proper motions compatible with that of the cluster, and colors following the known Pleiades sequence in the interval J = 15.5-8.8 mag, and Z_UKIDSS - J > 2.3 mag or Z nondetections for J > 18.8 mag. We found a neat sequence of astrometric and photometric Pleiades substellar member candidates in the intervals J = 15.5-21.2 mag and ~0.072-0.008 Msol. The faintest objects show very red near- and mid-infrared colors exceeding those of field high-gravity dwarfs by >0.5 mag. The Pleiades photometric sequence does not show any color turn-over because of the presence of photospheric methane absorption down to J = 20.3 mag, which is about 1 mag fainter than predicted by the color-computed models. Pleiades brown dwarfs have a proper motion dispersion of 6.4-7.5 mas/yr and are dynamically relaxed at the age of the cluster. The Pleiades mass function extends down to the deuterium burning-mass threshold, with a slope fairly similar to that of other young star clusters and stellar associations.Comment: Accepted for publication in A&A. 16 page

Actual and potential distribution of an invasive canola pest, Meligethes viridescens (Coleoptera: Nitidulidae), in Canada

Meligethes viridescens (Fabricius), bronzed or rape blossom beetle, is a widespread and common pest of oilseed rape [Brassica napus L. and Brassica rapa L. (Brassicaceae)] in the western Palaearctic subregion. The establishment of M. viridescens in eastern North America has raised concern that its presence is a potential risk to the Canadian canola industry, especially to the prairie ecozone of western Canada where up to 4 million ha of summer canola (B. napus and B. rapa) are grown annually. Study of museum specimens indicated that M. viridescens was first recorded in Nova Scotia in 1947. Field surveys indicated that, as of 2001, M. viridescens was established as far west as Saint-Hyacinthe, Quebec. A CLIMEXTM model for M. viridescens in Europe was developed and validated with actual distribution records. In Canada the model predicted that once introduced, M. viridescens would readily survive in the canola-growing areas. The actual distribution of M. viridescens in eastern Canada matched the predicted distribution well. The westward dispersal to and establishment of M. viridescens in canola-growing areas of Ontario and western Canada, particularly southern Manitoba, appear to be inevitable. Establishment in these areas presents the risk of substantial production losses to canola producer

A Mini-PET beamline for optimized proton delivery to the ISOTRACE™ target system

Introduction The ISOTRACE™ Super-Conducting Cyclotron is PMB-Alcen’s redeveloped and modernized version of Oxford Instrument’s OSCAR superconducting cyclotron [1]. Its extracted 80+ mi-croamperes of 12 MeV protons are used for the production of PET radioisotopes. Following the philosophy of Dickie, Stevenson, Szlavik [2] for minimizing dose to personnel, and as developed by Dehnel et al [3,4], and Stokely et al [5], the ISOTRACE™ shall utilize an innovative, light-weight, integrated and self-supporting Mini-Beamline. This permits the relatively high residual radiation fields around PET targets to be moved ~1 metre away from the cyclotron, and facilitates the use of local shielding (around the targets) that limits prompt gammas and neutrons, but more importantly attenuates the residual target radiation, so that maintenance/research staff can work on the cyclotron in a relatively low activity environment. In addition, the mini-beamline for PET utilizes a compound quadrupole/steerer doublet that permits active and dynamic focusing/steering of the extracted proton beam for optimized production and minimized losses [3], so it improves on the successful work of Theroux et al [6]. The integrated beamline unit is extremely small, so that it is very unlike bulky traditional PET and SPECT beamlines that require substantial support structures, such as described by Dehnel in [7,8]. Material and Methods The ISOTRACE™ cyclotron is pictured in FIG. 1. The exit port flange and gate valve to which the integrated mini-beamline for PET shall be mounted is shown. Immediately upstream of the exit port, hidden from view, is a 4 jaw collimator (called BPI for Beam Position Indicator) with spilled beam current readbacks to the control system. TABLE 1 shows the nominal beam emittance and Twiss parameter values at the exit port flange location. This ion-optical information is necessary to simulate ion beam transport, develop the mini-beamline, and determine a nominal tune (i.e. magnet settings). Results and Conclusion TABLE 2 shows the ion-optical system parameters. FIGS. 2 and 3 show the horizontal and vertical beam profiles. The Horizontally focusing Quadrupole magnet (HQ), and Vertically focusing Quadrupole magnet (VQ) aperture diameter, 33 mm, was chosen to give sufficient beam acceptance. The focusing strength is a function of BL, so the effective length, L = 150 mm, was chosen to ensure Bmax less than 0.3 Tesla, while keeping overall magnet mass down. The quad-rupole magnets are fitted with water-cooled compound coils in which the copper/mylar strip wound portion of each coil is a winding for the quadrupole focusing function, and the wire wound portion is for the steering function. To increase beam acceptance and provide additional section strength for the pipe support function, the internal aperture of the low-activation aluminium beam pipe and the external shape are in the shape of a cross. FIG. 4 shows the beam crosssection at the mid-point of the downstream quadrupole magnet, and illustrates the additional acceptance as compared to a round beampipe. In order to machine the interior profile, the pipe is comprised of two premachined pieces that are friction stirwelded together. FIG. 5 is an isometric of the mini-beamline for PET. The four upstream HQ compound coils are excited with a 75A power supply for the horizontally focusing quadrupole magnet function, and a ± 10A power supply for a vertical steering function. The same power supplies are used for the four downstream VQ compound coils for the purpose of a vertically focusing quadrupole magnet function and horizontal steering function

Ligand design and preparation, photophysical properties, and device performance of an encapsulated-type pseudo-tris(heteroleptic) iridium(iii) emitter

The organic molecule 2-(1-phenyl-1-(pyridin-2-yl)ethyl)-6-(3-(1-phenyl-1-(pyridin-2-yl)ethyl)phenyl)pyridine (H3L) has been designed, prepared, and employed to synthesize the encapsulated-type pseudo-tris(heteroleptic) iridium(III) derivative Ir(κ6-fac-C,C′,C″-fac-N,N′,N″-L). Its formation takes place as a result of the coordination of the heterocycles to the iridium center and the ortho-CH bond activation of the phenyl groups. Dimer [Ir(μ-Cl)(η4-COD)]2 is suitable for the preparation of this compound of class [Ir(9h)] (9h = 9-electron donor hexadentate ligand), but Ir(acac)3 is a more appropriate starting material. Reactions were carried out in 1-phenylethanol. In contrast to the latter, 2-ethoxyethanol promotes the metal carbonylation, inhibiting the full coordination of H3L. Complex Ir(κ6-fac-C,C′,C″-fac-N,N′,N″-L) is a phosphorescent emitter upon photoexcitation, which has been employed to fabricate four yellow emitting devices with 1931 CIE (x:y) ∼ (0.52:0.48) and a maximum wavelength at 576 nm. These devices display luminous efficacies, external quantum efficiencies, and power efficacies at 600 cd m–2, which lie in the ranges 21.4–31.3 cd A–1, 7.8–11.3%, and 10.2–14.1 lm W1–, respectively, depending on the device configuration

On the Purity of the ZZ Ceti Instability Strip: Discovery of More Pulsating DA White Dwarfs on the Basis of Optical Spectroscopy

We report the discovery of two new ZZ Ceti pulsators, LP 133-144 and HE 1258+0123, selected on the basis of model atmosphere fits to optical spectroscopic data. The atmospheric parameters for LP 133-144, Teff = 11,800 +/- 200 K and log g = 7.87 +/- 0.05, and for HE 1258+0123, Teff = 11,410 +/- 200 K and log g = 8.04 +/- 0.05, place them within the empirical boundaries of the ZZ Ceti instability strip. This brings the number of known ZZ Ceti stars to a total of 36, a quarter of which have now been discovered using the spectroscopic approach for estimating their atmospheric parameters. This method has had a 100% success rate so far in predicting the variability of candidate ZZ Ceti stars. We have also analyzed additional spectra of known nonvariable white dwarfs in the vicinity of the ZZ Ceti instability strip. Our study further strengthens the idea that ZZ Ceti stars occupy a pure region in the log g-Teff plane, a region where no nonvariable stars are found. This result supports the thesis that ZZ Ceti pulsators represent a phase through which all DA stars must evolve.Comment: 11 pages, 4 figures, accepted for publication in the Astrophysical Journa